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Open AccessJournal ArticleDOI

Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Citations
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Journal ArticleDOI

Mechanical characterization and constitutive modeling of visco-hyperelasticity of photocured polymers

TL;DR: In this article, a physically-based visco-hyperelastic model in the continuum thermodynamics framework was developed to study the nonlinear behavior of soft photocured polymers typically used in 3D-printing.
Journal ArticleDOI

Nanomaterials for 3D Printing of Polymers via Stereolithography: Concept, Technologies, and Applications

TL;DR: Stereolithography (SLA) is an additive manufacturing method with one of the highest accuracies (down to 100nm) of all solid freeform techniques and has been used in various areas, such as medicine, automotive, aerospace, electronics, and others as mentioned in this paper.
Journal ArticleDOI

Highly conjugated visible and near-infrared light photoinitiating systems for radical and cationic polymerizations

TL;DR: In this paper, the electron transfer reactions between the excited conjugated molecule and DPI ions were used to initiate free radical (FRP) and cationic polymerization (CP).
Journal ArticleDOI

Review: 3D printing hydrogels for the fabrication of soilless cultivation substrates

TL;DR: The idea of fabricating hydrogels as bioreceptive structures to be used as soilless cultivation substrates is introduced, and AM is suggested as the fabrication process to achieve structures with features similar to soil.
Journal ArticleDOI

Three-Dimensional Printing of Poly(glycerol sebacate) Acrylate Scaffolds via Digital Light Processing

TL;DR: The tunable properties of PGSA coupled with enhanced precision in microstructure geometry provide a fabrication platform for a variety of tissue regeneration applications.
References
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Journal ArticleDOI

Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI

Hydrogels as Extracellular Matrix Mimics for 3D Cell Culture

TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Journal ArticleDOI

Polymers for 3D Printing and Customized Additive Manufacturing

TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Journal ArticleDOI

3D printing of polymer matrix composites: A review and prospective

TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
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