Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Reactions of metallabromoalkanes [M{(CH2)nBr}(CO)3(η-C5H5)](M = Mo or W, n= 3 or 4) with transition metal anions. Dimetalla-alkane and cyclic carbene complex formation. Crystal and molecular structures of [(η-C5H5)(OC)3Mo{(CH2)4}Mo(CO)3(η-C5H5)] and [(η-C5H5)(OC)3MoW(CO)2{C–O–(CH2)2CH2}(η-C5H5)]
TL;DR: In this article, a cyclic carbene ligand was formed via the intermediate [Mo{(C5H5)(OC)3MoMoMo(CO)2{[graphic omitted]H2}(η-C 5H5)] using Br[CH2]3Br with excess [Mo[CO)3Br] with [W(CO]3
Journal ArticleDOI
Cyclic carbene complexes of molybdenum and tungsten. Crystal and molecular structure of [Mol(CO)2{CO(CH2)2CH2}(η-C5H5)]
Neil A. Bailey,Paul L. Chell,Christopher P. Manuel,Anuradha Mukhopadhyay,Deborah Rogers,Helen E. Tabbron,Mark J. Winter +6 more
TL;DR: The cyclic carbene complex [Mol(CO)2{[graphic omitted]H2}(η-C5H5)] is formed during reaction of [Mo(CO), H2, H3, H4R] with I[CH2]3l or [Mo{(CH2)3Br}(CO, H2), H4, H5H4R) with Lil as discussed by the authors.
Journal ArticleDOI
Highly reduced organometallics: XI. Formal derivatives of the tricarbonylmetallates (6-) of chromium, molybdenum and tungsten
Gary L. Rochfort,John E. Ellis +1 more
TL;DR: In this paper, the first triphenyltin derivatives with more than three tricarbonyl units attached to one transition metal were described. But these compounds were derived from a single transition metal.
Journal ArticleDOI
Nitrosyl complexes of molybdenum and tungsten. Part 17. Hydrazido(1–) complexes of [tris(3,5-dimethylpyrazolyl)borato]molybdenum, related tungsten compounds, and the structures of NN-dimethylhydrazido(1–)- and N-methyl-N-phenylhydrazido(1–)iodo(nitrosyl)[tris(3,5-dimethylpyrazol-1-yl)borato]molybdenum
TL;DR: In this article, the preparation of the compounds [Mo{HB(Me2pz)3}(NO)I(NHNRR′)](Me 2pz = 3,5-dimethylpyrazolyl; R = R′= H or Me; R= H,R′= Me or Ph; R
Journal ArticleDOI
UV photoelectron spectral and theoretical studies on tris(butadiene)-molybdenum and -tungsten
Jennifer C. Green,M.Ruth Kelly,Peter D. Grebenik,Clive E. Briant,Neil A. McEvoy,D. Michael P. Mingos +5 more
TL;DR: In this paper, the UV photoelectron spectra of tris(butadiene)molybdenum and -tungsten have been recorded and assigned with the assistance of extended Huckel molecular orbital calculations.