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Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks.
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This article is published in Chemical Reviews.The article was published on 2012-01-18. It has received 962 citations till now. The article focuses on the topics: Microporous material & Group 2 organometallic chemistry.read more
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Halogen Bonded Three-Dimensional Uranyl-Organic Compounds with Unprecedented Halogen-Halogen Interactions and Structure Diversity upon Variation of Halogen Substitution
TL;DR: The first case of halogen bonded three-dimensional (3D) uranyl-organic supramolecular frameworks with regular nanoscale channels has been obtained from multifunctional halogen-substituted isonicotinic acids as mentioned in this paper.
Journal ArticleDOI
Enlarging an Isoreticular Family: 3,3′,5,5′-Tetramethyl-4,4′-bipyrazolato-Based Porous Coordination Polymers
Aurel Tăbăcaru,Claudio Pettinari,Ivan Timokhin,Fabio Marchetti,Francisco Carrasco-Marín,Francisco J. Maldonado-Hódar,Simona Galli,Norberto Masciocchi +7 more
TL;DR: In this paper, the solvothermal reaction between the rigid spacer 3,3′,5, 5,5′-tetramethyl-4,4′-bipyrazole (H2Me4BPZ) and a number of transition metal salts promoted the formation of coordination polymers [M(Me4BZ)] (M = Zn, 1; Co, 2; Cd, 3; Cu, 4).
Journal ArticleDOI
A chemically stable nanoporous coordination polymer with fixed and free Cu 2+ ions for boosted C 2 H 2 /CO 2 separation
Si Chen,Nibedita Behera,Chao Yang,Qiubing Dong,Baishu Zheng,Yingying Li,Qi Tang,Zhaoxu Wang,Yanqing Wang,Jingui Duan +9 more
TL;DR: In this paper, a new nanoporous coordination polymer (PCP) with fixed and free Cu ions was prepared through post-synthetic approach via cation exchanging from the pristine NTU-66, an anionic framework with new 3, 4, 6-c topology and two kinds of cages.
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Two luminescent metal–organic frameworks with multifunctional properties for nitroaromatic compounds sensing and photocatalysis
TL;DR: In this paper, two new luminescent metal-organic frameworks (MOFs), [Zn(L)0.5(1,10-phen)(H2O)]·2H 2O (1) and [Cd(L 0.5 (1, 10-phen))·2 H2O (2), have been successfully synthesized using bis-(3,5-dicarboxyphenyl)terephthalamide(H4L) as organic linkers and 1,10phen as auxiliary ligand under solvothermal conditions
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Highly selective separation of small hydrocarbons and carbon dioxide in a metal–organic framework with open copper( ii ) coordination sites
Xing Duan,Yabing He,Yuanjing Cui,Yu Yang,Rajamani Krishna,Banglin Chen,Banglin Chen,Guodong Qian +7 more
TL;DR: The microporous metal-organic framework ZJU-25 with high density of open metal sites, has significantly better separation potential than other MOFs, ZIFs or zeolites as mentioned in this paper.
References
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Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)
TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.