Journal ArticleDOI
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
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TLDR
In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.Abstract:
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.read more
Citations
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Journal ArticleDOI
Face to Face at the Cathode Electrolyte Interphase: From Interface Features to Interphase Formation and Dynamics
TL;DR: In this article , the formation, composition, properties, and mechanisms of the cathode electrolyte interphase (CEI) formation and function are still to a large extent unknown for most lithium-based battery materials.
Journal ArticleDOI
Influence of EDTA in poly(acrylic acid) binder for enhancing electrochemical performance and thermal stability of silicon anode
Sun-Young Lee,Yunju Choi,Kyong-Soo Hong,Jung Kyoo Lee,Ju-Young Kim,Jong-Seong Bae,Euh Duck Jeong +6 more
TL;DR: In this article, the crucial roles of ethylenediaminetetraacetic acid (EDTA) in the poly(acrylic acid) (PAA)-binder system were investigated for the high electrochemical performance silicon anode in lithium-ion batteries.
Journal ArticleDOI
The Effect of the Fluoroethylene Carbonate Additive in LiNi0.5Mn1.5O4 - Li4Ti5O12 Lithium-Ion Cells
Burak Aktekin,Reza Younesi,Wolfgang Zipprich,Carl Tengstedt,Daniel Brandell,Kristina Edström +5 more
TL;DR: The effect of the electrolyte additive fluoroethylene carbonate (FEC) for Li-ion batteries has been widely discussed in literature in recent years as mentioned in this paper, and the additive is studied for the highvoltag...
Journal ArticleDOI
Preparation of LiBOB via rheological phase method and its application to mitigate voltage fade of Li1.16[Mn0.75Ni0.25]0.84O2 cathode
Fang Lian,Yang Li,Yi He,Guan Hongyan,Kun Yan,Weihua Qiu,Kuo-Chih Chou,Peter Axmann,Margret Wohlfahrt-Mehrens +8 more
TL;DR: In this article, LiBOB was synthesized via a novel rheological phase reaction method without any recrystallization procedure, and the results of XRD, ICP, and 11B NMR demonstrate that high pure Li-BOB has been synthesized with significantly simplified synthetic process.
Journal ArticleDOI
A Comparative Review of Metal Oxide Surface Coatings on Three Families of Cathode Materials for Lithium Ion Batteries
Thabang Ronny Somo,Tumiso Eminence Mabokela,Daniel Malesela Teffu,Tshepo Kgokane Sekgobela,Brian Ramogayana,Mpitloane J. Hato,Kwena D. Modibane +6 more
TL;DR: In this article, the role and effect of metal oxides as coatings for improvement of cathode materials in Li-ion batteries is reviewed and a clear evaluation of how metal oxide coatings sweep of metal ion dissolution, phase transitions and hydrofluoric acid attacks is detailed.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
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Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Nam-Soon Choi,Zonghai Chen,Stefan Freunberger,Xiulei Ji,Yang-Kook Sun,Khalil Amine,Gleb Yushin,Linda F. Nazar,Jaephil Cho,Peter G. Bruce +9 more
TL;DR: The Review will consider some of the current scientific issues underpinning lithium batteries and electric double-layer capacitors.