Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Elektrisch leitfähige poröse Metall-organische Gerüstverbindungen
TL;DR: In this paper, wegweisende Experimente zum elektrischen Ladungstransport and ausgewahlte Anwendungen fur diese spezielle Unterklasse von MOFs are discussed.
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Mechanochemical synthesis of metal–organic frameworks
TL;DR: In this paper, the authors summarize the typical advances in the mechanochemical synthesis of MOFs over the last two decades and present a mini review of these advances, as well as a discussion of the potential uses in gas adsorption, separation, and catalysis.
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Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework.
Xu Zhang,Xu Zhang,Libo Li,Libo Li,Jia-Xin Wang,Hui Min Wen,Rajamani Krishna,Hui Wu,Wei Zhou,Zhong-Ning Chen,Bin Li,Guodong Qian,Banglin Chen +12 more
TL;DR: The exceptional separation performance of HOF-76a for C2H6/C2H4 separation was clearly demonstrated by gas adsorption isotherms, ideal adsorbed solution theory calculations, and simulated and experimental breakthrough curves.
Journal ArticleDOI
An N-rich metal-organic framework with an rht topology: high CO2 and C2 hydrocarbons uptake and selective capture from CH4.
Kang Liu,Baiyan Li,Yi Li,Xu Li,Fen Yang,Guang Zeng,Yu Peng,Zhijuan Zhang,Guanghua Li,Zhan Shi,Shouhua Feng,Datong Song +11 more
TL;DR: Theoretical calculations reveal that s-heptazine and NH groups within the framework have synergistic effects on CO2 binding.
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Porphyrinic Silver Cluster Assembled Material for Simultaneous Capture and Photocatalysis of Mustard-Gas Simulant.
Man Cao,Rui Pang,Qian-You Wang,Zhen Han,Zhao-Yang Wang,Xi-Yan Dong,Shunfang Li,Shuang-Quan Zang,Thomas C. W. Mak,Thomas C. W. Mak +9 more
TL;DR: It is demonstrated that SCAMs offer a new route to the rational design of novel mate-rials for the detoxification of mustard gas by synergistic effects between the silver cluster and photosensitizer ligand pro-mote the efficiency of the generation of singlet oxygen (1O2), which accelerates the decontamination rate.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.