Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Trimethylenemethane Complexes of Cr, Mo, and W by Novel Methylenation of Allenes with Carbene Complexes; Cyclopentanes by [3+2] Cycloaddition of Trimethylenemethane Complexes to Allenes
Rudolf Aumann,Jürgen Uphoff +1 more
Journal ArticleDOI
Hexakis(trimethylphosphine)molybdenum chemistry: dinitrogen, ethylene, butadiene, η-cyclopentadienyl, and related derivatives
Maurice Brookhart,Kevin P. Cox,F. Geoffrey N. Cloke,Jennifer C. Green,Malcolm L. H. Green,Philip M. Hare,James K. Bashkin,Andrew E. Derome,Peter D. Grebenik +8 more
TL;DR: In this article, the rate constants and activation parameters for the hydrogen-scrambling process have been determined and a mechanism is proposed and the presence of the Mo-H-C bond is shown by low-temperature n.m. spectra.
Journal ArticleDOI
Photochemical isomerization of [Cp*MoS(.mu.-S)]2 (Cp* = .eta.5-(Me)5C5) to Cp*Mo4(.mu.-S2)(.mu.-S)2 and [Cp*MoS]2(.mu.-S2)
Alice E. Bruce,David R. Tyler +1 more
TL;DR: Determination de la sequence des reactions d'isomerisation entre les trois composes du titre is discussed in this paper, where the authors define the sequence of reactions.
Journal ArticleDOI
Facile synthesis of Cp2Mo2(.mu.-SH)2(.mu.-S)2 and its use in heterobimetallic cluster synthesis
Journal ArticleDOI
Koordinationschemie reduzierter N‐Heterocyclen. Zweikernige Pentacarbonyl‐Komplexe des Molybdäns und Wolframs mit paramagnetischen Brückenliganden
TL;DR: In this paper, the metal carbonyl coordination is established by high resolution ESR spectroscopy, satellite lines caused by the isotopes 95,97Mo, 183W, and 13C(CO) are observed.