Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Arsenic-sulfur heterocycle formation via metal coordination. Synthesis and molecular structure of cyclo-(CH3AsS)n (n = 3, 4), [(CO)3Mo][.eta.3-cyclo-(CH3As)6S3], and the triple-decker-sandwich complex [.eta.5-(C5H5)2Mo2(.eta.2,.mu.-As3)(.eta.2,.mu.-AsS)]
Journal ArticleDOI
Olefin isomerization catalysis by heterobimetallic hydrides, HFeM(CO)8L− (M=Cr, Mo, W; L=CO, PR3)
Journal ArticleDOI
Organotransition-metal complexes of multidentate ligands. 10. Steric vs. electronic control on formation of six- and seven-coordinate carbonyl halides of molybdenum(II) and tungsten(II)
Journal ArticleDOI
Reaktion der schwefelreichen komplexe (C5Me5)2Mo2S4 und (C5Me5)2Cr2S5 mit der M-M-dreifachbindung der komplexe [η5-C5R5(CO)2M′]2 (R = H, CH3; M′ = Cr, Mo, W) zu drei- und vierkernclustern mit M3S4- BZW. M4S4-gerüst
TL;DR: In this article, the cuban-like diamagnetic clusters (C 5 Me 5 ) 3 Mo 2 M′S 4 ) were synthesized by photolysing and the results showed that they can be obtained in high yields in boiling toluene.
Journal ArticleDOI
Synthesis of bis(.eta.6-2,6-dimethylpyridine)metal complexes of titanium, molybdenum, and vanadium by metal vapor deposition. Spectral properties of bis(.eta.6-2,6-dimethylpyridine)metal complexes of chromium, titanium, vanadium, molybdenum, and chromium(1+)
TL;DR: Synthese par cocondensation atome metallique. Coordinat et reactions redox. Spectres IR, RMN, RPE et UV-visible as mentioned in this paper.