Showing papers on "Terahertz radiation published in 2006"

Dynamical electric and magnetic metamaterial response at terahertz frequencies.

Abstract: Utilizing terahertz time domain spectroscopy, we have characterized the electromagnetic response of a planar array of split ring resonators (SRRs) fabricated upon a high resistivity GaAs substrate. The measured frequency dependent magnetic and electric resonances are in excellent agreement with theory and simulation. For two polarizations, the SRRs yield a negative electric response ($ϵl0$). We demonstrate, for the first time, dynamical control of the electrical response of the SRRs through photoexcitation of free carriers in the substrate. An excited carrier density of $\ensuremath{\sim}4\ifmmode\times\else\texttimes\fi{}{10}^{16}\text{ }\text{ }{\mathrm{cm}}^{\ensuremath{-}3}$ is sufficient to short the gap of the SRRs, thereby turning off the electric resonance, demonstrating the potential of such structures as terahertz switches. Because of the universality of metamaterial response over many decades of frequency, these results have implications for other regions of the electromagnetic spectrum.

Terahertz surface plasmon-polariton propagation and focusing on periodically corrugated metal wires

Abstract: In this Letter, we show how the dispersion relation of surface plasmon polaritons (SPPs) propagating along a perfectly conducting wire can be tailored by corrugating its surface with a periodic array of radial grooves. In this way, highly localized SPPs can be sustained in the terahertz region of the electromagnetic spectrum. Importantly, the propagation characteristics of these spoof SPPs can be controlled by the surface geometry, opening the way to important applications such as energy concentration on cylindrical wires and superfocusing using conical structures.

Biomedical applications of terahertz technology

Abstract: We review the development of terahertz (THz) technology and describe a typical system used in biomedical applications. By considering where the THz regime lies in the electromagnetic spectrum, we see that THz radiation predominantly excites vibrational modes that are present in water. Thus, water absorption dominates spectroscopy and imaging of soft tissues. However, there are advantages of THz methods that make it attractive for pharmaceutical and clinical applications. In this review, we consider applications ranging from THz spectroscopy of crystalline drugs to THz imaging of skin cancer.

Coherent Control of THz Wave Generation in Ambient Air

Abstract: Our study of THz wave generation in the pulsed laser induced air plasma with individually controlled phase, polarization, and amplitude of the optical fundamental wave (omega) and its second harmonic (2omega) indicates that the third-order nonlinear optical process mixing the omega and 2omega beams in the ionized plasma is the main mechanism of the efficient THz wave generation. The polarity and the strength of the emitted THz field are completely controlled by the relative phase between the omega and 2omega waves. The measured THz field amplitude is proportional to the pulse energy of the fundamental beam and to the square root of the pulse energy of the second-harmonic beam once the total optical pulse energy exceeds the plasma formation threshold. The optimal THz field is achieved when all waves (omega, 2omega, and THz waves) are at the same polarization in the four-wave-mixing process.

Terahertz dielectric properties of polymers

Abstract: The terahertz dielectric properties of polymers were characterized by transmission terahertz time domain spectroscopy (THz-TDS) in the frequency range extending from 0.2 to 3.0 THz. The terahertz absorption spectra, the refractive indices and the dielectric functions of various polymer materials were measured and compared. The variation of the refractive index of the polymers was less than 6 %, ranging from 1.4 to 1.8, within the investigated frequency range, but the absorption properties of the polymers showed very different frequency-dependent behaviors. The loss mechanism for terahertz radiation in polymers is discussed by correlating the absorption coefficients and the loss tangents (tan {delta}) of the materials.

Detection of broadband terahertz waves with a laser-induced plasma in gases.

Abstract: We report the experimental results and theoretical analysis of broadband detection of terahertz (THz) waves via electric-field-induced second-harmonic generation in laser-induced air plasma with ultrashort laser pulses. By introducing the second-harmonic component of the white light in the laser-induced plasma as a local oscillator, coherent detection of broadband THz waves with ambient air is demonstrated for the first time. Our results show that, depending on the probe intensity, detection of THz waves in air can be categorized as incoherent, hybrid, and coherent detection. Coherent detection is achieved only when the tunnel ionization process dominates in gases.

