Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Photochemistry of molybdenum hexacarbonyl in the gas phase
Journal ArticleDOI
Organometallic nitrosyl chemistry. 37. Synthesis, characterization, and some chemical properties of unusual 16-electron dialkyl(.eta.5-cyclopentadienyl)nitrosylmolybdenum and -tungsten complexes
TL;DR: In this article, a 16-electron dialkyl complex of molybdenum and tungsten, CpM(NO)R 2, was shown to possess a piano-stool molecular structure.
Journal ArticleDOI
Synthesis of [Mo(η-C5H4Pri)(PR3)2H3][R3= Me3 or Me2Ph), [Mo(η-C5H4Pri)(Pri2PCH2CH2PPri2)H3], and analogues and their ability to catalyse the photoinduced hydrogen–deuterium exchange of carbon–hydrogen bonds; crystal structure of [{Mo(η-C5H4Pri)(µ-Cl)2}2]
TL;DR: In this paper, the crystal structure of [Mo(ηC5H4)-(Me2PCH2CH2PMe2) H3] has been determined.
Journal ArticleDOI
Conformational Analysis of 1-Phenylethyl Substituents in Metal Complexes and Their Importance for Asymmetric Catalysis†
Journal ArticleDOI
Reaktionen an komplexgebundenen liganden
Dieter Sellmann,Ernst Thallmair +1 more
TL;DR: In this article, the stabilization of dialkylketimines with transition metal-ammonia complexes with ketones has been studied and the methods of preparation, reactions and spectroscopic properties of the complexes are reported.