Showing papers on "Dipole published in 2020"
TL;DR: The results directly demonstrate that a change in the molecular dipole moments induced by intramolecular electron transfer can introduce a macroscopic polarization change in VT compounds.
Abstract: Polarization change induced by directional electron transfer attracts considerable attention owing to its fast switching rate and potential light control. Here, we investigate electronic pyroelectricity in the crystal of a mononuclear complex, [Co(phendiox)(rac-cth)](ClO4)·0.5EtOH (1·0.5EtOH, H2phendiox = 9, 10-dihydroxyphenanthrene, rac-cth = racemic 5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane), which undergoes a two-step valence tautomerism (VT). Correspondingly, pyroelectric current exhibits double peaks in the same temperature domain with the polarization change consistent with the change in dipole moments during the VT process. Time-resolved Infrared (IR) spectroscopy shows that the photo-induced metastable state can be generated within 150 ps at 190 K. Such state can be trapped for tens of minutes at 7 K, showing that photo-induced polarization change can be realized in this system. These results directly demonstrate that a change in the molecular dipole moments induced by intramolecular electron transfer can introduce a macroscopic polarization change in VT compounds. Polarization change from directional electron transfer attracts considerable attention owing to its fast switching rate and potential light control. Here, the authors provide a proof-of-concept of electronic pyroelectricity induced by intramolecular electron transfer in the single crystal of a valence tautomeric compound.
159 citations
TL;DR: In this article, the authors introduce new classes of hydrodynamic theories inspired by the recently discovered fracton phases of quantum matter, which are characterized by elementary excitations (fractons) with restricted mobility.
Abstract: We introduce new classes of hydrodynamic theories inspired by the recently discovered fracton phases of quantum matter. Fracton phases are characterized by elementary excitations (fractons) with restricted mobility. The hydrodynamic theories we introduce describe thermalization in systems with fracton-like mobility constraints, including fluids where charge and dipole moment are both locally conserved, and fluids where charge is conserved along every line or plane of a lattice. Each of these fluids is subdiffusive, and constitutes a new universality class of hydrodynamic behavior. There are infinitely many such classes, each with distinct subdiffusive exponents, all of which are captured by our formalism. Our framework naturally explains recent results on dynamics with constrained quantum circuits, as well as recent experiments with ultracold atoms in tilted optical lattices. We identify crisp experimental signatures of these novel hydrodynamics, and explain how they may be realized in near term ultracold atom experiments.
143 citations
TL;DR: From a perspective to identifying the electric dipole of various interlayers and correlating interfacial dipole with device performance on the basis of classic semiconductor device theory.
Abstract: Incorporating a dipole interlayer has been one of the most crucial interfacial engineering strategies in organic and perovskite solar cells. An interfacial dipole brings steep shifts in electronic band structure across interfaces and thus effectively tunes charge carrier transport. However, the origin of the interfacial dipole and its effects on device performance are not entirely clear; they are even controversial in some cases. We devote this Perspective to identifying the electric dipole of various interlayers and correlating the interfacial dipole with device performance on the basis of classical semiconductor device theory. It is important to further consider the chemical nature of interlayers beyond the simplified model of an interfacial dipole to develop a full understanding of interfacial structure, energy bands, and device operation mechanism. Researchers are encouraged to integrate in situ and in operando characterizations with numerical simulations in future studies.
134 citations
TL;DR: In this paper, the authors present the first detection of the thermal Sunyaev-Zeldovich (tSZ) effect in the tSZ maps and find that it is consistent with direct measurements of the CMB dipole.
Abstract: The largest temperature anisotropy in the cosmic microwave background (CMB) is the dipole, which has been measured with increasing accuracy for more than three decades, particularly with the Planck satellite. The simplest interpretation of the dipole is that it is due to our motion with respect to the rest frame of the CMB. Since current CMB experiments infer temperature anisotropies from angular intensity variations, the dipole modulates the temperature anisotropies with the same frequency dependence as the thermal Sunyaev-Zeldovich (tSZ) effect. We present the first, and significant, detection of this signal in the tSZ maps and find that it is consistent with direct measurements of the CMB dipole, as expected. The signal contributes power in the tSZ maps, which is modulated in a quadrupolar pattern, and we estimate its contribution to the tSZ bispectrum, noting that it contributes negligible noise to the bispectrum at relevant scales.