Dispersion of surface plasmon polaritons on metal wires in the terahertz frequency range.

Abstract: We report the experimental and theoretical study of the dispersive behavior of surface plasmon polaritons (SPPs) on cylindrical metal surfaces in the terahertz frequency range. Time-domain measurements of terahertz SPPs propagating on metal wires reveal a unique structure that is inconsistent with a simple extrapolation of the high frequency portion of the dispersion diagram for SPPs on a planar metal surface, and also distinct from that of SPPs on metal nanowires observed at visible and near-infrared frequencies. The results are consistent with a numerical solution of Maxwell's equations, showing that the dispersive behavior of SPPs on a cylindrical metal surface at terahertz frequencies is quite different from that of SPPs on a flat surface. These findings indicate the increasing importance of skin effects for SPPs in the terahertz range, as well as the enhancement of such effects on curved surfaces.

Negative index materials using simple short wire pairs

Abstract: Negative refraction is currently achieved by a combination of artificial ``electric atoms'' (metallic wires with negative electrical permittivity $\ensuremath{\epsilon}$) and artificial ``magnetic atoms'' (split-ring resonators with negative magnetic permeability $\ensuremath{\mu}$). Both $\ensuremath{\epsilon}$ and $\ensuremath{\mu}$ must be negative at the same frequency, which is not easy to achieve at higher than THz frequencies. We introduce improved and simplified structures made of periodic arrays of pairs of short metal wires and continuous wires that offer a potentially simpler approach to building negative index materials. Using simulations and microwave experiments, we have investigated the negative index $n$ properties of short wire-pair structures. We have measured experimentally both the transmittance and the reflectance properties and found unambiguously that $nl0$. The same is true for $\ensuremath{\epsilon}$ and $\ensuremath{\mu}$. Our results show that short wire-pair arrays can be used very effectively in producing materials with negative refractive indices.

Solute-induced retardation of water dynamics probed directly by terahertz spectroscopy

Abstract: The dynamics of water surrounding a solute is of fundamental importance in chemistry and biology. The properties of water molecules near the surface of a bio-molecule have been the subject of numerous, sometimes controversial experimental and theoretical studies, with some suggesting the existence of rather rigid water structures around carbohydrates and proteins [Pal, S. K., Peon, J., Bagchi, B. & Zewail A. H. (2002) J. Phys. Chem. B 106, 12376–12395]. Hydrogen bond rearrangement in water occurs on the picosecond time scale, so relevant experiments must access these times. Here, we show that terahertz spectroscopy can directly investigate hydration layers. By a precise measurement of absorption coefficients between 2.3 THz and 2.9 THz we could determine the size and the characteristics of the hydration shell. The hydration layer around a carbohydrate (lactose) is determined to extend to 5.13 ± 0.24 A from the surface corresponding to ≈123 water molecules beyond the first solvation shell. Accompanying molecular modeling calculations support this result and provide a microscopic visualization. Terahertz spectroscopy is shown to probe the collective modes in the water network. The observed increase of the terahertz absorption of the water in the hydration layer is explained in terms of coherent oscillations of the hydration water and solute. Simulations also reveal a slowing down of the hydrogen bond rearrangement dynamics for water molecules near lactose, which occur on the picosecond time scale. The present study demonstrates that terahertz spectroscopy is a sensitive tool to detect solute-induced changes in the water network.

