Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Design of a MOF-based nano-trap for the efficient separation of propane from propylene.
TL;DR: In this paper , a parallel Cu paddle wheel structure was developed to form an efficient C3H6 nano-trap with high selectivity at 298 K. Benefiting from having this trap, ATC-Cu showed a very high capacity for binding C 3H6 and high C 3 H6/C 3 H8 selectivity.
Journal ArticleDOI
Al‐based Isoreticular Metal‐Organic Frameworks with MIL‐53 Topology as Effective Adsorbents in Methane Purification
Honore N. Wamba,Narendra Singh,Suman Dalakoti,Swapnil Divekar,Aarti Arya,Alain C. Tagne Kuate,Jean Ngoune,Soumen Dasgupta +7 more
TL;DR: In this paper , an isoreticular series of Al-based metal-organic frameworks (MOFs) with MIL-53 topology were examined for their adsorption capacity for C3H8, C3h6, C2H4, and CH4.
Journal ArticleDOI
Crystal structure of the chained metal-organic coordination polymer [Cd(dmf)(ntca)]
TL;DR: The crystal structure of a novel chained metal-organic coordination polymer [Cd(dmf)(ntca)] obtained by heating of cadmium nitrate and naphthalene-1,4,5,8-tetracarboxylic acid monoanhydride (H2ntca) in N,N′-dimethylformamide (DMF) is determined as mentioned in this paper.
Journal ArticleDOI
Full Exclusion of Branched Hexanes from Their Linear Isomer by a Robust Aluminum Metal–Organic Framework with Tailored Pore Structure
Liang Yu,Saif Ullah,Jinze Yao,Danxia Lin,Jiajin Huang,Shih-Tien Tu,Haoyuan Luo,Qibin Xia,Timo Thonhauser,Hao Wang +9 more
TL;DR: In this paper , the complete exclusion of branched hexanes from their linear isomer by an aluminum metal-organic framework, CAU-21-ODB (ODB = 4,4′-oxidibenzoate) with high stability was reported.
Patent
Porous metal-organic framework with pyrimidine groups for methane storage exhibiting high working capacity
Banglin Chen,Bin Li,Hui Min Wen +2 more
TL;DR: In this paper, the metal-organic frameworks (MOF) and uses thereof are discussed, including those comprising a repeat unit of the formula [Cu 2 L(H 2 O) 2 ]-5DMF-3 H 2 O, wherein L is a ligand of the MOF, and are useful for many applications, including purification of hydrogen gas from production byproducts CH 4 and CO 2, sensing, heterogeneous catalysis, drug delivery, lithium sulfide battery, membrane and analytical devices.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.