134 citations
TL;DR: This work establishes the multipole topology and its full hierarchy in three-dimensional geometries and presents a three dimensional acoustic metamaterial that exhibits the full hierarchy of topological multipole states including corner, hinge, surface and bulk states.
Abstract: Berry phase associated with energy bands in crystals can lead to quantised observables like quantised dipole polarizations in one-dimensional topological insulators. Recent theories have generalised the concept of quantised dipoles to multipoles, resulting in the discovery of multipole topological insulators which exhibit a hierarchy of multipole topology: a quantised octupole moment in a three-dimensional bulk induces quantised quadrupole moments on its two-dimensional surfaces, which in turn induce quantised dipole moments on one-dimensional hinges. Here, we report on the realisation of an octupole topological insulator in a three-dimensional acoustic metamaterial. We observe zero-dimensional topological corner states, one-dimensional gapped hinge states, two-dimensional gapped surface states, and three-dimensional gapped bulk states, representing the hierarchy of octupole, quadrupole and dipole moments. Conditions for forming a nontrivial octupole moment are demonstrated by comparisons with two different lattice configurations having trivial octupole moments. Our work establishes the multipole topology and its full hierarchy in three-dimensional geometries. The concept of topological corner states in two dimensional topological insulators can be generalised to higher dimensions. Here, authors present a three dimensional acoustic metamaterial that exhibits the full hierarchy of topological multipole states including corner, hinge, surface and bulk states.
124 citations
TL;DR: An alternative architecture is used that realizes a giant atom by coupling small atoms to a waveguide at multiple, but well separated, discrete locations, producing tunable atom–waveguide coupling and enabling decoherence-free interactions.
Abstract: Models of light–matter interactions in quantum electrodynamics typically invoke the dipole approximation1,2, in which atoms are treated as point-like objects when compared to the wavelength of the electromagnetic modes with which they interact. However, when the ratio between the size of the atom and the mode wavelength is increased, the dipole approximation no longer holds and the atom is referred to as a ‘giant atom’2,3. So far, experimental studies with solid-state devices in the giant-atom regime have been limited to superconducting qubits that couple to short-wavelength surface acoustic waves4–10, probing the properties of the atom at only a single frequency. Here we use an alternative architecture that realizes a giant atom by coupling small atoms to a waveguide at multiple, but well separated, discrete locations. This system enables tunable atom–waveguide couplings with large on–off ratios3 and a coupling spectrum that can be engineered by the design of the device. We also demonstrate decoherence-free interactions between multiple giant atoms that are mediated by the quasi-continuous spectrum of modes in the waveguide—an effect that is not achievable using small atoms11. These features allow qubits in this architecture to switch between protected and emissive configurations in situ while retaining qubit–qubit interactions, opening up possibilities for high-fidelity quantum simulations and non-classical itinerant photon generation12,13. Superconducting giant atoms are realized in a waveguide by coupling small atoms to the waveguide at multiple discrete locations, producing tunable atom–waveguide coupling and enabling decoherence-free interactions.
116 citations
TL;DR: It is shown that systems conserving the dipole moment of an associated global charge, or even higher-moment generalizations thereof, escape this scenario, displaying subdiffusive decay instead.
Abstract: The presence of global conserved quantities in interacting systems generically leads to diffusive transport at late times. Here, we show that systems conserving the dipole moment of an associated global charge, or even higher-moment generalizations thereof, escape this scenario, displaying subdiffusive decay instead. Modeling the time evolution as cellular automata for specific cases of dipole- and quadrupole conservation, we numerically find distinct anomalous exponents of the late time relaxation. We explain these findings by analytically constructing a general hydrodynamic model that results in a series of exponents depending on the number of conserved moments, yielding an accurate description of the scaling form of charge correlation functions. We analyze the spatial profile of the correlations and discuss potential experimentally relevant signatures of higher-moment conservation.
112 citations
TL;DR: The newly developed stimulated Raman excited fluorescence microscopy is employed to measure the electric field at the water-oil interface of microdroplets and it is suggested that this strong electric field might account in part for the unique properties of chemical reactions reported in micro droplets.