Single-wire transmission lines at terahertz frequencies

Abstract: In this paper, we report results on an original way to excite surface waves on a single-wire transmission line. Although these waves were proposed many decades ago by Goubau, the novelty of our structures is to achieve a broadband planar excitement. This configuration is very well suited for the terahertz frequency range and allows the investigation of biological entities with high spatial resolution with the use of novel biomicroelectromechanical systems, which include microfluidic functions. From experimental results, we compare different types of transitions from coplanar waveguides, and different substrates are also used. We show that the excitation is highly efficient and broadband for structures on a quartz substrate

Generation of terahertz pulses through optical rectification in organic DAST crystals: theory and experiment

Abstract: We present a combined theoretical and experimental investigation of the generation of few-cycle terahertz (THz) pulses via the nonlinear effect of optical rectification and of their coherent detection via electro-optic sampling. The effects of dispersive velocity matching, absorption of the optical and the THz waves, crystal thickness, pulse diameter, pump pulse duration, and two-photon absorption are discussed. The theoretical calculations are compared with the measured spectra of THz pulses that have been generated and detected in crystals of the highly nonlinear organic salt 4-N,N-dimethylamino-4′-N′-methyl stilbazolium tosylate (DAST). The results are found to be in agreement with the theory. By the selection of the optical pump wavelength between 700 and 1600 nm, we achieved several maxima of the overall generation and detection efficiency in the spectral range between 0.4 and 6.7 THz, with an optimum at 2 THz generated with 1500 nm laser pulses.

Conductivity of ZnO nanowires, nanoparticles, and thin films using time-resolved terahertz spectroscopy

Abstract: The terahertz absorption coefficient, index of refraction, and conductivity of nanostructured ZnO have been determined using time-resolved terahertz spectroscopy, a noncontact optical probe. ZnO properties were measured directly for thin films and were extracted from measurements of nanowire arrays and mesoporous nanoparticle films by applying Bruggeman effective medium theory to the composite samples. Annealing significantly reduces the intrinsic carrier concentration in the ZnO films and nanowires, which were grown by chemical bath deposition. The complex-valued, frequency-dependent photoconductivities for all morphologies were found to be similar at short pump-probe delay times. Fits using the Drude-Smith model show that films have the highest mobility, followed by nanowires and then nanoparticles, and that annealing the ZnO increases its mobility. Time constants for decay of photoinjected electron density in films are twice as long as those in nanowires and more than 5 times those for nanoparticles due to increased electron interaction with interfaces and grain boundaries in the smaller-grained materials. Implications for electron transport in dye-sensitized solar cells are discussed.

Plasma wave detection of terahertz radiation by silicon field effects transistors: Responsivity and noise equivalent power

Abstract: Si metal oxide semiconductor field effect transistors (MOSFETs) with the gate lengths of 120–300nm have been studied as room temperature plasma wave detectors of 0.7THz electromagnetic radiation. In agreement with the plasma wave detection theory, the response was found to depend on the gate length and the gate bias. The obtained values of responsivity (⩽200V∕W) and noise equivalent power (⩾10−10W∕Hz0.5) demonstrate the potential of Si MOSFETs as sensitive detectors of terahertz radiation.

Real-time, continuous-wave terahertz imaging using a microbolometer focal-plane array

Abstract: The present invention generally provides a terahertz (THz) imaging system that includes a source for generating radiation (e.g., a quantum cascade laser) having one or more frequencies in a range of about 0.1 THz to about 10 THz, and a two-dimensional detector array comprising a plurality of radiation detecting elements that are capable of detecting radiation in that frequency range. An optical system directs radiation from the source to an object to be imaged. The detector array detects at least a portion of the radiation transmitted through the object (or reflected by the object) so as to form a THz image of that object.

Low-loss subwavelength plastic fiber for terahertz waveguiding.

Abstract: We report a simple subwavelength-diameter plastic wire, similar to an optical fiber, for guiding a terahertz wave with a low attenuation constant. With a large wavelength-to-fiber-core ratio, the fractional power delivered inside the lossy core is reduced, thus lowering the effective fiber attenuation constant. In our experiment we adopt a polyethylene fiber with a 200 µm diameter for guiding terahertz waves in the frequency range near 0.3 THz in which the attenuation constant is reduced to of the order of or less than 0.01 cm−1. Direct free-space coupling efficiency as high as 20% can be achieved by use of an off-axis parabolic mirror. Furthermore, all the plastic wires are readily available, with no need for complex or expensive fabrication.

