Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Metal–Organic Frameworks for Air Purification of Toxic Chemicals
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Methane storage in advanced porous materials
TL;DR: An overview of the current status of the application of these two types of advanced porous materials in the storage of methane is provided, and methods for increasing the applicability of these advanced porous material in methane storage technologies described are described.
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Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications
TL;DR: In this review, emphasis has been placed on the design and the structural diversity of FL-MOFs and dynamic frameworks induced by flexible ligands are briefly outlined.
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Metal–Organic Frameworks for Light Harvesting and Photocatalysis
TL;DR: In this paper, the authors summarize recent progress on light harvesting and photocatalysis with metal-organic frameworks (MOFs), a new class of crystalline molecular solids built from linking organic ligands with metal or metal-cluster connecting points.
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Porous Metal–Organic Frameworks for Heterogeneous Biomimetic Catalysis
Min Zhao,Sha Ou,Chuan-De Wu +2 more
TL;DR: The immobilization of metalloporphyrin moieties onto the pore surfaces of MOFs not only prevents their suicidal self-oxidation but also allows them to activate inert substrate molecules, such as cyclohexane.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.