Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Formation of η6-pyridine complexes of molybdenum (0) by a σ to π rearrangement in Mo(N2)2(NC5H4-4-R)(PMePh2)3, RH, Me
Robert H. Morris,Joel M. Ressner +1 more
TL;DR: The first stable η6-pyridine complexes of molybdenum were obtained in this article, where they were trans,mer-Mo(N2)2(NC5H4-4-R)(PMePh2)3, RH, Me lose dinitrogen in Vacuo at 25 °C in arene solvents.
Journal ArticleDOI
Reaction of dialkylamido and alkylimido derivatives of molybdenum and tungsten with o-arylphenols: intramolecular activation of aromatic carbon-hydrogen bonds by Mo-NR2 groups
Journal ArticleDOI
Chelate complexes containing the {Mo(NO)HB(3,5-Me2C3N2H)3} moiety and an example of a pyrazole substitution reaction involving the HB(3,5-Me2C3N2H)3 ligand
TL;DR: In this article, Toluene-3,4-dithiol (TDTH 2 ) reacts with [Mo(NO)LX 2 ] (X = OEt or I; L = HB(3,5-Me 2 C 3 N 2 H) 3 ) to produce the chelate complex [Mo{NO}L(TDT)].
Journal ArticleDOI
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]·0.5CH2Cl2and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, it was shown that the reaction between [WBr3(CO)2(η5-C5H5)] and excess of Tl(SC6F5)(CH2Cl2, 20 °C) affords Tl[W(SC 6F5)4( η5 −C5 −H5)