University of Nevada, Reno

About: University of Nevada, Reno is a education organization based out in Reno, Nevada, United States. It is known for research contribution in the topics: Population & Poison control. The organization has 13561 authors who have published 28217 publications receiving 882002 citations. The organization is also known as: University of Nevada & Nevada State University.

Gas-particle partitioning of atmospheric Hg(II) and its effect on global mercury deposition

Abstract: Atmospheric deposition of Hg(II) represents a major input of mercury to surface environments. The phase of Hg(II) (gas or particle) has important implications for deposition. We use long-term observations of reactive gaseous mercury (RGM, the gaseous component of Hg(II)), particle-bound mercury (PBM, the particulate component of Hg(II)), fine particulate matter (PM 2.5), and temperature (T ) at five sites in North America to derive an empirical gas-particle partitioning relationship log 10(K 1 ) = (10±1)- (2500±300)/T where K = (PBM/PM2.5)/RGM with PBM and RGM in common mixing ratio units, PM2.5 in µg m 3 , and T in K. This relationship is within the range of previ- ous work but is based on far more extensive data from mul- tiple sites. We implement this empirical relationship in the GEOS-Chem global 3-D Hg model to partition Hg(II) be- tween the gas and particle phases. The resulting gas-phase fraction of Hg(II) ranges from over 90 % in warm air with lit- tle aerosol to less than 10 % in cold air with high aerosol. Hg deposition to high latitudes increases because of more effi- cient scavenging of particulate Hg(II) by precipitating snow. Model comparison to Hg observations at the North Ameri- can surface sites suggests that subsidence from the free tro- posphere (warm air, low aerosol) is a major factor driving the seasonality of RGM, while elevated PBM is mostly associ- ated with high aerosol loads. Simulation of RGM and PBM at these sites is improved by including fast in-plume reduc- tion of Hg(II) emitted from coal combustion and by assum- ing that anthropogenic particulate Hg(p) behaves as semi- volatile Hg(II) rather than as a refractory particulate compo- nent. We improve the simulation of Hg wet deposition fluxes in the US relative to a previous version of GEOS-Chem; this largely reflects independent improvement of the washout al- gorithm. The observed wintertime minimum in wet depo- sition fluxes is attributed to inefficient snow scavenging of gas-phase Hg(II).

Plants, symbiosis and parasites: a calcium signalling connection

Abstract: A unique family of protein kinases has evolved with regulatory domains containing sequences that are related to Ca(2+)-binding EF-hands. In this family, the archetypal Ca(2+)-dependent protein kinases (CDPKs) have been found in plants and some protists, including the malarial parasite, Plasmodium falciparum. Recent genetic evidence has revealed isoform-specific functions for a CDPK that is essential for Plasmodium berghei gametogenesis, and for a related chimeric Ca(2+) and calmodulin-dependent protein kinase (CCaMK) that is essential to the formation of symbiotic nitrogen-fixing nodules in plants. In Arabidopsis thaliana, the analysis of 42 isoforms of CDPK and related kinases is expected to delineate Ca(2+) signalling pathways in all aspects of plant biology.

A higher-than-predicted measurement of iron opacity at solar interior temperatures.

Abstract: Laboratory measurements of iron opacity made under conditions similar to those inside the Sun reveal much higher opacity than predicted, helping to resolve inconsistencies within stellar models of the internal temperatures of stars. Internal temperature profiles of the Sun and other stars are controlled in large part by the rate at which radiation is absorbed by stellar matter. Until now it has not been possible to determine the opacity of matter in star-like conditions in the laboratory, but James Bailey et al. have now achieved that feat using the Sandia National Laboratories' Z facility, the world's most powerful X-ray generator. The experiments reveal a wavelength-resolved iron opacity that is 30 to 400 times greater than predicted in conditions very similar to those at the radiation/convection zone boundary in the Sun. Previous measurements of stellar interiors have been based on observations of surface waves, and there were serious discrepancies between theoretical predictions and observations. The new measurements account for about half of adjustment in opacity figures required to restore agreement between standard solar models and observations. Nearly a century ago it was recognized1 that radiation absorption by stellar matter controls the internal temperature profiles within stars. Laboratory opacity measurements, however, have never been performed at stellar interior conditions, introducing uncertainties in stellar models2,3,4,5. A particular problem arose2,3,6,7,8 when refined photosphere spectral analysis9,10 led to reductions of 30–50 per cent in the inferred amounts of carbon, nitrogen and oxygen in the Sun. Standard solar models11 using the revised element abundances disagree with helioseismic observations that determine the internal solar structure using acoustic oscillations. This could be resolved if the true mean opacity for the solar interior matter were roughly 15 per cent higher than predicted2,3,6,7,8, because increased opacity compensates for the decreased element abundances. Iron accounts for a quarter of the total opacity2,12 at the solar radiation/convection zone boundary. Here we report measurements of wavelength-resolved iron opacity at electron temperatures of 1.9–2.3 million kelvin and electron densities of (0.7–4.0) × 1022 per cubic centimetre, conditions very similar to those in the solar region that affects the discrepancy the most: the radiation/convection zone boundary. The measured wavelength-dependent opacity is 30–400 per cent higher than predicted. This represents roughly half the change in the mean opacity needed to resolve the solar discrepancy, even though iron is only one of many elements that contribute to opacity.

A Reservoir of Nitrate Beneath Desert Soils

Abstract: A large reservoir of bioavailable nitrogen (up to approximately 10(4) kilograms of nitrogen per hectare, as nitrate) has been previously overlooked in studies of global nitrogen distribution. The reservoir has been accumulating in subsoil zones of arid regions throughout the Holocene. Consideration of the subsoil reservoir raises estimates of vadose-zone nitrogen inventories by 14 to 71% for warm deserts and arid shrublands worldwide and by 3 to 16% globally. Subsoil nitrate accumulation indicates long-term leaching from desert soils, impelling further evaluation of nutrient dynamics in xeric ecosystems. Evidence that subsoil accumulations are readily mobilized raises concern about groundwater contamination after land-use or climate change.