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Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries

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TLDR
In this article, the authors describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganes oxide (NCM), spinel lithium ion ion oxide (SILO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and highvoltage solvents in high-performance cells.
Abstract
Advanced electrolytes with unique functions such as in situ formation of a stable artificial solid electrolyte interphase (SEI) layer on the anode and the cathode, and the improvement in oxidation stability of the electrolyte have recently gained recognition as a promising means for highly reliable lithium-ion batteries with high energy density. In this review, we describe several challenges for the cathode (spinel lithium manganese oxide (LMO), lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), spinel lithium manganese nickel oxide (LNMO), and lithium-rich layered oxide (Li-rich cathode))-electrolyte interfaces and highlight the recent progress in the use of oxidative additives and high-voltage solvents in high-performance cells.

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Journal ArticleDOI

A review of Ni-based layered oxides for rechargeable Li-ion batteries

TL;DR: In this paper, a review of Ni-based layered oxide materials as cathodes for high-energy Li-ion batteries is presented, including traditional stoichiometric layered compounds and those containing two lithium ions per formula unit (with potentially even higher energy density).
Journal ArticleDOI

Reviving lithium cobalt oxide-based lithium secondary batteries-toward a higher energy density

TL;DR: This review summarizes the key challenges of synthesizing L CO-based LBs with a higher energy density from the perspectives of structure and interface stability, and gives an account of effective modification strategies in view of the electrodes, liquid electrolytes, binders, separators, solid electrolytes and LCO-based full cells.
Journal ArticleDOI

Dynamic evolution of cathode electrolyte interphase (CEI) on high voltage LiCoO2 cathode and its interaction with Li anode

TL;DR: Li et al. as discussed by the authors studied the evolution of CEI layer upon charging and discharging in LiCoO2/Li battery and established a strong correlation on interface products between cathode and Li anode.
Journal ArticleDOI

High-voltage liquid electrolytes for Li batteries: progress and perspectives

TL;DR: In this article, the authors present a comprehensive and in-depth overview on the recent advances, fundamental mechanisms, scientific challenges, and design strategies for the novel high-voltage electrolyte systems, especially focused on stability issues of the electrolytes, the compatibility and interactions between electrolytes and the electrodes, and reaction mechanisms.
Journal ArticleDOI

Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes

TL;DR: In this paper, a review of recent progress in designing electrolytes for high voltage lithium ion batteries and solid state batteries is summarized, and the applications of inorganic solids, solid polymers, gel and ionic liquids in solid state electrolytes are presented.
References
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Journal ArticleDOI

Issues and challenges facing rechargeable lithium batteries

TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI

Electrical Energy Storage for the Grid: A Battery of Choices

TL;DR: The battery systems reviewed here include sodium-sulfur batteries that are commercially available for grid applications, redox-flow batteries that offer low cost, and lithium-ion batteries whose development for commercial electronics and electric vehicles is being applied to grid storage.
Journal ArticleDOI

Li-O2 and Li-S batteries with high energy storage.

TL;DR: The energy that can be stored in Li-air and Li-S cells is compared with Li-ion; the operation of the cells is discussed, as are the significant hurdles that will have to be overcome if such batteries are to succeed.
Journal ArticleDOI

Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.

TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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