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Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Bottleneck Effect Explained by Le Bail Refinements: Structure Transformation of Mg-CUK-1 by Confining H2O Molecules
Elí Sánchez-González,J. Gabriel Flores,Julio C. Flores-Reyes,Ivette Morales-Salazar,Roberto E. Blanco-Carapia,Mónica A. Rincón-Guevara,Alejandro Islas-Jácome,Eduardo González-Zamora,Julia Aguilar-Pliego,Ilich A. Ibarra +9 more
TL;DR: A bottleneck effect was observed when one hydrogen-bonded H2O molecule per unit cell (18% relative humidity (RH) was confined within Mg-CUK-1, confirming the increase in the CO2 capture for M g-C UK-1.
Journal ArticleDOI
A Benzimidazole‐linked Porphyrin Covalent Organic Polymers as Efficient Heterogeneous Catalyst/Photocatalyst
TL;DR: In this article , the benzimidazole-linked porphyrin COPs MPp-BTA (M = 2H, Zn, Co) were synthesized using a new porphin with aldehyde group peripherally MPp and 1,2,4,5-tetraminobenzene tetrahydrochloride (BTA) as monomers.
Journal ArticleDOI
Growth of Fe-BDC Metal Organic Frameworks onto functionalized Si (111) surfaces.
Hongye Yuan,Weichu Fu,Nadia Soulmi,Christian Serre,Nathalie Steunou,Michel Rosso,C. Henry de Villeneuve +6 more
TL;DR: In this article , the growth of metal organic frameworks (MOFs) onto solid surfaces is reported, whose coverage depends on the surface chemistry and/or the solution composition of the MOFs.
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Isomerization of 1-Butene to 2-Butene Catalyzed by Metal–Organic Frameworks
Donghai Sheng,Ying Zhang,Qingxiang Song,Guang Xu,Dandan Peng,Heqian Hou,Ronggui Xie,Dongming Shan,Pengxiao Liu +8 more
TL;DR: MIL-100 and MIL-101 were synthesized and evacuated to generate a series of heterogeneous catalysts for isomerization of 1-butene as discussed by the authors, and their crystal structures and pore properties were characterized by...
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Ionic π‐Conjugated Polymer Networks by Catalyst‐Free Polymerization, Photoluminescence and Gas Sorption Behavior
TL;DR: In this article, the preparation of conjugated polyelectrolyte (CPE) networks with 4-pyridyl polyacetylene type chains and ionic alternating type chains is presented.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.