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Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Composites of metal–organic frameworks and carbon-based materials: preparations, functionalities and applications
TL;DR: In this article, a review aims to specifically group together the important reports focused on MOF-carbon composites till now, and exclusively discusses the functionalities stemming from the synergistic effects of the two intriguing materials and pictures the future prospects.
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Surfactants as promising media in the field of metal-organic frameworks
TL;DR: In this article, a review offers recent developments and prospects in the surfactants as promising templates in the field of growing metal-organic frameworks (MOFs), namely, surfactant-assisted strategy for the synthesis of crystalline MOFs, the separation of the pure single-phase, the control of the pore's sizes and morphologies of MOFs (such as core/shell, nanodisks, nanoplates, nanorods, nanosheets) as well as their mechanism.
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Synergistic sorbent separation for one-step ethylene purification from a four-component mixture.
Kai-Jie Chen,David G. Madden,Soumya Mukherjee,Tony Pham,Katherine A. Forrest,Amrit Kumar,Brian Space,Jie Kong,Qiuyu Zhang,Michael J. Zaworotko +9 more
TL;DR: A synergistic sorbent separation method for the one-step production of polymer-grade C2H4 from ternary or quaternary gas mixtures with a series of physisorbents in a packed-bed geometry is introduced.
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Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs
TL;DR: In this paper, the authors summarize recent advances in the synthesis of zirconium cluster-based MOFs in the light of reticular chemistry design principles and discuss tuning of parent structures and post-synthetic modification of Zr-MOFs for targeted applications.
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Adsorption, separation, and catalytic properties of densified metal-organic frameworks
TL;DR: In this article, the properties and applications of densified metal-organic frameworks with different metal clusters and organic linkers are discussed, as well as the methods that increase the packing density in MOFs (for example, intentional interpenetration, etc.).
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.