Terahertz all-optical modulation in a silicon–polymer hybrid system

Abstract: Although gigahertz-scale free-carrier modulators have been demonstrated in silicon, intensity modulators operating at terahertz speeds have not been reported because of silicon's weak ultrafast nonlinearity. We have demonstrated intensity modulation of light with light in a silicon–polymer waveguide device, based on the all-optical Kerr effect—the ultrafast effect used in four-wave mixing. Direct measurements of time-domain intensity modulation are made at speeds of 10 GHz. We showed experimentally that the mechanism of this modulation is ultrafast through spectral measurements, and that intensity modulation at frequencies in excess of 1 THz can be obtained. By integrating optical polymers through evanescent coupling to silicon waveguides, we greatly increase the effective nonlinearity of the waveguide, allowing operation at continuous-wave power levels compatible with telecommunication systems. These devices are a first step in the development of large-scale integrated ultrafast optical logic in silicon, and are two orders of magnitude faster than previously reported silicon devices.

Real-time terahertz imaging over a standoff distance (>25meters)

Abstract: The authors demonstrate the use of a terahertz quantum cascade laser (QCL) for real-time imaging in transmission mode at a standoff distance of 25meters. Lasing frequency was selected for optimum transmission within an atmospheric window at ∼4.9THz. Coarse frequency selection was made by design of the QCL gain medium. Finer selection (to within 0.1THz) was made by judicious choice of laser cavity length to adjust facet losses and therefore lasing threshold bias, in order to overlap the peak frequency of the Stark-shifted gain spectrum with the atmospheric window. Images are shown using an uncooled 320×240 microbolometer camera.

Terahertz achromatic quarter-wave plate

Abstract: Phase retarders usually present a strong frequency dependence. We discuss the design and characterization of a terahertz achromatic quarter-wave plate. This wave plate is made from six birefringent quartz plates precisely designed and stacked together. Phase retardation has been measured over the whole terahertz range by terahertz polarimetry. This achromatic wave plate demonstrates a huge frequency bandwidth (upsilonmax/upsilonmin approximately 7), and therefore can be applied to terahertz time domain spectroscopy and polarimetry.

Intense terahertz excitation of semiconductors

Abstract: 1. Experimental Technique 2. Tunneling in Terahertz Fields 3. Multi-Photon Excitation Beyond the Perturbative Limit 4. Saturation of Absorption 5. Electron Gas Heating 6. Terahertz Nonlinear Optics 7. Terahertz Radiation Induced Currents 8. Bloch Oscillations

High-power terahertz quantum-cascade lasers

Abstract: Demonstration of quantum-cascade lasers at ∼4.4 THz (λ∼68 µm), which are measured to emit 248 mW peak power in pulsed mode, and 138 mW continuous-wave power at heatsink temperatures of 10 K, is reported. These lasers are based on a resonant-phonon depopulation scheme, and use a semi-insulating surface-plasmon waveguide.

Identification and classification of chemicals using terahertz reflective spectroscopic focal-plane imaging system.

Abstract: We present terahertz (THz) reflective spectroscopic focal-plane imaging of four explosive and bio-chemical materials (2, 4-DNT, Theophylline, RDX and Glutamic Acid) at a standoff imaging distance of 0.4 m. The 2 dimension (2-D) nature of this technique enables a fast acquisition time and is very close to a camera-like operation, compared to the most commonly used point emission-detection and raster scanning configuration. The samples are identified by their absorption peaks extracted from the negative derivative of the reflection coefficient respect to the frequency (-dr/dv) of each pixel. Classification of the samples is achieved by using minimum distance classifier and neural network methods with a rate of accuracy above 80% and a false alarm rate below 8%. This result supports the future application of THz time-domain spectroscopy (TDS) in standoff distance sensing, imaging, and identification.

