Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Fine-Tuning of Nano-Traps in a Stable Metal-Organic Framework for Highly Efficient Removal of Propyne from Propylene
TL;DR: Zhang et al. as mentioned in this paper designed a microporous MOF with a fine-tuned nanocage, exhibiting the desired size, shape, and functionalities that are suitable for trapping a single propyne (C3H4) molecule.
Journal ArticleDOI
Metastable interwoven mesoporous metal-organic frameworks.
Yabing He,Zhiyong Guo,Shengchang Xiang,Zhangjing Zhang,Wei Zhou,Wei Zhou,Frank R. Fronczek,Sean Parkin,Stephen T. Hyde,Michael O'Keeffe,Banglin Chen +10 more
TL;DR: Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology were synthesized and structurally characterized and the most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.
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Correlation of Gas Permeability in a Metal-Organic Framework MIL-101(Cr)–Polysulfone Mixed-Matrix Membrane with Free Volume Measurements by Positron Annihilation Lifetime Spectroscopy (PALS)
TL;DR: Positron annihilation lifetime spectroscopy (PALS) indicated that the increased gas permeability of the mixed-matrix membranes is due to the free volume in the PSF polymer and the added large free volume inside the MIL-101 particles.
Journal ArticleDOI
Siloxane-based metal–organic frameworks with remarkable catalytic activity in mild environmental photodegradation of azo dyes
Carmen Racles,Mirela-Fernanda Zaltariov,Mihail Iacob,Mihaela Silion,Mihaela Avadanei,Alexandra Bargan +5 more
TL;DR: In this article, three metal-organic frameworks (MOFs) were obtained from a siloxane dicarboxylic acid (CX), 4,4′-bipyridyne (BPy) or 1,2-bis(4-pyridyl)ethylene (EBPy) and copper or cobalt acetates.
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Incorporation of In2S3 Nanoparticles into a Metal-Organic Framework for Ultrafast Removal of Hg from Water.
Linfeng Liang,Luyao Liu,Feilong Jiang,Caiping Liu,Daqiang Yuan,Qihui Chen,Dong Wu,Dong Wu,Hai-Long Jiang,Maochun Hong,Maochun Hong +10 more
TL;DR: A mild and facile method has been developed to confine ultrasmall In2S3 nanoparticles in the cavities of a MOF for the first time, which can remove 99.95% of the Hg2+ from wastewater very efficiently in as short as 1 min with the highest distribution coefficient among all MOF-based mercury adsorbents.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.