Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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A Robust Multifunctional Eu6-Cluster Based Framework for Gas Separation and Recognition of Small Molecules and Heavy Metal Ions
TL;DR: In this article, a multifunction lanthanide-based metal organic framework (Eu-SPFF) was constructed by a hexanuclear Eu(III) cluster and a tetracarboxylate ligand.
Journal ArticleDOI
High-temperature in situ crystallographic observation of reversible gas sorption in impermeable organic cages
Seung Bin Baek,Dohyun Moon,Robert Graf,Woo Jong Cho,Sung-Woo Park,Tae Ung Yoon,Seung Joo Cho,In-Chul Hwang,Youn Sang Bae,Hans Wolfgang Spiess,Hee Cheon Lee,Kwang S. Kim +11 more
TL;DR: It is shown that the flexible nature of the transient pathways leads to the temperature-driven reversible CO2 sorption, understanding of which can contribute to the design of a system with controlled capture/release of gas molecules.
Journal ArticleDOI
Syntheses, structures and properties of group 12 element (Zn, Cd, Hg) coordination polymers with a mixed-functional phosphonate-biphenyl-carboxylate linker
Christian Heering,Biju Francis,Bahareh Nateghi,Gamall Makhloufi,Steffen Lüdeke,Christoph Janiak +5 more
TL;DR: In this article, the coordination behavior of the carboxy-phosphonate-carboxylate ligand was studied for the group 12 elements zinc, cadmium and mercury.
Journal ArticleDOI
A Stable Amino-Functionalized Interpenetrated Metal-Organic Framework Exhibiting Gas Selectivity and Pore-Size-Dependent Catalytic Performance.
Weidong Fan,Yutong Wang,Zhenyu Xiao,Liangliang Zhang,Yaqiong Gong,Fangna Dai,Rongming Wang,Daofeng Sun +7 more
TL;DR: Gas adsorption measurements indicate that UPC-30 exhibits high H2 adsorptive heat and CO2/CH4 separation efficiency and because of the existence of -NH2 groups in the channels, U PC-30 can effectively catalyze Knoevenagel condensation reactions with high yield and pore-size-dependent selectivity.
Journal ArticleDOI
A Threefold Interpenetrated Pillared-Layer Metal–Organic Framework for Selective Separation of C2H2/CH4 and CO2/CH4
Osamah Alduhaish,Hailong Wang,Bin Li,Hadi D. Arman,Vladimir N. Nesterov,Khalid O. Al-Footy,Banglin Chen,Banglin Chen +7 more
TL;DR: The desolvated framework, UTSA-85 a, was revealed to exhibit permanent porosity with a BET surface area of 558 m2 g-1 and a high selectivity of 64 for C2 H2 /CH4 separation at 296 K owing to the microporous structure and functional azine groups that decorated the pore channels.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.