Determination of the carrier-envelope phase of few-cycle laser pulses with terahertz-emission spectroscopy

Abstract: The availability of few-cycle optical pulses opens a window to physical phenomena occurring on the attosecond timescale. To take full advantage of such pulses, it is crucial to measure1,2,3,4 and stabilize1,2 their carrier-envelope (CE) phase, that is, the phase difference between the carrier wave and the envelope function. We introduce an approach to determine the CE phase by down-conversion of the laser light to the terahertz (THz) frequency range by means of plasma generation in ambient air, an isotropic medium where optical rectification (down-conversion) in the forward direction is only possible if the inversion symmetry is broken by electrical or optical means5,6,7,8,9,10. We show that few-cycle pulses directly produce a spatial charge asymmetry in the plasma. The asymmetry, associated with THz emission, depends on the CE phase, which allows determination of the phase by measurement of the amplitude and polarity of the THz pulse.

Terahertz frequency comb by multifrequency-heterodyning photoconductive detection for high-accuracy, high-resolution terahertz spectroscopy

Abstract: We report a terahertz spectroscopy technique based on a stable terahertz frequency comb from a photoconductive terahertz emitter driven by a stabilized femtosecond laser. To this end, a photocurrent frequency comb is induced in a photoconductive terahertz detector by instantaneous photogating with another detuned femtosecond laser and is applied to read out the terahertz frequency comb. The detailed structure of the terahertz frequency comb was clearly observed with frequency accuracy of 2.5×10−7 and resolution of 81.8MHz using multifrequency-heterodyning photoconductive detection, which in turn is caused by the slightly mismatched frequency spacing between terahertz and photocurrent frequency combs.

Resonant and voltage-tunable terahertz detection in InGaAs /InP nanometer transistors

Abstract: The authors report on detection of terahertz radiation by high electron mobility nanometer InGaAs∕AlInAs transistors. The photovoltaic type of response was observed at the 1.8–3.1THz frequency range, which is far above the cutoff frequency of the transistors. The experiments were performed in the temperature range from 10to80K. The resonant response was observed and was found to be tunable by the gate voltage. The resonances were interpreted as plasma wave excitations in the gated two-dimensional electron gas. The minimum noise equivalent power was estimated, showing possible application of these transistors in sensing of terahertz radiation.

Terahertz Pulsed Spectroscopy of Human Basal Cell Carcinoma

Abstract: Good contrast is seen between normal tissue and regions of tumor in terahertz pulsed imaging of basal cell carcinoma (BCC). To date, the source of contrast at terahertz frequencies is not well understood. In this paper we present results of a spectroscopy study comparing the terahertz properties (absorption coefficient and refractive index) of excised normal human skin and BCC. Both the absorption coefficient and refractive index were higher for skin that contained BCC. The difference was statistically significant over the range 0.2 to 2.0 THz (6.6 cm(-1) to 66.6 cm(-1)) for absorption coefficient and 0.25 to 0.90 THz (8.3 cm(-1) to 30 cm(-1)) for refractive index. The maximum difference for absorption was at 0.5 THz(16.7 cm(-1)). These changes are consistent with higher water content. These results account for the contrast seen in terahertz images of BCC and explain why parameters relating to the reflected terahertz pulse provide information about the lateral spread of the tumor. Knowing the properties of the tissue over the terahertz frequency range will enable the use of mathematical models to improve understanding of the terahertz response of normal and diseased tissue.

Terahertz Radiation by an Ultrafast Spontaneous Polarization Modulation of Multiferroic BiFeO 3 Thin Films

Abstract: Terahertz (THz) radiation has been observed from multiferroic ${\mathrm{BiFeO}}_{3}$ thin films via ultrafast modulation of spontaneous polarization upon carrier excitation with illumination of femtosecond laser pulses. The radiated THz pulses from ${\mathrm{BiFeO}}_{3}$ thin films were clarified to directly reflect the spontaneous polarization state, giving rise to a memory effect in a unique style and enabling THz radiation even at zero-bias electric field. On the basis of our findings, we demonstrate potential approaches to ferroelectric nonvolatile random access memory with nondestructive readability and ferroelectric domain imaging microscopy using THz radiation as a sensitive probe.

