Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Reversible adsorption and separation of volatile aromatics based on a porous Cd(II) MOF
Lei Wang,Lei Wang,Qi-Kui Liu,Chu Xin,Hong Pan,Neng-Xiu Zhu,Jian-Ping Ma,Jian-Cheng Ren,Yu-Bin Dong +8 more
TL;DR: In this paper, a series of isostructual aromatics (CdL2(OTs)2) were developed based on aromatic templates, which can reversibly adsorb benzene, toluene, o-xylene, m xylene and p xylene in the liquid phase without loss of structural integrity.
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Roles of anions in the structural diversity of Cd(II) complexes based on a V-shaped triazole-carboxylate ligand: synthesis, structure and photoluminescence properties
TL;DR: In this paper, five novel Cd(II) complexes were synthesized under hydrothermal conditions by the reaction of different CdII salts with a V-shaped, bifunctional triazole-carboxylate ligand 3-(4H-1,2,4-triazole)-4-yl)benzoic acid (3-Htba).
Journal ArticleDOI
Serrated single-wall metal–organic nanotubes (SWMONTs) for benzene adsorption
TL;DR: A self-assembled functionalized metal-organic nanotube, compound 1, has been hydrothermally synthesized using 5-(3-methyl-5-phenyl-4H-1, 2, 4-triazol-4-yl)isophthalic acid (H2L) with Zn(II) ions.
Journal ArticleDOI
Generation of 3D-Intracrystalline Diffusion Structures from a 1D/12MR HZSM-12 Zeolite: Improvements in the Catalytic Stability
TL;DR: In this paper, three-dimensional intracrystalline diffusion structures were prepared from a 1D/12MR-HZSM-12 zeolite that was desilicated with NaOH solutions at different temperatures.
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Synthesis, Crystal Structure, and Catalytic Properties of Porous 3d-4f Heterometallic Coordination Polymers Constructed from Pyrazine-2,3-dicarboxylic Acid
TL;DR: In this article, pyrazine-2,3-dicarboxylic acid (H2pzdc), cobalt nitrate and lanthanide (Ln) oxide under hydrothermal conditions result in four new 3D-4f heterometal coordination polymers, namely, [Ln2Co(pzdc)4(H2O)6]·2H 2O [ln = La (1), Pr (2), Eu (3) and Gd (4)].
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.