Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
About:
This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
More filters
Journal ArticleDOI
Electric field-induced assembly of monodisperse polyhedral metal-organic framework crystals
TL;DR: It is observed that well-regulated crystal orientation is observed not only for rhombic dodecahedra all of whose facets are equivalent, but also for truncated cubes with nondegenerate facets.
Journal ArticleDOI
Adsorptive denitrogenation of model fuels with porous metal-organic frameworks (MOFs): Effect of acidity and basicity of MOFs
TL;DR: In this paper, the effect of the acidity or basicity of porous metal-organic frameworks (MOFs) on the adsorptive removal of nitrogen-containing compounds (NCCs) was investigated.
Journal ArticleDOI
Microporous Metal-Organic Frameworks for Adsorptive Separation of C5-C6 Alkane Isomers
TL;DR: By applying topologically directed design strategy and precisely controlling the pore structure or ligand functionality, this Account has successfully synthesized a series of highly robust MOFs built on tetratopic carboxylate linkers that demonstrate high performance for the separation of C5-C6 alkane isomers.
Journal ArticleDOI
Crystalline Capsules: Metal–Organic Frameworks Locked by Size‐Matching Ligand Bolts
TL;DR: This proposed strategy provides a mechanical way to prevent the leaching of guests and thereby has less dependence on the specific chemical environment of the hosts, thus making it applicable for a wide variety of existing MOFs once the size-matching ligands are employed.
Journal ArticleDOI
Computational characterization and prediction of metal-organic framework properties
TL;DR: An overview of computational chemistry methods commonly used in the field of metal-organic frameworks (MOFs) to describe or predict the structures themselves and characterize their various properties, either at the quantum chemical level or through classical molecular simulation is given in this article.
References
More filters
Journal ArticleDOI
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.