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Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Seed-mediated growth of MOF-encapsulated Pd@Ag core–shell nanoparticles: toward advanced room temperature nanocatalysts
TL;DR: Core–shell Pd@Ag nanoparticles are formed within the pores of MOFs via a seed mediated growth strategy with activated hydrogen atoms as the reducing agent, leading to a family of bimetallic core–shell MOF nanomaterials with excelling catalytic performance in room temperature reactions.
Journal ArticleDOI
Synthesis, characterization and photocatalytic properties of MIL-53(Fe)–graphene hybrid materials
TL;DR: In this paper, a MIL-53(Fe)-reduced graphene oxide (rGO) hybrid materials with different rGO contents were prepared through a simple one-step solvothermal method.
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Functional materials from self-assembled bis-urea macrocycles.
TL;DR: The optimal design of the macrocyclic unit that leads to columnar assembly in high fidelity is examined and the feasibility of incorporating a second functional group within the macrocycles is probed to enable systematic evaluation of the effects of channel dimensions, guest dimensions, and channel-guest interactions on the processes of absorption, diffusion, and reaction of guests within these nanochannels.
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A Microporous Metal–Organic Framework with Lewis Basic Nitrogen Sites for High C2H2 Storage and Significantly Enhanced C2H2/CO2 Separation at Ambient Conditions
Hui Min Wen,Huizhen Wang,Bin Li,Yuanjing Cui,Hailong Wang,Guodong Qian,Banglin Chen,Banglin Chen +7 more
TL;DR: Owing to the combined features of high porosity, moderate pore sizes, and immobilized Lewis basic nitrogen sites, the activated ZJU-40a exhibits the second-highest gravimetric C2H2 uptake among all of the reported MOFs so far, leading to a superior MOF material for highly selective C 2H2/CO2 separation.
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Designed fabrication of biomimetic metal–organic frameworks for catalytic applications
Kai Chen,Chuan-De Wu +1 more
TL;DR: This review will selectively illustrate biomimetically MOF catalysts, consisting of immobilized biomimetic active sites on the pore surfaces or inside the p pores of porous MOFs, and the relationships between their catalytic properties and structures.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.