Journal ArticleDOI
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
TLDR
In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.Abstract:
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.read more
Citations
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Journal ArticleDOI
High-voltage positive electrode materials for lithium-ion batteries
TL;DR: This review gives an account of the various emerging high-voltage positive electrode materials that have the potential to satisfy the requirements of lithium-ion batteries either in the short or long term, including nickel-rich layered oxides, lithium- rich layeredOxides, high- voltage spinel oxide compounds, and high- voltage polyanionic compounds.
Journal ArticleDOI
Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
Journal ArticleDOI
Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes I. Nickel-Rich, LiNixCoyMnzO2
Florian Schipper,Evan M. Erickson,Christoph Erk,Ji-Yong Shin,Frederick Chesneau,Doron Aurbach +5 more
Journal ArticleDOI
Review—Superconcentrated Electrolytes for Lithium Batteries
Yuki Yamada,Atsuo Yamada +1 more
Journal ArticleDOI
Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives.
Heng Zhang,Gebrekidan Gebresilassie Eshetu,Xabier Judez,Chunmei Li,Lide M. Rodriguez-Martinez,Michel Armand +5 more
TL;DR: This Review gives an overview of the various functional additives that are being applied in lithium metal rechargeable batteries and aims to stimulate new avenues for the practical realization of these appealing devices.
References
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Journal ArticleDOI
Study of the Cathode–Electrolyte Interface of LiMn1.5Ni0.5O4 Synthesized by a Sol–Gel Method for Li-Ion Batteries
TL;DR: In this article, high voltage spinel LiMn 1.5 Ni 0.5 O 4 has been synthesized by a modified Pechini sol-gel method and has been characterized by transmission electron microscopy, X-ray diffraction (XRD), and electrochemical methods.
Journal ArticleDOI
Superior Long-Term Energy Retention and Volumetric Energy Density for Li-Rich Cathode Materials
TL;DR: A novel activation method is proposed that overcomes the previous limits of Li-rich materials with large particles and may open the door to new material engineering methods for high-performance cathode materials.
Journal ArticleDOI
Impact of Lithium Bis(oxalate)borate Electrolyte Additive on the Performance of High-Voltage Spinel/Graphite Li-Ion Batteries
Nicholas P. W. Pieczonka,Li Yang,Michael P. Balogh,Bob R. Powell,Katharine R. Chemelewski,Arumugam Manthiram,Sergey A. Krachkovskiy,Gillian R. Goward,Minghong Liu,Jung-Hyun Kim +9 more
TL;DR: In this paper, the impact of LiBOB additive on the performance of full lithium-ion cells pairing the highvoltage spinel cathode with the graphite anode was systematically investigated.
Journal ArticleDOI
The study of LiNi0.5Mn1.5O4 5-V cathodes for Li-ion batteries
TL;DR: In this paper, a stable electrochemical performance and low capacity fading were found upon cycling and storage (charged state) of LiNi0.5Mn1.5O4 electrodes in DMC-EC/LiPF6 solutions at elevated temperatures (60°C).
Journal ArticleDOI
SEI layer-forming additives for LiNi0.5Mn1.5O4/graphite 5 V Li-ion batteries
TL;DR: In this paper, Succinic anhydride (SA) and 1,3-propane sultone (PS) were found to greatly extend cycle life and suppress swelling behavior of LNMO/graphite cells.