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Journal ArticleDOI

Ultra-low power, highly uniform polymer memory by inserted multilayer graphene electrode

TLDR
In this paper, a multilayer graphene (MLG) was inserted at the electrode/polymer interface to improve the resistive switching uniformity and reduce the power consumption.
Abstract
Filament type resistive random access memory (RRAM) based on polymer thin films is a promising device for next generation, flexible nonvolatile memory. However, the resistive switching nonuniformity and the high power consumption found in the general filament type RRAM devices present critical issues for practical memory applications. Here, we introduce a novel approach not only to reduce the power consumption but also to improve the resistive switching uniformity in RRAM devices based on poly(1,3,5-trimethyl-3,4,5-trivinyl cyclotrisiloxane) by inserting multilayer graphene (MLG) at the electrode/polymer interface. The resistive switching uniformity was thereby significantly improved, and the power consumption was markedly reduced by 250 times. Furthermore, the inserted MLG film enabled a transition of the resistive switching operation from unipolar resistive switching to bipolar resistive switching and induced self-compliance behavior. The findings of this study can pave the way toward a new area of application for graphene in electronic devices.

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Citations
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Journal ArticleDOI

Resistive Switching Performance Improvement via Modulating Nanoscale Conductive Filament, Involving the Application of Two-Dimensional Layered Materials.

TL;DR: Two-dimensional nanomaterials with excellent properties including and beyond graphene, are discussed with emphasis on performance improvement by their active roles as the switching layer, insertion layer, thin electrode, patterned electrode, and edge electrode.
Journal ArticleDOI

Decade of 2D-materials-based RRAM devices: a review.

TL;DR: Most prominent advantages offered by RRAM devices based on 2D materials include fast switching speed, less power losses, lower threshold voltage, long retention time, high electrical endurance and extended mechanical robustness.
Journal ArticleDOI

Flexible Nonvolatile Polymer Memory Array on Plastic Substrate via Initiated Chemical Vapor Deposition.

TL;DR: The pV3D3-RRAM arrays fabricated via the solvent-free technique called initiated chemical vapor deposition (iCVD) process for flexible memory application showed unipolar resistive switching memory with an on/off ratio of over 10(7), stable retention time for 10(5) s, excellent cycling endurance over 10 (5) cycles, and robust immunity to mechanical stress.
Journal ArticleDOI

Highly improved performance in Zr0.5Hf0.5O2 films inserted with graphene oxide quantum dots layer for resistive switching non-volatile memory

TL;DR: In this article, a novel approach to resolve the problem of random nature of the nucleation and growth of the conductive filaments (CFs) caused instability of the switching parameter, which is a major obstacle for RRAM performance improvement, was proposed by inserting graphene oxide quantum dots (GOQDs) in Zr0.5Hf0.2 (ZHO) films.
References
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Journal ArticleDOI

Reliable Control of Filament Formation in Resistive Memories by Self-Assembled Nanoinsulators Derived from a Block Copolymer

TL;DR: This work presents an innovative approach to reliably and reproducibly control the CF growth in unipolar NiO resistive memory by exploiting uniform formation of insulating SiOx nanostructures from the self-assembly of a Si-containing block copolymer.
Journal ArticleDOI

Graphene as an atomically thin barrier to Cu diffusion into Si.

TL;DR: The time-dependent dielectric breakdown (TDDB) test is used to evaluate graphene as a Cu diffusion barrier under real device operating conditions, revealing that both large- grain SLG and MLG have excellent barrier performance, while small-grain SLG fails quickly.
Journal ArticleDOI

Highly Uniform, Self-Compliance, and Forming-Free ALD $\hbox{HfO}_{2}$ -Based RRAM With Ge Doping

TL;DR: In this paper, an atomic layer deposited (ALD) HfO2 resistive-switching random access memory devices with high uniformity, self-compliance, and forming-free behavior are demonstrated.
Journal ArticleDOI

A facile route to recover intrinsic graphene over large scale.

TL;DR: Graphene field effect transistors subsequently exposed to air, became p-type doped due to recovery of the H(2)O/O( 2) redox system, and poly(methyl methacrylate) (PMMA)-coated graphene FETs had improved stability for maintaining the intrinsic graphene electronic properties.
Journal ArticleDOI

Comprehensive modeling of resistive switching in the Al/TiOx/TiO2/Al heterostructure based on space-charge-limited conduction

TL;DR: In this article, the authors investigated the reversible resistance switching (RS) effect of the Al/TiOx/TiO2/Al heterostructure and attributed it to space-charge-limited conduction (SCLC) as controlled by localized traps in the TiOx layer.
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