Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Book ChapterDOI
Alkaline Earth Metal-Based Metal–Organic Frameworks: Synthesis, Properties, and Applications
Journal ArticleDOI
Molecular simulation of penetration separation for ethanol/water mixtures using two-dimensional nanoweb graphynes
TL;DR: In this paper, the authors investigate the performance of liquid ethanol-water mixtures across polyporous two-dimensional γ-graphyne sheets and find that ethanol with larger molecular diameter permeates faster through the graphyne pores than water.
Journal ArticleDOI
Separation of Light Hydrocarbons through Selective Molecular Exclusion by a Microporous Metal–Organic Framework
TL;DR: The results show that compound 1 possesses remarkably high selectivity towards C2 over C3 /C4 hydrocarbons and the separation is achieved by selective molecular exclusion.
Journal ArticleDOI
Direct Structural Evidence of Molecular Packing Effects of Xylene Isomers Adsorbed in BIF-20
TL;DR: In this paper, a boron imidazolate framework material with high xylene uptake and a single component diffusion selectivity of 3.5 was reported, showing the presence of steric effects in ortho-xylene adsorption.
Molecular simulation of tunable materials: Metal-organic frameworks a ionic liquids theory a application
TL;DR: In this paper, the authors deal with two types of materials, Metal-Organic Frameworks and Ionic Liquids, and the study with molecular simulation to determine their potential for specific gas separations.
References
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Journal ArticleDOI
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.