Abstract: Chemical reactions in aqueous microdroplets often exhibit unusual kinetic and thermodynamic properties not observed in bulk solution. While an electric field has been implicated at the water interface, there has been no direct measurement in aqueous microdroplets, largely due to the lack of proper measurement tools. Herein, we employ newly developed stimulated Raman excited fluorescence microscopy to measure the electric field at the water-oil interface of microdroplets. As determined by the vibrational Stark effect of a nitrile-bearing fluorescent probe, the strength of the electric field is found to be on the order of 107 V/cm. This strong electric field aligns probe dipoles with respect to the interface. The formation of the electric field likely arises from charge separation caused by the adsorption of negative ions at the water-oil interface of microdroplets. We suggest that this strong electric field might account in part for the unique properties of chemical reactions reported in microdroplets.
111 citations
108 citations
TL;DR: In this paper, the effects of crystal symmetry on the electronic and excitonic properties of a Van der Waals superlattice have been investigated using far-field optics, and it was shown that the AB and BA domains support interlayer excitons with out-of-plane electric dipole moments.
Abstract: Van der Waals heterostructures obtained via stacking and twisting have been used to create moire superlattices1, enabling new optical and electronic properties in solid-state systems. Moire lattices in twisted bilayers of transition metal dichalcogenides (TMDs) result in exciton trapping2–5, host Mott insulating and superconducting states6 and act as unique Hubbard systems7–9 whose correlated electronic states can be detected and manipulated optically. Structurally, these twisted heterostructures feature atomic reconstruction and domain formation10–14. However, due to the nanoscale size of moire domains, the effects of atomic reconstruction on the electronic and excitonic properties have not been systematically investigated. Here we use near-0°-twist-angle MoSe2/MoSe2 bilayers with large rhombohedral AB/BA domains15 to directly probe the excitonic properties of individual domains with far-field optics. We show that this system features broken mirror/inversion symmetry, with the AB and BA domains supporting interlayer excitons with out-of-plane electric dipole moments in opposite directions. The dipole orientation of ground-state Γ–K interlayer excitons can be flipped with electric fields, while higher-energy K–K interlayer excitons undergo field-asymmetric hybridization with intralayer K–K excitons. Our study reveals the impact of crystal symmetry on TMD excitons and points to new avenues for realizing topologically non-trivial systems16,17, exotic metasurfaces18, collective excitonic phases19 and quantum emitter arrays20,21 via domain-pattern engineering. Domain-resolved spectroscopy reveals the impact of local atomic registry and crystal symmetry on the exciton properties of individual domains in near-0°-twist-angle MoSe2/MoSe2.
107 citations
TL;DR: Repulsive dipole–dipole interactions between localized interlayer excitons are shown to modify the optical response of van der Waals heterobilayers, forming the basis to obtain strong optical nonlinearity and excitonic many-body states in two-dimensional materials.
Abstract: Although photons in free space barely interact, matter can mediate interactions between them resulting in optical nonlinearities. Such interactions at the single-quantum level result in an on-site photon repulsion, crucial for photon-based quantum information processing and for realizing strongly interacting many-body states of light. Here, we report repulsive dipole–dipole interactions between electric field-tuneable, localized interlayer excitons in the MoSe2/WSe2 heterobilayer. The presence of a single, localized exciton with an out-of-plane, non-oscillating dipole moment increases the energy of the second excitation by ~2 meV—an order of magnitude larger than the emission linewidth and corresponding to an inter-dipole distance of ~7 nm. At higher excitation power, multi-exciton complexes appear at systematically higher energies. The magnetic field dependence of the emission polarization is consistent with the spin-valley singlet nature of the dipolar molecular state. Our finding represents a step towards the creation of excitonic few- and many-body states such as dipolar crystals with spin-valley spinor in van der Waals heterostructures. Repulsive dipole–dipole interactions between localized interlayer excitons are shown to modify the optical response of van der Waals heterobilayers, forming the basis to obtain strong optical nonlinearity and excitonic many-body states in two-dimensional materials.
TL;DR: This work demonstrates efficient optical metamaterial engineering based on structured ensembles of atoms and paves the way towards controlling many-body physics with light5,6,11 and light–matter interfaces at the single-quantum level.
