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Book ChapterDOI

The Organometallic and Metal-Organic Chemistry of Molybdenum

J.A. McCLEVERTY
- 01 Jan 1994 - 
- Vol. 19, Iss: 42, pp 277-402
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.

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Reference EntryDOI

Molybdenum and Molybdenum Compounds

TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI

Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.

TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article

Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]

TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI

Synthesis, crystal structures, and bonding of the molybdenum cubane compounds [Mo(µ-C5H4Pri)(µ3-S)]4n+, where n= 0, 1, and 2

TL;DR: In this article, the photoelectrom spectrum for the neutral compound, n = 0, provided a description of the bonding in the cubane system, and the compounds [Mo(η-C5H4Pri)(µ3-S)]4n+ were determined to have a cubane structure.
Journal ArticleDOI

Interconversion of oxo and imido ligands at a dimolybdenum centre: molecular and electronic structure of [{Mo(η-C5H4Me)(NPh)(µ-NPh)}2]

TL;DR: The tetraimido complexes [{Mo(η-C5H4R)(NR′)(µ-NR′)}2] have been synthesised from the corresponding oxo compounds and the aryl isocyanates R′NCO as mentioned in this paper.
Journal ArticleDOI

A new coordination mode for carbon monoxide. Synthesis and structure of Cp4Mo2Ni2S2(.eta.1,.mu.4-CO)

TL;DR: In this article, a new sulfido bimetallic cluster, Cp{sub 4}Mo{sub 2}Ni{sub 3]S{sub 6}(CO) (2), was reported, which contains an unprecedented {eta}{sup 1-, {mu}{sub 4}, {sub 6]-CO ligand, which may serve as a model of CO coordinated in the 4-fold hollows of the 110 surfaces of face-centered cubic (fcc) metals.