Journal ArticleDOI
Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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A stable, pillar-layer metal–organic framework containing uncoordinated carboxyl groups for separation of transition metal ions
Xing Meng,Rong-Lin Zhong,Xue-Zhi Song,Shuyan Song,Zhaomin Hao,Min Zhu,Shu-Na Zhao,Hongjie Zhang +7 more
TL;DR: A 3D pillar-layer framework with uncoordinated carboxyl groups exhibits exceptional stability and can effectively and selectively adsorb Cu( 2+) ions and has been applied as a chromatographic column for separating Cu(2+)/Co(2+) ions.
Journal ArticleDOI
Heteroepitaxial growth of surface mounted metal–organic framework thin films with hybrid adsorption functionality
Min Tu,Roland A. Fischer +1 more
TL;DR: In this paper, metal-organic framework thin film heterostructures of type [Cu3btc2] on top of [Cu2ndc2dabco] were fabricated on quartz crystal microbalance substrates using a step-by-step growth approach and the resulting hybrid adsorption properties for volatile organic compounds were studied.
Journal ArticleDOI
An Anionic Interpenetrated Zeolite‐Like Metal–Organic Framework Composite As a Tunable Dual‐Emission Luminescent Switch for Detecting Volatile Organic Molecules
TL;DR: The luminescent MOF [(CH3 )2 NH2 ]2 [(Zn2 O)L]⋅5 DMF (NENU-519, NENU=Northeast Normal University) with a zeolite BCT topology was successfully synthesized and demonstrates the ability to selectively adsorb cationic dyes.
Journal ArticleDOI
High acetylene/ethylene separation in a microporous zinc(II) metal–organic framework with low binding energy
TL;DR: A novel zinc(II) metal-organic framework UTSA-67a with narrow one-dimensional pore channels and inner cages of moderate size has been developed for highly selective separation of C2H2/C2H4 mixtures at room temperature.
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Coordination polymers and metal-organic frameworks built up with poly(tetrazolate) ligands
TL;DR: In this article, the authors focus on the transition-metal-ion coordination polymers and metal-organic frameworks (MOFs) built up with bis-, tris- and tetrakis(5-substituted tetrazolate) ligands.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.