Journal ArticleDOI
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
TLDR
In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.Abstract:
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.read more
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DissertationDOI
Investigations of catalyst and energy storage materials using 57Fe Mössbauer spectroscopy
TL;DR: In this article, 57Fe Mossbauer spectroscopy was employed in a collaborative effort with industrial scientists from Johnson Matthey to help develop shared understanding of a selection of industrially important materials.
Book ChapterDOI
Carbon quantum dots and its composites for electrochemical energy storage applications
TL;DR: In this article , the interesting properties of CQDs, graphene quantum dots, and the composites that help in increasing the charge storage properties are discussed, and various CQD supercapacitors and metal-ion batteries are presented with future scope.
Journal ArticleDOI
Modeling the effect of acid attack on the capacity fading in lithium-ion batteries during cycling
Vikalp Jha,Balaji Krishnamurthy +1 more
Journal ArticleDOI
Superb High-Voltage Performance of LiCoO2 with Structure and Surface Highly Stabilized by Co-Doping Trace Mg and F during One-Pot Solid-State Synthesis
Yongxin Zhang,Xinghua Tan,Luting Song,Dongdong Mao,Zhengwei Fan,Sai Su,Pian Zhang,Jianping Xie,Zhao Xia Lu,Weiguo Chu +9 more
TL;DR: In this paper , a facile solid-state reaction strategy via co-doping trace Mg and F ions using MgO and LiF sources is proposed, which achieves superb rate capability and long-term cycling stability both in half and full cells, such as a capacity of 124 mAh/g at 20 C (1 C = 280 mA/g).
Journal ArticleDOI
Recent Advances in the Electrolytes for Interfacial Stability of High‐Voltage Cathodes in Lithium‐Ion Batteries
TL;DR: In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Li-O2 and Li-S batteries with high energy storage.
Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Nam-Soon Choi,Zonghai Chen,Stefan Freunberger,Xiulei Ji,Yang-Kook Sun,Khalil Amine,Gleb Yushin,Linda F. Nazar,Jaephil Cho,Peter G. Bruce +9 more
TL;DR: The Review will consider some of the current scientific issues underpinning lithium batteries and electric double-layer capacitors.