Abstract: Efficient and versatile interfaces for the interaction of light with matter are an essential cornerstone for quantum science. A fundamentally new avenue of controlling light-matter interactions has been recently proposed based on the rich interplay of photon-mediated dipole-dipole interactions in structured subwavelength arrays of quantum emitters. Here we report on the direct observation of the cooperative subradiant response of a two-dimensional (2d) square array of atoms in an optical lattice. We observe a spectral narrowing of the collective atomic response well below the quantum-limited decay of individual atoms into free space. Through spatially resolved spectroscopic measurements, we show that the array acts as an efficient mirror formed by only a single monolayer of a few hundred atoms. By tuning the atom density in the array and by changing the ordering of the particles, we are able to control the cooperative response of the array and elucidate the interplay of spatial order and dipolar interactions for the collective properties of the ensemble. Bloch oscillations of the atoms out of the array enable us to dynamically control the reflectivity of the atomic mirror. Our work demonstrates efficient optical metamaterial engineering based on structured ensembles of atoms and paves the way towards the controlled many-body physics with light and novel light-matter interfaces at the single quantum level.
TL;DR: Floquet driving is incorporated into HOTIs, and for the first time a dynamical polarization theory with anomalous nonequilibrium multipoles is reported, and a proposal to detect not only corner states but also their dynamical origin in cold atoms is demonstrated.
Abstract: Higher-order topological insulators (HOTIs) have emerged as a new class of phases, whose robust in-gap "corner" modes arise from the bulk higher-order multipoles beyond the dipoles in conventional topological insulators. Here, we incorporate Floquet driving into HOTIs, and report for the first time a dynamical polarization theory with anomalous nonequilibrium multipoles. Further, a proposal to detect not only corner states but also their dynamical origin in cold atoms is demonstrated, with the latter one never achieved before. Experimental determination of anomalous Floquet corner modes is also proposed.
TL;DR: In this article, a stochastic lattice gas of particles in one dimension with strictly finite-range interactions was studied, where the fracton-like conservation laws of total charge and dipole moment were studied.
Abstract: We study a stochastic lattice gas of particles in one dimension with strictly finite-range interactions that respect the fractonlike conservation laws of total charge and dipole moment. As the charge density is varied, the connectivity of the system's charge configurations under the dynamics changes qualitatively. We find two distinct phases: Near half filling the system thermalizes subdiffusively, with almost all configurations belonging to a single dynamically connected sector. As the charge density is tuned away from half filling there is a phase transition to a frozen phase, where locally active finite bubbles cannot exchange particles and the system fails to thermalize. The two phases exemplify what has recently been referred to as weak and strong Hilbert space fragmentation, respectively. We study the static and dynamic scaling properties of this weak-to-strong fragmentation phase transition in a kinetically constrained classical Markov circuit model, obtaining some conjectured exact critical exponents.
TL;DR: Battery-type lithiation of TiO2 generates a built-in electric field in the bulk material, giving a 750% enhancement in photocurrent density and 100 mV negative shift of onset potential upon the lithiation.
Abstract: Providing sufficient driving force for charge separation and transfer (CST) is a critical issue in photoelectrochemical (PEC) energy conversion. Normally, the driving force is derived mainly from band bending at the photoelectrode/electrolyte interface but negligible in the bulk. To boost the bulky driving force, we report a rational strategy to create effective electric field via controllable lattice distortion in the bulk of a semiconductor film. This concept is verified by the lithiation of a classic TiO2 (Li-TiO2) photoelectrode, which leads to significant distortion of the TiO6 unit cells in the bulk with well-aligned dipole moment. A remarkable internal built-in electric field of ~2.1 × 102 V m−1 throughout the Li-TiO2 film is created to provide strong driving force for bulky CST. The photoelectrode demonstrates an over 750% improvement of photocurrent density and 100 mV negative shift of onset potential upon the lithiation compared to that of pristine TiO2 film. The driving force for charge transfer in photoelectrochemical systems is typically derived from band bending at a surface-electrolyte interface. In this work, battery-type lithiation of TiO2 generates a built-in electric field in the bulk material, giving a 750% enhancement in photocurrent density.
TL;DR: Theoretically, both the counter-rotating terms and the dipole self-energy in the quantum electrodynamics Hamiltonian are important for obtaining an accurate polariton eigenspectrum, hence, the polariton mediated charge transfer rate constant is found, especially in the ultra-strong coupling regime.
