Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Multiple metal-carbon bonds. 34. Metathesis of acetylenes by molybdenum(VI) alkylidyne complexes
Journal ArticleDOI
Nucleophilic oxygenation of carbon dioxide by superoxide ion in aprotic media to form the peroxydicarbonate(2-) ion species
TL;DR: In this article, a combinaison de hyperoxyde avec CO 2 dans l'acetonitrile, DMF, and DMSO is described, together with an addition nucleophile avec formation du radical CO 4 −
Journal ArticleDOI
Electron-transfer catalysis. Radical chain mechanism for the ligand substitution of metal carbonyls
Journal ArticleDOI
Nackte hauptgruppenelemente als trigonal planar gebundene μ3-brückenliganden
TL;DR: In this paper, the synthesis and properties of 12 species of (LnM)2X-Hal compounds are described and the trigonally planar coordination of the bridging element X is confirmed by eight X-ray analyses.
Journal ArticleDOI
The first stable transition metal (molybdenum or tungsten) complexes having a metal–phosphorus(III) double bond: the phosphorus analogues of metal aryl- and alkyl-imides; X-ray structure of [Mo(η-C5H5)2(PAr)](Ar = C6H2But3-2,4,6)
TL;DR: Arylphosphinylidenemetal complexes [M(η-C5H5)2(PAr)][M = Mo (1) or W (2), Ar = C6H2But3-2,4,6] and an alkyl analogue as mentioned in this paper have been prepared from PCl2R′(R′= Ar or R), and show low-field 31P chemical shifts.