Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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A novel multi-purpose Zn-MOF fluorescent sensor for 2,4-dinitrophenylhydrazine, picric acid, La3+ and Ca2+: Synthesis, structure, selectivity, sensitivity and recyclability.
TL;DR: Real-time fluorescence quenching responses and good reversibility were observed in the fluorescence titration experiments with nano-molar scale detection limits for 2,4-dinitrophenylhydrazine and picric acid and complex 1 could be a promising fluorescent sensor for explosives and metal ions.
Journal ArticleDOI
Selective molecular-gating adsorption in a novel copper-based metal-organic framework
Atsushi Kondo,Taiki Yashiro,Naoya Okada,Shotaro Hiraide,Takahiro Ohkubo,Hideki Tanaka,Kazuyuki Maeda +6 more
TL;DR: In this paper, the authors showed the successful incorporation of "molecular gates" into one dimensional (1D) pores of a novel copper-based MOF, which was formed by stacking of bumpy 2D sheets composed of Cu(I) ions and 2,4,6-tri(4-pyridyl)-1,3,5-triazine (tpt) ligands.
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A review on synthesis, crystal structure and functionality of naphthalenedicarboxylate ligated metal-organic frameworks
TL;DR: A comprehensive overview of metal-organic frameworks using Naphthalenedicarboxylate (NDC) ligands can be found in this article, where the authors provide a comprehensive insight into the design and synthesis of various MOFs using NDC ligands and their probable applications.
Journal ArticleDOI
Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization
Gervasio Gomez,María C. Bernini,Elena V. Brusau,Griselda E. Narda,Walter A. Massad,Ana Labrador +5 more
TL;DR: In this paper, the crystal structure has been solved for the Pr (1)-, Sm (3)-, and Ho (7)-containing compounds by means of single-crystal XRD methods, whereas powder XRD Rietveld refinement was used for the rest of the MOFs.
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A series of metal–organic frameworks based on a semi-rigid bifunctional ligand 5-[(1H-1,2,4-triazol-1-yl)methoxy] isophthalic acid and flexible N-donor bridging ligands
TL;DR: In this paper, the metal-organic frameworks, namely, [Co2(L)2(biim-4)(H2O)2] (1), [Mn2L]2(Biim- 4)(H 2O) 2] (2), [Ni2L 2(L 2 )2 (biim 4 ), [NiL 2 (L) 2 (BiIM-4), H2O 2 ] (3,4)-connected network with topology of (4·52)2 (54·82)(42·52
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.