Abstract: We investigate the polariton-mediated electron transfer reaction in a model system with analytic rate constant theory and direct quantum dynamical simulations We demonstrate that the photoinduced charge transfer reaction between a bright donor state and dark acceptor state can be significantly enhanced or suppressed by coupling the molecular system to the quantized radiation field inside an optical cavity This is because the quantum light-matter interaction can influence the effective driving force and electronic couplings between the donor state, which is the hybrid light-matter excitation, and the molecular acceptor state Under the resonance condition between the photonic and electronic excitations, the effective driving force can be tuned by changing the light-matter coupling strength; for an off-resonant condition, the same effect can be accomplished by changing the molecule-cavity detuning We further demonstrate that using both the electronic coupling and light-matter coupling helps to extend the effective couplings across the entire system, even for the dark state that carries a zero transition dipole Theoretically, we find that both the counter-rotating terms and the dipole self-energy in the quantum electrodynamics Hamiltonian are important for obtaining an accurate polariton eigenspectrum as well as the polariton-mediated charge transfer rate constant, especially in the ultrastrong coupling regime
TL;DR: In this paper, the authors proposed a theoretical approach based on density functional properties of the FeNC catalyst for electrochemical CO2 reduction (CO2R) based on FeNC.
Abstract: Iron–nitrogen-doped graphene (FeNC) has emerged as an exciting earth-abundant catalyst for electrochemical CO2 reduction (CO2R). However, standard theoretical approaches based on density functional...
TL;DR: Tensile strain is applied to quantum emitters embedded in few-layer hBN films and both red and blue spectral shifts are realized with tuning magnitudes up to 65 meV, a record for any 2D quantum source.
Abstract: Quantum emitters in hexagonal boron nitride (hBN) are promising building blocks for the realization of integrated quantum photonic systems. However, their spectral inhomogeneity currently limits their potential applications. Here, tensile strain is applied to quantum emitters embedded in few-layer hBN films and both red and blue spectral shifts are realized with tuning magnitudes up to 65 meV, a record for any 2D quantum source. Reversible tuning of the emission and related photophysical properties is demonstrated. Rotation of the optical dipole in response to strain is also observed, suggesting the presence of a second excited state. A theoretical model is derived to describe strain-based tuning in hBN, and the rotation of the optical dipole. The study demonstrates the immense potential for strain tuning of quantum emitters in layered materials to enable their employment in scalable quantum photonic networks.
TL;DR: In this article, the effects of progenitor's rotation and magnetic fields on core-collapse supernovae in full general relativity (GR) with spectral neutrino transport were studied.
Abstract: We present results of three-dimensional (3D), radiation-magnetohydrodynamics (MHD) simulations of core-collapse supernovae in full general relativity (GR) with spectral neutrino transport. In order to study the effects of progenitor's rotation and magnetic fields, we compute three models, where the precollapse rotation rate and magnetic fields are included parametrically to a 20 M$_{\odot}$ star. While we find no shock revival in our two non-magnetized models during our simulation times ($\sim500$ ms after bounce), the magnetorotationally (MR) driven shock expansion immediately initiates after bounce in our rapidly rotating and strongly magnetized model. We show that the expansion of the MR-driven flows toward the polar directions is predominantly driven by the magnetic pressure, whereas the shock expansion toward the equatorial direction is supported by neutrino heating. Our detailed analysis indicates that the growth of the so-called kink instability may hinder the collimation of jets, resulting in the formation of broader outflows. Furthermore we find a dipole emission of lepton number, only in the MR explosion model, whose asymmetry is consistent with the explosion morphology. Although it is similar to the lepton-number emission self-sustained asymmetry (LESA), our analysis shows that the dipole emission occurs not from the protoneutron star convection zone but from above the neutrino sphere indicating that it is not associated with the LESA. We also report several unique neutrino signatures, which are significantly dependent on both the time and the viewing angle, if observed, possibly providing a rich information regarding the onset of the MR-driven explosion.
TL;DR: In this paper, a higher-order topological insulator (PHOTI) was constructed in synthetic dimensions, where each photonic molecule comprises two coupled rings, and the phase difference of the modulation between adjacent coupled photonic molecules was predicted to predict a dynamical topological phase transition.
