Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Transient spectroscopy and kinetics of monomeric molybdenocene Mo(η-C5H5)2 in solution
Robin N. Perutz,J. C. Scaiano +1 more
TL;DR: In this article, flash photolysis of Mo(η-C5H5)2H2 in tetrahydrofuran solution results in formation of Mo((η)-C5h5)5 )2, identified by comparison of flash and matrix spectra; it decays in ca.10 µs by reaction with Mo(−C5 h5) 2H2 or with CO.
Journal ArticleDOI
Reactions of co-ordinated ligands. XLIV: The reactivity of the carbyne complex [Mo(≡CCH2But){P(OMe)3}2(η-C5H5)] towards protonic acids, diphenylphosphine, and the π-acid tetracyanoethylene. Formation and crystal structures of [MoH(≡CCH2But){P(OMe)3}2(η-C5H5)][BF4], [Mo{σ-OC(O)CF3}{η2-HOC(O)CF3}{P(OMe)3}2(η-C5H5)], and [Mo(≡CCH2But){η2C2(CN)4}{P(OMe)3}(η-C5H5)]
Journal ArticleDOI
Stereochemically nonrigid molybdenum alkyne complexes studied by 2-dimensional NMR spectroscopy
TL;DR: In this paper, the processus d'echange intramoleculaire dans le complexe [Mo(CO) (HC≡CR) 2 (Cp)] + (R=t-Bu, Ph, CO 2 Me, Me) is studied in 2 dimensions, dans lesquelles les parametres cinetiques relatifs aux 2 rotations des groupes alcyne sont deduits des intensites des pics non diagonaux.
Journal ArticleDOI
Synthesis of (pentamethylcyclopentadienyl)nitrosylmolybdenum complexes containing halide, methyl, or cyclopentadienyl ligands. Crystal structures of [MoMe(η-C5H5)(η-C5Me5)(NO)] and [{Mo(η-C5Me5)O(µ-O)}2]
Ernesto de Jesús,Amelio Vázquez de Miguel,Pascual Royo,Anna Maria Manotti Lanfredi,Antonio Tiripicchio +4 more
TL;DR: In this paper, the structure of the first crystal examined (B) contained (7) and the oxo complex trans-[{Mo(η-C5Me5)O(µ-O)}2](8) in an ordered mixture with a 2:1 molar ratio.
Journal ArticleDOI
Some New Cyano and isonitrile complexes of Mo(η5-C5H5)2
TL;DR: In this paper, new cyano and isonitrile complexes of molybdenocene, [MoCp2(CN)X] (X = CN, H, Cl, Cl), [MoCl2Cl2] with Na/Hg or from MoCl2H]I with NaH.