Polytechnic University of Valencia

About: Polytechnic University of Valencia is a education organization based out in Valencia, Spain. It is known for research contribution in the topics: Catalysis & Population. The organization has 16282 authors who have published 40162 publications receiving 850234 citations.

Thermal-, pressure-, and light-induced spin transition in novel cyanide-bridged FeII-AgI bimetallic compounds with three-dimensional interpenetrating double structures (FeIILx[Ag(CN)2]2).G.

Abstract: Low-spin, high-spin and spin-transition behaviours have been observed for the doubly interpenetrating three-dimensional bimetallic compounds {Fe I I (pz)[Ag(CN) 2 ] 2 }.pz (pz = pyrazine), {Fe I I (4,4'-bipy) 2 [Ag(CN) 2 ] 2 } (4,4'-bipy = 4,4'-bipyridine), and {Fe I I -(bpe) 2 [Ag(CN) 2 ] 2 } (bpe = bispyridyl-ethylene), respectively. The single crystals of the bpe derivative undergo a spin transition with a large hysteresis loop at about 95 K. After several warming and cooling cycles, the single crystals become a microcrystalline powder with 50% spin transition. Influence of pressure- as well as light-induced excited spin-state trapping (LIESST) on the thermal 50% spin transition of the microcrystalline sample has also been investigated. Thermal spin-transition behaviour has also been induced at pressures higher than 1 bar for the 4,4'-bipy derivative. Both the 4,4'-bipy and bpe derivatives show strong pressure dependence of the spin state at 300 K.

Overview of the 1st international competition on plagiarism detection

Abstract: Thispaper overviews 18 plagiarism detectors that have been developed and evaluated within PAN'10. We start with a unified retrieval process that sum- marizes the best practices employed this year. Then, the detectors' performances are evaluated in detail, highlighting several important aspects of plagiarism de- tection, such as obfuscation, intrinsic vs. external plagiarism, and plagiarism case length. Finally, all results are compared to those of last year's competition.

A Review of Interface Electronic Systems for AT-cut Quartz Crystal Microbalance Applications in Liquids

Abstract: From the first applications of AT-cut quartz crystals as sensors in solutions more than 20 years ago, the so-called quartz crystal microbalance (QCM) sensor is becoming into a good alternative analytical method in a great deal of applications such as biosensors, analysis of biomolecular interactions, study of bacterial adhesion at specific interfaces, pathogen and microorganism detection, study of polymer film-biomolecule or cell-substrate interactions, immunosensors and an extensive use in fluids and polymer characterization and electrochemical applications among others. The appropriate evaluation of this analytical method requires recognizing the different steps involved and to be conscious of their importance and limitations. The first step involved in a QCM system is the accurate and appropriate characterization of the sensor in relation to the specific application. The use of the piezoelectric sensor in contact with solutions strongly affects its behavior and appropriate electronic interfaces must be used for an adequate sensor characterization. Systems based on different principles and techniques have been implemented during the last 25 years. The interface selection for the specific application is important and its limitations must be known to be conscious of its suitability, and for avoiding the possible error propagation in the interpretation of results. This article presents a comprehensive overview of the different techniques used for AT-cut quartz crystal microbalance in in-solution applications, which are based on the following principles: network or impedance analyzers, decay methods, oscillators and lock-in techniques. The electronic interfaces based on oscillators and phase-locked techniques are treated in detail, with the description of different configurations, since these techniques are the most used in applications for detection of analytes in solutions, and in those where a fast sensor response is necessary.