Abstract: Conventional topological insulators support boundary states with dimension one lower than that of the bulk system that hosts them, and these states are topologically protected due to quantized bulk dipole moments. Recently, higher-order topological insulators have been proposed as a way of realizing topological states with dimensions two or more lower than that of the bulk due to the quantization of bulk quadrupole or octupole moments. However, all these proposals as well as experimental realizations have been restricted to real-space dimensions. Here, we construct photonic higher-order topological insulators (PHOTIs) in synthetic dimensions. We show the emergence of a quadrupole PHOTI supporting topologically protected corner modes in an array of modulated photonic molecules with a synthetic frequency dimension, where each photonic molecule comprises two coupled rings. By changing the phase difference of the modulation between adjacent coupled photonic molecules, we predict a dynamical topological phase transition in the PHOTI. Furthermore, we show that the concept of synthetic dimensions can be exploited to realize even higher-order multipole moments such as a fourth-order hexadecapole (16-pole) insulator supporting 0D corner modes in a 4D hypercubic synthetic lattice that cannot be realized in real-space lattices.
TL;DR: In this paper, a physically inspired machine learning model was proposed to represent the molecular dipole moment (μ) with a physically-inspired ML model that captures two distinct physical effects: local atomic polarization is captured within the symmetry-adapted Gaussian process regression framework, while the movement of charge across the entire molecule is captured by assigning a partial (scalar) charge to each atom.
Abstract: The molecular dipole moment (μ) is a central quantity in chemistry. It is essential in predicting infrared and sum-frequency generation spectra as well as induction and long-range electrostatic interactions. Furthermore, it can be extracted directly-via the ground state electron density-from high-level quantum mechanical calculations, making it an ideal target for machine learning (ML). In this work, we choose to represent this quantity with a physically inspired ML model that captures two distinct physical effects: local atomic polarization is captured within the symmetry-adapted Gaussian process regression framework which assigns a (vector) dipole moment to each atom, while the movement of charge across the entire molecule is captured by assigning a partial (scalar) charge to each atom. The resulting "MuML" models are fitted together to reproduce molecular μ computed using high-level coupled-cluster theory and density functional theory (DFT) on the QM7b dataset, achieving more accurate results due to the physics-based combination of these complementary terms. The combined model shows excellent transferability when applied to a showcase dataset of larger and more complex molecules, approaching the accuracy of DFT at a small fraction of the computational cost. We also demonstrate that the uncertainty in the predictions can be estimated reliably using a calibrated committee model. The ultimate performance of the models-and the optimal weighting of their combination-depends, however, on the details of the system at hand, with the scalar model being clearly superior when describing large molecules whose dipole is almost entirely generated by charge separation. These observations point to the importance of simultaneously accounting for the local and non-local effects that contribute to μ; furthermore, they define a challenging task to benchmark future models, particularly those aimed at the description of condensed phases.
TL;DR: It is shown that two-time, second-order correlations of scattered photons from planar arrays and chains of atoms display nonclassical features that can be described by a superatom picture of the canonical single-atom g_{2}(τ) resonance fluorescence result.
Abstract: We show that two-time, second-order correlations of scattered photons from planar arrays and chains of atoms display nonclassical features that can be described by a superatom picture of the canonical single-atom g2(τ) resonance fluorescence result. For the superatom, the single-atom linewidth is replaced by the linewidth of the underlying collective low light-intensity eigenmode. Strong light-induced dipole-dipole interactions lead to a correlated response, suppressed joint photon detection events, and dipole blockade that inhibits multiple excitations of the collective atomic state. For targeted subradiant modes, the nonclassical nature of emitted light can be dramatically enhanced even compared with that of a single atom.
TL;DR: In this article, a quantitative analysis of the Rydberg sensor's sensitivity to oscillating electric fields with frequencies between 1 kHz and 1 THz is presented, using a combination of analytical and semi-classical Floquet models.
Abstract: Rydberg atoms have attracted significant interest recently as electric field sensors. In order to assess potential applications, detailed understanding of relevant figures of merit is necessary, particularly in relation to other, more mature, sensor technologies. Here we present a quantitative analysis of the Rydberg sensor's sensitivity to oscillating electric fields with frequencies between 1 kHz and 1 THz. Sensitivity is calculated using a combination of analytical and semi-classical Floquet models. Using these models, optimal sensitivity at arbitrary field frequency is determined. We validate the numeric Floquet model via experimental Rydberg sensor measurements over a range of 1-20 GHz. Using analytical models, we compare with two prominent electric field sensor technologies: electro-optic crystals and dipole antenna-coupled passive electronics.
