Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Tetranuclear halide-alkoxide clusters of molybdenum formed by the coupling of M-M triple-bonded dinuclear compounds. Synthesis, characterization, and molecular structures of Mo4F2(O-iso-Pr)10, Mo4X3(O-iso-Pr)9, and Mo4X4(O-iso-Pr)8 (X = chloride, bromide, iodide)
Journal ArticleDOI
The reactions of an ambident lithium molybdenumvinylidene complex with electrophiles; novel formation of a 1,3-diene complex and evidence for intramolecular carbon–hydrogen activation on photolysis of a carbyne complex
TL;DR: In this paper, the reaction of Li[Mo(C·CHBut){P(OMe)3}2(η-C5H5)] with a range of electrophiles affords carbon substituted carbynes, whereas allyl iodide forms the crystallographically identified 1,3-diene complex.
Journal ArticleDOI
η3-Allyl complexes of molybdenum—IV. Preparation and crystal structures of some substituted-cyclopentadienyl molybdenum allyl derivatives
TL;DR: In this article, a series of substituted-cyclopentadienyl molybdenum allyl derivatives has been prepared by reacting (η 3 -C 3 H 5 ) 3 MoCl with substitutedcyclopentadiyl and -indenyl alkali metal salts.
Journal ArticleDOI
Rapid binding and activation of small molecules by [MoH4(Ph2PCH2CH2PPh2)2] in the presence of HBF4 · OEt2. Crystal structure of the product obtained with phenylacetylene trans-[MoF(η2-PhCCH)(Ph2PCH2CH2PPh2)2]BF4
TL;DR: In this paper, the crystal structure of the product obtained in the presence of phenylacetylene, trans-[MoF(η2-PhCCH)(Ph2PCH2CH2PPh2)2]BF4 is reported.