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Journal ArticleDOI

Mechanisms of liquefaction and pyrolysis reactions of biomass

Ayhan Demirbas
- 01 Apr 2000 - 
- Vol. 41, Iss: 6, pp 633-646
TLDR
In the liquefaction process, the micellar-like broken down fragments produced by hydrolysis are degraded to smaller compounds by dehydration, dehydrogenation, deoxygenation and decarboxylation as mentioned in this paper.
About
This article is published in Energy Conversion and Management.The article was published on 2000-04-01. It has received 904 citations till now. The article focuses on the topics: Deoxygenation & Thermal depolymerization.

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Citations
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High-strength charcoal briquette preparation from hydrothermal pretreated biomass wastes.

TL;DR: In this paper, the authors investigated the physical properties and combustion characteristics of the derived charcoal briquettes to assess the feasibility of its application as barbecue charcoal and found that the results indicated that the mass densities and compressive strengths of HT charcoal briques are better than those of DT and unpretreated charcoal briqueettes, even those of the commercial barbecue charcoal with binder addition.
Journal ArticleDOI

Wood moisture content during the thermal modification process affects the improvement in hygroscopicity of Scots pine sapwood

TL;DR: In this article, the effect of elevated wood moisture content is based on the impact of water on chemical reactions which determine the cell wall matrix stiffness, and it was shown that the modification in oven-dry state increased the cellwall matrix stiffness which improved dimensional stability and hygroscopicity.
Journal ArticleDOI

Effect of ash on hydrothermal liquefaction of high-ash content algal biomass

TL;DR: In this paper, mixed-culture algal biomass from wastewater systems (AW) was separated into two fractions (AW-418 and AW-385) and converted into biocrude oil via HTL at 300°C for a 60min reaction time.
Journal ArticleDOI

Hydrothermal carbonization of maize straw for hydrochar production and its injection for blast furnace

TL;DR: In this paper, the authors investigate the characterized hydrochar of maize straw prepared via the hydrothermal carbonization (HTC) process as a solid fuel for blast furnace injection and find that with the increase in HTC temperature and time, the yields, H/C and O/C values of hydrochar decreased, and the higher heating value increased.
Journal ArticleDOI

Biomass Gasification Using Carbon Dioxide: Effect of Temperature, CO2/C Ratio, and the Study of Reactions Influencing the Process

TL;DR: In this paper, the effect of temperature and CO2/C ratios on the output syngas was investigated in a bench-scale atmospheric bubbling fluidized bed gasifier and compared with an oxygen gasification study from literature.
References
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Book

Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

Jerry March
TL;DR: Localized Chemical bonding Delocalized Chemical Bonding Bonding Weaker than Covalent Stereochemistry Carbocations, Carbanions, Free Radicals, Carbenes and Nitrenes Mechanisms and Methods of Determining them Photochemistry Acids and Bases Effects of Structure on Reactivity Aliphatic Nucleophilic Substitution Aromatic Electrophilic Substitutes Aliphatically Electrophilic Substitution Free-Radical Substitution Addition to Carbon-Carbon Multiple Bonds Adding to Carbon Hetero Multiple Bonds Eliminations Rearrangements Ox
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Wood: chemistry, ultrastructure, reactions.

TL;DR: The anatomy and chemistry of wood are described in detail, and with extensive reference to the literature, under the following headings: Introduction; Structure and ultrastructure; Chemical composition and analysis of wood; Cellulose; Polyoses (hemicelluloses); Lignin; Extractives; Distribution of the components within the wood cell wall; Constituents of bark; Reactions in acidic medium; reactions in alkaline medium; Influence of temperature; Degradation by light and ionizing rays; Microbial and enzymatic degradation; Aging and fossilization; Pul
Book

Textbook of Wood Technology

A. J. Panshin, +1 more
TL;DR: The first part deals with the formation, anatomy and properties of wood, and the second part is important for the numerous means of identifying woods which it contains as discussed by the authors, including anatomical means, structural features, physical characteristics, figure as it is related to the various planes of cut, and by chemical means.
Journal ArticleDOI

Lignin chemistry—past, present and future

TL;DR: Later development, beginning with the dehydrogenation theory and experimental studies on the de-hydrogenative polymerization of p-hydroxycinnamyl alcohols, is reviewed in this article.
Journal ArticleDOI

Recent progress in the chemistry of wood hemicelluloses

TL;DR: In this article, the present status of the chemistry of wood hemicelluloses is summarized, with special emphasis on recent contributions, and problems still to be solved in wood chemistry are discussed, and an attempt is made to predict future developments in this field.
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