Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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A systematic study of fluorescence-based detection of nitroexplosives and other aromatics in the vapor phase by microporous metal-organic frameworks.
TL;DR: All four compounds are capable of detecting these molecules in the vapor phase through fluorescence quenching or enhancement and Interestingly, compound 3 also shows an emission frequency shift when exposed to benzene, chlorobenzene, and toluene, which provides an additional variable for the identification of different analytes in the same category.
Journal ArticleDOI
M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites
Matthew T. Kapelewski,Stephen J. Geier,Matthew R. Hudson,David Stück,Jarad A. Mason,Jocienne N. Nelson,Dianne J. Xiao,Zeric Hulvey,Zeric Hulvey,Elizabeth Gilmour,Stephen A. FitzGerald,Martin Head-Gordon,Craig M. Brown,Craig M. Brown,Jeffrey R. Long +14 more
TL;DR: A family of structural isomers of this framework, M2(m-dobdc) is reported, featuring exposed M(2+) cation sites with a higher apparent charge density, and the regioisomeric linker alters the symmetry of the ligand field at the metal sites, leading to increases of 0.4-1.5 kJ/mol in the H2 binding enthalpies relative to M2 (dobDC).
Journal ArticleDOI
Metal-organic frameworks (MOFs) and their composites as electrodes for lithium battery applications: Novel means for alternative energy storage
Vishal Shrivastav,Vishal Shrivastav,Shashank Sundriyal,Shashank Sundriyal,Priyanshu Goel,Priyanshu Goel,Harmeet Kaur,Harmeet Kaur,Satish K. Tuteja,Kumar Vikrant,Ki-Hyun Kim,Umesh Tiwari,Umesh Tiwari,Akash Deep,Akash Deep +14 more
TL;DR: In this article, the recent developments on pristine MOFs and their derived nanostructures (e.g., nanoporous carbons and metal oxides) for electrode applications are discussed in detail.
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Metal–Organic Framework@Microporous Organic Network: Hydrophobic Adsorbents with a Crystalline Inner Porosity
Jiseul Chun,Sungah Kang,Nojin Park,Eun Ji Park,Xing Jin,Kwang-Dae Kim,Hyun Ook Seo,Sang Moon Lee,Hae Jin Kim,Woo Hyun Kwon,Young-Kwon Park,Ji Man Kim,Young Dok Kim,Seung Uk Son +13 more
TL;DR: The synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water.
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Porous metal–organic frameworks for fuel storage
TL;DR: In this paper, the development history on the design and synthesis of porous metal-organic frameworks for acetylene and methane storage in which some representative examples were analyzed and discussed their adsorption mechanisms including the gas binding sites and gas-framework interactions.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.