Journal ArticleDOI
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
TLDR
In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.Abstract:
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.read more
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Journal ArticleDOI
Exploiting chemically and electrochemically reactive phosphite derivatives for high-voltage spinel LiNi0.5Mn1.5O4 cathodes
TL;DR: In this article, a family of organophosphorus compounds including triphenyl phosphite, trimethyl phosphite (TMP), tris 2,2,2-trifluoroethyl (TFEP), and tris(trimethylsilyl) phosphite(TMSP) were investigated as additives for the stabilization of highvoltage LiNi 0.5 Mn 1.5 O 4 (LNMO) cathode-electrolyte interface.
Journal ArticleDOI
Surface Modification of Li-Rich Mn-Based Layered Oxide Cathodes: Challenges, Materials, Methods, and Characterization
Yike Lei,Jie Ni,Zijun Hu,Ziming Wang,Fukang Gui,Bing Li,Pingwen Ming,Cunman Zhang,Yuval Elias,Doron Aurbach,Qiangfeng Xiao +10 more
Journal ArticleDOI
In situ polymerization process: an essential design tool for lithium polymer batteries
Vidyanand Vijayakumar,Vidyanand Vijayakumar,Vidyanand Vijayakumar,Bihag Anothumakkool,Sreekumar Kurungot,Martin Winter,Martin Winter,Jijeesh Ravi Nair +7 more
TL;DR: In this article, the authors focus on the in situ polymerization processes that employ various polymerization methods (e.g., free-radical polymerization, ionic polymerisation, electropolymerization, condensation polymerization etc.), functional monomers and oligomers, and PE integration strategies for the fabrication of lithium (ion and metal) polymer batteries (LIPBs and LMPBs).
Journal ArticleDOI
Advanced Lithium-Ion Batteries for Practical Applications: Technology, Development, and Future Perspectives
Sinho Choi,Guoxiu Wang +1 more
Journal ArticleDOI
Correlation between long range and local structural changes in Ni-rich layered materials during charge and discharge process
Shiyao Zheng,Chaoyu Hong,Xiaoyun Guan,Yuxuan Xiang,Xiangsi Liu,Gui-Liang Xu,Rui Liu,Guiming Zhong,Feng Zheng,Yixiao Li,Xiaoyi Zhang,Yang Ren,Zonghai Chen,Khalil Amine,Khalil Amine,Yong Yang +15 more
TL;DR: LiNi0.6Co0.1Mn0.2O2 (NCM622) and LiNi 0.8Co 0.1O2(NCM811) are investigated by C X-ray diffraction (XRD) measurement, and the relationship between structural change and capacity degradation is discussed, showing that H3 phase can be harmful for cycling.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
Electrical Energy Storage for the Grid: A Battery of Choices
TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI
Li-O2 and Li-S batteries with high energy storage.
Peter G. Bruce,Stefan Freunberger,Laurence J. Hardwick,Laurence J. Hardwick,Jean-Marie Tarascon +4 more
TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
Journal ArticleDOI
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Nam-Soon Choi,Zonghai Chen,Stefan Freunberger,Xiulei Ji,Yang-Kook Sun,Khalil Amine,Gleb Yushin,Linda F. Nazar,Jaephil Cho,Peter G. Bruce +9 more
TL;DR: The Review will consider some of the current scientific issues underpinning lithium batteries and electric double-layer capacitors.