TL;DR: A reconfigurable graphene antenna is designed and numerically analyzed that contains a radiating graphene patch and non-radiating graphene ring and can be steered in different directions as per the location of applied gate voltage at the periphery of graphene ring.
Abstract: A reconfigurable graphene antenna is designed and numerically analyzed. The antenna structure contains a radiating graphene patch and non-radiating graphene ring. The operating frequency of the antenna can be tuned by applying the gate voltage on the graphene patch. This proximity coupled antenna structure operates with the [Formula: see text] mode. In this configuration, the field is distributed in the form of horizontal magnetic dipole. The application of gate voltage at the periphery of graphene ring converts the field configuration to the form of the vertical electric dipole. Thus, the mode of operation of the antenna is changed to [Formula: see text] Consequently, the radiation pattern of the antenna can be steered in different directions as per the location of the applied gate voltage at the periphery of the graphene ring.
TL;DR: This work optically probed the interaction between intra- and interlayer excitons as they were energetically tuned into resonance and found highly tunable excitonic transitions with large in-built dipoles and oscillator strengths will result in strong exciton–exciton interactions and hold great promise for non-linear optics with polaritons.
Abstract: Transition metal dichalcogenides (TMDs) constitute a versatile platform for atomically thin optoelectronics devices and spin-valley memory applications. In monolayers optical absorption is strong, but the transition energy is not tunable as the neutral exciton has essentially no out-of-plane electric dipole. In contrast, interlayer exciton transitions in heterobilayers are widely tunable in applied electric fields, but their coupling to light is considerably reduced. Here, we show tuning over 120 meV of interlayer excitons with high oscillator strength in bilayer MoS2. These shifts are due to the quantum confined Stark effect, here the electron is localised to one of the layers yet the hole is delocalised across the bilayer. We optically probe the interaction between intra- and interlayer excitons as they are energetically tuned into resonance. This allows studying their mixing supported by beyond standard density functional theory calculations including excitonic effects. In MoS2 trilayers our experiments uncover two types of interlayer excitons with and without in-built electric dipoles, respectively. Highly tunable excitonic transitions with large oscillator strength and in-built dipoles, that lead to considerable exciton-exciton interactions, hold great promise for non-linear optics with polaritons.
TL;DR: In this article, a chiral enhancement from a non-trivial quartic coupling of the scalar potential was introduced to explain the anomalous magnetic moments of the electron and the muon.
Abstract: The stringent experimental bound on μ → eγ is compatible with a simultaneous and sizable new physics contribution to the electron and muon anomalous magnetic moments (g − 2)l (l = e, μ), only if we assume a non-trivial flavor structure of the dipole operator coefficients. We propose a mechanism in which the realization of the (g − 2)l correction is manifestly related to the mass generation through a flavor symmetry. A radiative flavon correction to the fermion mass gives a contribution to the anomalous magnetic moment. In this framework, we introduce a chiral enhancement from a non-trivial
$$ \mathcal{O} $$
(1) quartic coupling of the scalar potential. We show that the muon and electron anomalies can be simultaneously explained in a vast region of the parameter space with predicted vector-like mediators of masses as large as Mχ ∈ [0.6, 2.5] TeV.
TL;DR: The LCPGE in twisted bilayer graphene is calculated, and it is found that it exhibits a resonance peak whose frequency can be tuned from visible to infrared as the twisting angle varies, particularly in the infrared range.
Abstract: We develop a general theory of the layer circular photogalvanic effect (LCPGE) in quasi-two-dimensional chiral bilayers, which refers to the appearance of a polarization-dependent, out-of-plane static dipole moment induced by circularly polarized light. We elucidate the geometric origin of the LCPGE as two types of interlayer coordinate shift weighted by the quantum metric tensor and the Berry curvature, respectively. As a concrete example, we calculate the LCPGE in twisted bilayer graphene, and find that it exhibits a resonance peak whose frequency can be tuned from visible to infrared as the twisting angle varies. The LCPGE thus provides a promising route toward frequency-sensitive, circularly polarized light detection, particularly in the infrared range.
