Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Luminescent metal–organic frameworks for chemical sensing and explosive detection
TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
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Covalent organic frameworks (COFs): from design to applications
San-Yuan Ding,Wei Wang +1 more
TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
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Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
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Water stability and adsorption in metal-organic frameworks.
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Tuning the structure and function of metal–organic frameworks via linker design
Weigang Lu,Zhangwen Wei,Zhi-Yuan Gu,Tian-Fu Liu,Jinhee Park,Jihye Park,Jian Tian,Muwei Zhang,Qiang Zhang,Thomas Gentle,Mathieu Bosch,Hong-Cai Zhou +11 more
TL;DR: This critical review of metal-organic frameworks (MOFs) highlights advances in MOF synthesis focusing on linker design and examples of building MOFs to reach unique properties, such as unprecedented surface area, pore aperture, molecular recognition, stability, and catalysis, through linkers are described.
References
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Journal ArticleDOI
Flexible metal–organic supramolecular isomers for gas separation
Motkuri Radha Kishan,Jian Tian,Praveen K. Thallapally,Carlos Fernandez,Scott J. Dalgarno,John E. Warren,B. Peter McGrail,Jerry L. Atwood +7 more
TL;DR: In this article, three interpenetrated metal-organic supramolecular isomers were synthesized using a flexible tetrahedral organic linker and Zn(2) clusters that sorb CO(2), H(2 ) and methane at room temperature.
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Separation of C5-Hydrocarbons on Microporous Materials: Complementary Performance of MOFs and Zeolites
Michael Maes,Luc Alaerts,Frederik Vermoortele,Rob Ameloot,Sarah Couck,Vincent Finsy,Joeri Denayer,Dirk De Vos +7 more
TL;DR: A flow scheme can be devised in which the C(5)-fraction can be completely separated using a combination of MOFs and zeolites, and the MOF [Cu(3)(BTC)(2)] (BTC = benzene-1,3,5-tricarboxylate) is shown to be able to separate C( 5)-olefins from paraffins.
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The Behavior of Flexible MIL-53(Al) upon CH4 and CO2 Adsorption
Anne Boutin,François-Xavier Coudert,Marie Anne Springuel-Huet,Alexander V. Neimark,Gérard Férey,Alain H. Fuchs +5 more
TL;DR: In this paper, a generic temperatureloading phase diagram has been derived; it is shown that the breathing effect in MIL-53 is a very general phenomenon, which should be observed in a limited temperature range regardless of the guest molecule.
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The nature of surface barriers on nanoporous solids explored by microimaging of transient guest distributions.
Florian Hibbe,Christian Chmelik,Lars Heinke,Sanhita Pramanik,Jing Li,Douglas M. Ruthven,Despina Tzoulaki,Jörg Kärger +7 more
TL;DR: The revealed correlation between intracrystalline diffusion and surface permeation provides a new view of the nature of transport resistances in nanoporous materials acting in addition to the diffusion resistance of the regular pore network, leading to a rational explanation of the discrepancy which is often observed between microscopic and macroscopic diffusion measurements.