Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
High yield synthesis of arylphosphine molybdenum complex Mo(.eta.6-PhPMe2)(PMe2Ph)3 and its dimerization to form {Mo(.mu.-.eta.1,.eta.6-PMe2Ph)(PMe2Ph)2}2, a complex characterized by x-ray crystallography
Journal ArticleDOI
Reaction of polynuclear acetylide clusters. Synthesis of pentanuclear heterometallic clusters by addition of [M(CO)3(CCPh)(η-C5H5)] to [MOs3(CO)11(CCPh)(η-C5H5)](M = Mo or W). Crystal structures of [Mo2Os3(CO)11(CCPhCCPh)(η-C5H5)2]·2H2O and [MoWOs3(CO)8(µ4-C)-(µ3-CPh)(CCPh)(η-C5H5)2]·CH2Cl2
TL;DR: In this paper, a planar pentanuclear complex was derived from head-to-tail coupling between the two acetylide fragments, and the structure of the complex was determined by single-crystal X-ray diffraction studies.
Journal ArticleDOI
Zur synthese von tetramesitylmolybdän-verbindungen
W. Seidel,I. Bürger +1 more
TL;DR: Zusammenfassung Molybdenum trichloride reacts with mesityllithium in THF forming LiMo(C 9 H 11 ) 4 (THF) 4.