TL;DR: A novel terahertz nanofilm sensor consisting of toroidal dipole bound states in the continuum (TD-BIC inspired Fano resonance metasurface) is proposed and investigated, which exhibits both the TD character and BIC feature.
Abstract: A novel terahertz nanofilm sensor consisting of toroidal dipole bound states in the continuum (TD-BIC) inspired Fano resonance metasurface is proposed and investigated, which exhibits both the TD character and BIC feature. When the mirror symmetry of the unit cell was broken, the TD resonance was excited and demonstrated by anti-aligned magnetic dipoles and calculated scattering powers and the BIC mode was verified with the quality factor satisfying the inverse square law. Combined with the amplitude difference referencing technique, the TD-BIC inspired Fano resonance was utilized for nanofilm sensing at THz frequencies for the first time. Simulation results show that the amplitude difference can be easily observed by comparing the resonance frequency shift under difference thicknesses of germanium overlayer. Moreover, by coating with a 40 nm-thick analyte overlayer, the sensitivity of amplitude difference can achieve 0.32/RIU, which is a significant value and more suitable for sensing nanofilm analytes than the traditional frequency shift method. These advantages make our proposed structure have potential applications in sensing nanofilm analytes.
12 May 2020
TL;DR: In this paper, a tunable number of dipolar inter-layer excitons (NIX) were trapped in a nanoscale confinement potential induced by placing a MoSe2-WSe2 hetero-bilayer onto an array of SiO2 nanopillars.
Abstract: Inter-layer excitons (IXs) in hetero-bilayers of transition metal dichalcogenides (TMDs) represent an exciting emergent class of long-lived dipolar composite bosons in an atomically thin, near-ideal two-dimensional (2D) system. The long-range interactions that arise from the spatial separation of electrons and holes can give rise to novel quantum, as well as classical multi-particle correlation effects. Indeed, first indications of exciton condensation have been reported recently. In order to acquire a detailed understanding of the possible many-body effects, the fundamental interactions between individual IXs have to be studied. Here, we trap a tunable number of dipolar IXs (NIX ~ 1–5) within a nanoscale confinement potential induced by placing a MoSe2–WSe2 hetero-bilayer (HBL) onto an array of SiO2 nanopillars. We control the mean occupation of the IX trap via the optical excitation level and observe discrete sharp-line emission from different configurations of interacting IXs. The intensities of these features exhibit characteristic near linear, quadratic, cubic, quartic and quintic power dependencies, which allows us to identify them as different multiparticle configurations with NIX ~ 1–5. We directly measure the hierarchy of dipolar and exchange interactions as NIX increases. The interlayer biexciton (NIX = 2) is found to be an emission doublet that is blue-shifted from the single exciton by ΔE = (8.4 ± 0.6) meV and split by 2J = (1.2 ± 0.5) meV. The blueshift is even more pronounced for triexcitons ((12.4 ± 0.4) meV), quadexcitons ((15.5 ± 0.6) meV) and quintexcitons ((18.2 ± 0.8) meV). These values are shown to be mutually consistent with numerical modelling of dipolar excitons confined to a harmonic trapping potential having a confinement lengthscale in the range $$\ell \approx 3$$
nm. Our results contribute to the understanding of interactions between IXs in TMD hetero-bilayers at the discrete limit of only a few excitations and represent a key step towards exploring quantum correlations between IXs in TMD hetero-bilayers.
TL;DR: In this article, the authors demonstrate extreme tunability of ultracold chemical reaction rates by inducing resonant dipolar interactions by means of an external electric field and demonstrate the contribution from the three dominant angular momentum projections of the collisions.
Abstract: Full control of molecular interactions, including reactive losses, would open new frontiers in quantum science. We demonstrate extreme tunability of ultracold chemical reaction rates by inducing resonant dipolar interactions by means of an external electric field. We prepared fermionic potassium-rubidium molecules in their first excited rotational state and observed a modulation of the chemical reaction rate by three orders of magnitude as we tuned the electric field strength by a few percent across resonance. In a quasi–two-dimensional geometry, we accurately determined the contributions from the three dominant angular momentum projections of the collisions. Using the resonant features, we shielded the molecules from loss and suppressed the reaction rate by an order of magnitude below the background value, thereby realizing a long-lived sample of polar molecules in large electric fields.