Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
Citations
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Coupling metal-organic framework nanosphere and nanobody for boosted photoelectrochemical immunoassay of Human Epididymis Protein 4.
Kaiyang Chen,Jiyang Xue,Qing Zhou,Yue Zhang,Mingming Zhang,Yuanjian Zhang,Hai Zhang,Yanfei Shen +7 more
TL;DR: The immunosensor could clearly distinguish ovarian cancer patients in different stages from healthy individuals, and the as-obtained results matched well with those by traditional electrochemiluminescence immunoassay method from the hospital.
Journal ArticleDOI
Metal-organic framework composites with luminescent pincer platinum(ii) complexes: 3MMLCT emission and photoinduced dehydrogenation catalysis.
TL;DR: Metal–organic framework materials are introduced to provide a “solid solution” environment for easy access to metal–metal-to-ligand charge transfer excited states of pincer platinum(ii) complexes and act as photocatalysts.
Journal ArticleDOI
Synthesis, structure and properties of 2D lanthanide coordination polymers based on N-heterocyclic arylpolycarboxylate ligands
Li-Xin You,Shu-Ju Wang,Shu-Ju Wang,Gang Xiong,Fu Ding,Katrien Meert,Dirk Poelman,Philippe Smet,Bao-Yi Ren,Yan-Wen Tian,Yaguang Sun +10 more
TL;DR: The reaction of 3-(2,4-dicarboxyphenyl)-2,6-pyridinedicar boxylic acid with rare earth nitrates under hydrothermal conditions generated a series of new two-dimensional (2D) coordination polymers, which exhibited frequency dependent out-of-phase signals and ferromagnetic coupling exists in 8.
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Removal of congo red from aqueous solution by its sorption onto the metal organic framework MIL-100(Fe): equilibrium, kinetic and thermodynamic studies
TL;DR: In this article, an iron-based metal organic framework (MIL-100(Fe)) with high surface area and large pore volume has been synthesized by the hydrothermal method and its capability as an efficient sorbent for congo red (CR) removal from aqueous samples has been evaluated.
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A study on high-performance composite membranes comprising heterogeneous polyamide layers on an electrospun substrate for ethanol dehydration
Wei-Song Hung,Cheng-Lee Lai,Quan-Fu An,Manuel Reyes De Guzman,Tai-Jung Shen,Yun-Hsuan Huang,Kuei-Chien Chang,Chi-Hui Tsou,Chien-Chieh Hu,Kueir-Rarn Lee +9 more
TL;DR: In this paper, a novel high-performance pervaporation membrane for ethanol dehydration through interfacial polymerization integrated with spin-coating, a method called dynamic interfacial polyamide polymerization, was fabricated.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.