Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Selective adsorption and removal of drug contaminants by using an extremely stable Cu(II)-based 3D metal-organic framework.
Weicong Liu,Xin Shen,Yaoyao Han,Zhaohui Liu,Wei Dai,Archisman Dutta,Abhinav Kumar,Jianqiang Liu +7 more
TL;DR: Investigations indicate that 1 could become a potential material to adsorb DCF from aqueous medium, which is higher in comparison to most of the reported MOFs.
Journal ArticleDOI
Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale
TL;DR: This review aims to summarise the chemical strategies that have guided the design of conductive metal-organic frameworks and the identified opportunities for further development and showcase relevant examples of functional devices that have received increasing attention from researchers.
Journal ArticleDOI
Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework
Selvan Demir,Nicholas K. Brune,Jeffrey F. Van Humbeck,Jarad A. Mason,Tatiana V. Plakhova,Shuao Wang,Guoxin Tian,Stefan G. Minasian,Tolek Tyliszczak,Tsuyoshi Yaita,Tohru Kobayashi,Stepan N. Kalmykov,Hideaki Shiwaku,David K. Shuh,Jeffrey R. Long +14 more
TL;DR: A study of the adsorption of selected metal ions, Sr2+, Fe3+, Nd3+, and Am3+, from aqueous solutions employing a carbon-based porous aromatic framework, BPP-7 (Berkeley Porous Polymer-7), which displays high metal loading capacities together with excellent Adsorption selectivity for neodymium over strontium.
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Non-Interpenetrated Metal-Organic Frameworks Based on Copper(II) Paddlewheel and Oligoparaxylene-Isophthalate Linkers: Synthesis, Structure, and Gas Adsorption.
Yong Yan,Yong Yan,Michal Juríček,Michal Juríček,François-Xavier Coudert,Nicolaas A. Vermeulen,Sergio Grunder,Dailly Anne M,William Lewis,Alexander J. Blake,J. Fraser Stoddart,Martin Schröder,Martin Schröder +12 more
TL;DR: The single-crystal structure of MFM-131 confirms that the methyl substituents of the paraxylene units block the windows in the Kagomé lattice layer of the framework, effectively inhibiting network interpenetration in M FM-131, and provides an efficient method for preventing network inter penetration.
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Coordination polymers with nucleobases: From structural aspects to potential applications
Pilar Amo-Ochoa,Félix Zamora +1 more
TL;DR: The state-of-the-art of coordination polymers using nucleobases as ligands can be found in this article, which collects the literature already published in a comprehensive way and attempts to provide perspectives for this research field.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.