Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Multiple metal-carbon bonds. 34. Metathesis of acetylenes by molybdenum(VI) alkylidyne complexes
Journal ArticleDOI
A simple route to molybdenum–carbene catalysts for alkene metathesis
TL;DR: In this paper, a method for the synthesis of tetra-coordinate molybdenum-carbene complexes such as Mo(NBut)(CHBut)[OCH(CF3)2]2, which are catalytically active in alkene metathesis reactions, is reported.
Journal ArticleDOI
Metal-metal multiple bonds. Part 11. Metal-metal multiple bonds in rational cluster synthesis. Novel isomerism in iron-molybdenum-sulfur clusters and a molybdenum-sulfur cubane. Structure of (.eta.5-CH3C5H4)2Mo2Fe2(.mu.3-S)2(CO)6(.mu.-CO)2
Journal ArticleDOI
Synthesis of the WW triply bonded dimers [W2(η-C5H4R)2X4](X = Cl, R = Me or Pri; X = Br, R = Pri) and X-ray crystal structures of [W(η-C5H4Pri)Cl4] and [W2(η-C5H4Pri)2Cl4]
TL;DR: The syntheses of the WW triply bonded species [W2(η-C5H4R)2X4] and their singly bonded congeners are reported along with X-ray crystal-structure determinations of [W 2.367 8(6)A].
Journal ArticleDOI
Nucleophilic displacement at terminal chloromethylidyne ligands. New synthetic routes to organothio-, organoseleno-, and organotelluro-methylidyne and carbon monosulphide, monoselenide, and monotelluride complexes of molybdenum: X-ray crystallographic characterisation of η1-p-nitrophenylthiomethylidyne(dicarbonyl)[hydrotris(3,5-dimethylpyrazol-1-yl)borato]molybdenum(IV)
TL;DR: In this paper, nucleophilic displacement at the carbon atom of a terminal methylidyne ligand has been observed for the first time in the reaction of [Mo(η1-CCl)(CO)2(L)][L = hydrotris(3,5-dimethylpyrazol-1-yl)borato] with RE−(E = S, Se) and E2−(S, Se, Te); the products isolated include the organothiomethylidyne complex, which has been characterised by X-ray crystall