Terahertz All-Optical Modulation in a Silicon-Polymer Hybrid System

Abstract: Although Gigahertz-scale free-carrier modulators have been previously demonstrated in silicon, intensity modulators operating at Terahertz speeds have not been reported because of silicon's weak ultrafast optical nonlinearity. We have demonstrated intensity modulation of light with light in a silicon-polymer integrated waveguide device, based on the all-optical Kerr effect - the same ultrafast effect used in four-wave mixing. Direct measurements of time-domain intensity modulation are made at speeds of 10 GHz. We showed experimentally that the ultrafast mechanism of this modulation functions at the optical frequency through spectral measurements, and that intensity modulation at frequencies in excess of 1 THz can be obtained in this device. By integrating optical polymers through evanescent coupling to high-mode-confinement silicon waveguides, we greatly increase the effective nonlinearity of the waveguide for cross-phase modulation. The combination of high mode confinement, multiple integrated optical components, and high nonlinearities produces all-optical ultrafast devices operating at continuous-wave power levels compatible with telecommunication systems. Although far from commercial radio frequency optical modulator standards in terms of extinction, these devices are a first step in development of large-scale integrated ultrafast optical logic in silicon, and are two orders of magnitude faster than previously reported silicon devices.

Detection of terahertz radiation in gated two-dimensional structures governed by dc current

Abstract: We present theoretical and experimental studies of the direct current effect on the detection of subterahertz and terahertz radiation in gated two-dimensional structures. We developed a theory of the current-driven detection both for resonant case, when the fundamental frequency of plasma oscillation is large compared to inverse scattering time, ${\ensuremath{\omega}}_{0}\ensuremath{\tau}⪢1$, and for the nonresonant case, ${\ensuremath{\omega}}_{0}\ensuremath{\tau}⪡1$, when the plasma oscillations are damped. We predict that, in the nonresonant case, even a very small dc current would increase the detection amplitude up to two orders of magnitude. Physically, this increase is related to an abrupt transition from the linear to saturation region near the knee of the current-voltage characteristic. When the current increases up to the saturation value, the electron concentration near the drain becomes very low and can be strongly affected by a small external field. As a consequence, the two-dimensional channel becomes extremely sensitive to external perturbations. In the resonant case, the detection amplitude has maxima when the radiation frequency is equal to fundamental plasma frequency and its harmonics. We predict that the effective linewidths of the respective resonances would decrease with the increasing current. Physically, this happens because dc current shifts the system towards the plasma wave instability. At some critical current value, the width corresponding to the fundamental frequency would turn to zero, indicating the onset of plasma waves generation. Our experimental measurements performed on $\mathrm{GaAs}$ HEMT confirm the theoretical predictions.

Probing the collective vibrational dynamics of a protein in liquid water by terahertz absorption spectroscopy

Abstract: Biological polymers are expected to exhibit functionally relevant, global, and subglobal collective modes in the terahertz (THz) frequency range (i.e., picosecond timescale). In an effort to monitor these collective motions, we have experimentally determined the absorption spectrum of solvated bovine serum albumin (BSA) from 0.3 to 3.72 THz (10–124 cm−1). We successfully extract the terahertz molar absorption of the solvated BSA from the much stronger attenuation of water and observe in the solvated protein a dense, overlapping spectrum of vibrational modes that increases monotonically with increasing frequency. We see no evidence of distinct, strong, spectral features, suggesting that no specific collective vibrations dominate the protein's spectrum of motions, consistent with the predictions of molecular dynamics simulations and normal mode analyses of a range of small proteins. The shape of the observed spectrum resembles the ideal quadratic spectral density expected for a disordered ionic solid, indicating that the terahertz normal mode density of the solvated BSA may be modeled, to first order, as that of a three-dimensional elastic nanoparticle with an aperiodic charge distribution. Nevertheless, there are important detailed departures from that of a disordered inorganic solid or the normal mode densities predicted for several smaller proteins. These departures are presumably the spectral features arising from the unique molecular details of the solvated BSA. The techniques used here and measurements have the potential to experimentally confront theoretical calculations on a frequency scale that is important for macromolecular motions in a biologically relevant water environment.