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Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Three novel bismuth-based coordination polymers: Synthesis, structure and luminescent properties
TL;DR: In this paper, three bismuth-based coordination polymers, [(CH3)2NH2][Bi(pdc)(bdc)]·2DMF, [Bi(bpdc)2H2O]·xGuest (compounds 1-3), have been successfully synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction.
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Commensurate CO2 Capture, and Shape Selectivity for HCCH over H2CCH2, in Zigzag Channels of a Robust CuI(CN)(L) Metal–Organic Framework
TL;DR: 1 was investigated for shape-based selectivity of small hydrocarbons, revealing preferential uptake of linear acetylene gas over ethylene and methane, partially due to kinetic trapping of the guests with larger kinetic diameters.
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Structure-Driven Photoluminescence Enhancement in a Zn-Based Metal–Organic Framework
Stephanie Jensen,Kui Tan,William P. Lustig,Dmitri S. Kilin,Jing Li,Yves J. Chabal,Timo Thonhauser +6 more
TL;DR: In this paper, the authors investigated the mechanism that leads to an enhancement of the photoluminescence upon small aromatic molecule adsorption in the Zn-based metal-organic framework (MOF) material Zn2(bd).
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Metal ion-driven assembly of 3D coordination polymers with 5-oxyacetate isophthalic acid and 4,4′-bis(1-imidazolyl)bibenzene
Hong-Jian Cheng,Bing Wu,Lian-Wen Zhu,Chun-Yan Ni,Ming Dai,Hong-Xi Li,Zhi-Gang Ren,Jian-Ping Lang,Jian-Ping Lang +8 more
TL;DR: The results showed that metal ions did exert great influence upon the coordination modes and the geometrical conformations of ligands and the topological structures of the final products as discussed by the authors.
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Metal-Organic Frameworks for NOx Adsorption and Their Applications in Separation, Sensing, Catalysis, and Biology.
TL;DR: The different advantages of MOFs for coping with current environmental burdens and improving the habitable environment of humans on the basis of NOx adsorption are reviewed.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.