Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
η3-allyl complexes of molybdenum: reactions of [MoCl(η3-C3H5)3]2 and the crystal structure of [MoOAc(η3-C3H5)3]
Reinhard Benn,Sigrid Holle,Peter W. Jolly,Carl Krüger,Carlos C. Romão,Maria João Romão,Anna Rufińska,Gerhard Schroth +7 more
TL;DR: In this article, the 1H NMR spectra of tris(η3-allyl)molybdenum complexes indicate that the three allyl groups are magnetically inequivalent and asymmetrically bonded to the metal atom.
Journal ArticleDOI
Reactivity of alkynes toward M-η2-CS2 metal complexes. 3. The coupling products obtainable with bis(cyclopentadienyl)molybdenum fragments and their relative stability
Françoise Conan,Jean Sala-Pala,Jacques E. Guerchais,Jing Li,Roald Hoffmann,Carlo Mealli,R. Mercier,Loïc Toupet +7 more
Journal ArticleDOI
1,2-dimetallacyclo-1,2-hexyne compounds of molybdenum and tungsten
TL;DR: In this article, a structural model based on the observed molecular structure of 1,2-Mo2Et2(NMe2)4 was presented and compared with the observed structure of Mo2(CH2)-R2-R2(nMe2)-4 found in the solid state.
Journal ArticleDOI
The reactions of trans-[MoH4(Ph2PCH2CH2PPh2)2] with RCO2CCH (R = Me or Et) in the presence of acids. Preparation of hydrido-σ-alkenyl complexes of molybdenum(IV)
TL;DR: In this paper, the reaction of trans-[MoH4(dppe)2] (dppe = Ph2PCH2CH2PPh2) with RCO2CCH (R = Me or Et) in the presence of HBF4 in tetrahydrofuran (thf) gives the carboxylato-σ-alkenyl complexes.
Journal ArticleDOI
Reactions of hydride reagents with alkylmolybdenum carbonyl complexes. Reaction of LiBHEt3 with [MoMe(CO)3(η-C5H5)], formation of an anionic acetaldehyde complex, and a stoicheiometric cycle for the synthesis of acetaldehyde
TL;DR: In this paper, the molybdenum alkyl complex [MoMe(CO)3(η-C5H5)] reacts with LiBHEt3 in tetrahydrofuran (thf) solution at ambient temperature to give the anionic acetaldehyde complex.