Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Luminescent metal–organic frameworks for chemical sensing and explosive detection
TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
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Covalent organic frameworks (COFs): from design to applications
San-Yuan Ding,Wei Wang +1 more
TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
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Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
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Water stability and adsorption in metal-organic frameworks.
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Tuning the structure and function of metal–organic frameworks via linker design
Weigang Lu,Zhangwen Wei,Zhi-Yuan Gu,Tian-Fu Liu,Jinhee Park,Jihye Park,Jian Tian,Muwei Zhang,Qiang Zhang,Thomas Gentle,Mathieu Bosch,Hong-Cai Zhou +11 more
TL;DR: This critical review of metal-organic frameworks (MOFs) highlights advances in MOF synthesis focusing on linker design and examples of building MOFs to reach unique properties, such as unprecedented surface area, pore aperture, molecular recognition, stability, and catalysis, through linkers are described.
References
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Journal ArticleDOI
RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption
TL;DR: The unexpected nonplanar arrangement of the tricoordinate boron center in 1 provides another demonstration of the many novel structural patterns that the heavier elements of the main group can contribute to the firstrow elements, and invites experimental verification.
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Novel scheme to study structural and thermal properties of continuously deformable molecules
TL;DR: In this paper, a configurational-bias Monte Carlo (DBMC) algorithm was proposed to calculate the chemical potential of arbitrary chain molecules in a computer simulation, based on a generalization of the Siepmann's method.
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Zn(tbip) (H2tbip= 5-tert-Butyl Isophthalic Acid): A Highly Stable Guest-Free Microporous Metal Organic Framework with Unique Gas Separation Capability
TL;DR: A novel guest-free metal organic framework (GFMMOF) is synthesized and structurally characterized that demonstrates a remarkable thermal stability, a unique ability to separate methanol from dimethyl ether or water, and is among the microporous MOFs having the highest adsorbed hydrogen density.
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How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53**
TL;DR: Taking a deep breath: the hydrated form of the microporous metal organic framework MIL-53(Cr) performs better than the dehydrated form for the selectivity binding of carbon dioxide over methane (see graph).
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Flexible (Breathing) Interpenetrated Metal−Organic Frameworks for CO2 Separation Applications
Praveen K. Thallapally,Jian Tian,Motkuri Radha Kishan,Carlos Fernandez,Scott J. Dalgarno,Peter B. McGrail,John E. Warren,Jerry L. Atwood +7 more
TL;DR: A breathing 2-fold interpenetrated microporous metal-organic framework was synthesized with a flexible tetrahedral organic linker and Zn( 2) clusters that sorb CO(2) preferably over N (2) and H(2).