Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Highly water-selective hybrid membrane by incorporating g-C3N4 nanosheets into polymer matrix
Keteng Cao,Zhongyi Jiang,Zhang Xiaoshan,Yamin Zhang,Jing Zhao,Ruisi Xing,Sen Yang,Chengyun Gao,Fusheng Pan +8 more
TL;DR: In this paper, highly water-selective hybrid membranes with superior water/ethanol separation performance were fabricated by incorporating g-C3N4 nanosheets (CNs) into the SA matrix.
Journal ArticleDOI
Computational characterization and prediction of metal–organic framework properties
TL;DR: An overview of computational chemistry methods commonly used in the field of metal-organic frameworks (MOFs) to describe or predict the structures themselves and characterize their various properties, either at the quantum chemical level or through classical molecular simulation is given in this paper.
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A novel photochromic calcium-based metal-organic framework derived from a naphthalene diimide chromophore.
TL;DR: A novel 3D calcium-based metal-organic framework based on a naphthalene diimide chromophore has been synthesized which displays a unique doubly interpenetrated 7-connected net with total point symbol of {3( 6)·4(9)·5(6)}.
Journal ArticleDOI
Synthesis, functionalization, and applications of metal-organic frameworks in biomedicine.
Wei Chen,Chunsheng Wu +1 more
TL;DR: The recent progress in the synthesis, functionalization and applications of MOFs in biomedicine is outlined, mainly focusing on two promising, yet challenging areas, i.e., drug delivery and biosensing applications.
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Removal of nitroimidazole antibiotics from water by adsorption over metal-organic frameworks modified with urea or melamine
TL;DR: In this paper, the authors examined the possible applications of metal-organic frameworks (MOFs) in the purification of water contaminated with nitroimidazole antibiotics (NIABs) and found that the MOFs, especially after grafting with urea or melamine, effectively adsorbed NIABs.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.