University of Wollongong

About: University of Wollongong is a education organization based out in Wollongong, New South Wales, Australia. It is known for research contribution in the topics: Population & Context (language use). The organization has 15674 authors who have published 46658 publications receiving 1197471 citations. The organization is also known as: UOW & Wollongong University.

Boosting Zinc Electrode Reversibility in Aqueous Electrolytes by Using Low-Cost Antisolvents

Abstract: Antisolvent addition has been widely studied in crystallization in the pharmaceutical industries by breaking the solvation balance of the original solution. Here we report a similar antisolvent strategy to boost Zn reversibility via regulation of the electrolyte on a molecular level. By adding for example methanol into ZnSO4 electrolyte, the free water and coordinated water in Zn2+ solvation sheath gradually interact with the antisolvent, which minimizes water activity and weakens Zn2+ solvation. Concomitantly, dendrite-free Zn deposition occurs via change in the deposition orientation, as evidenced by in situ optical microscopy. Zn reversibility is significantly boosted in antisolvent electrolyte of 50 % methanol by volume (Anti-M-50 %) even under harsh environments of -20 °C and 60 °C. Additionally, the suppressed side reactions and dendrite-free Zn plating/stripping in Anti-M-50 % electrolyte significantly enhance performance of Zn/polyaniline coin and pouch cells. We demonstrate this low-cost strategy can be readily generalized to other solvents, indicating its practical universality. Results will be of immediate interest and benefit to a range of researchers in electrochemistry and energy storage.

Spontaneous Weaving of Graphitic Carbon Networks Synthesized by Pyrolysis of ZIF-67 Crystals.

Abstract: Three-dimensional (3D) networks of graphitic carbon are promising materials for energy storage and conversion devices because of their high electrical conductivity, which is promoted by the good interconnection between the carbon particles. However, it is still difficult to directly synthesize such carbon networks. Herein, we report the novel synthesis of 3D graphitic carbon networks through the pyrolysis of nanosized ZIF-67 crystals. Interestingly, the unusual effect of downsizing the ZIF-67 crystals and the incorporation of catalytic Co nanoparticles was the spontaneous formation of graphitic networks. The obtained graphitic carbon networks show excellent electrochemical performance for the insertion and extraction of potassium ions.

Doing Discourse Analysis

Abstract: My hope in writing this chapter is to generate enthusiasm for geographical research employing discourse analysis. My intention is to provide some advice on doing discourse analysis to facilitale the design of research. I first outline why some geographers have been inspired by this approach. I suggest how Foucauldian discourse analysis is a break from other critical methods applied to textual analysis, including content analysis, semiology, and iconography. The theoretical underpinnings of the method provided by Michel Foucault, a French poststructuralist philosopher, is a key source of difference. I therefore condense Michel Foucault's contribution to discourse analysis by sketching out his key theoretical concepts and their methodological implications. To discuss the methodological implications 0f doing discourse analysis I draw upon the advice of feminist geographer Gillian Rose and linguist Norman Fairclough. I provide a list of questions to help implement a Foucauldian approach to discourse analysis and illustrate their implications lor 'doing' geography by drawing upon examples. This chapter should therefore be read only as an appetiser as there are many forms of discourse analysis. The suggested readings provide a much larger selection of the theoretical and methodological possibilities.

Five-Year Outcomes With Pembrolizumab Versus Chemotherapy for Metastatic Non-Small-Cell Lung Cancer With PD-L1 Tumor Proportion Score >= 50%

Abstract: PURPOSEWe report the first 5-year follow-up of any first-line phase III immunotherapy trial for non–small-cell lung cancer (NSCLC). KEYNOTE-024 (ClinicalTrials.gov identifier: NCT02142738) is an op...

Photocatalytic Degradation of Methyl Orange by CeO2 and Fe–doped CeO2 Films under Visible Light Irradiation

Abstract: Undoped CeO2 and 0.50-5.00 mol% Fe-doped CeO2 nanoparticles were prepared by a homogeneous precipitation combined with homogeneous/impreganation method, and applied as photocatalyst films prepared by a doctor blade technique. The superior photocatalytic performances of the Fe-doped CeO2 films, compared with undoped CeO2 films, was ascribed mainly to a decrease in band gap energy and an increase in specific surface area of the material. The presence of Fe(3+) as found from XPS analysis, may act as electron acceptor and/or hole donor, facilitating longer lived charge carrier separation in Fe-doped CeO2 films as confirmed by photoluminescence spectroscopy. The 1.50 mol% Fe-doped CeO2 film was found to be the optimal iron doping concentration for MO degradation in this study.