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Open AccessJournal ArticleDOI

Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Citations
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Journal ArticleDOI

Functional 3D printing: Approaches and bioapplications

TL;DR: By combining 3D printing technology with an accurate materials' design, functional 3D objects with built-in (bio)chemical functionalities, having biorecognition, biocatalytic and drug delivery capabilities are reported.
Journal ArticleDOI

Recent Advances on Chalcone-based Photoinitiators of Polymerization

TL;DR: In this paper, an overview of the recent development concerning chalcone-based photo-initiating systems is reported, with aim at evidencing the crucial interest of this family of dyes, comparisons with benchmark photoinitiators will be presented.
Journal ArticleDOI

Reversible Deactivation Radical Polymerization: From Polymer Network Synthesis to 3D Printing.

TL;DR: In this paper, reversible deactivation radical polymerization (RDRP) is applied to polymer networks to tune network homogeneity and enable the production of advanced materials containing dormant reactivatable species that can be used for subsequent processes in a postsynthetic stage.
Journal ArticleDOI

3D printing of polymer composites: Materials, processes, and applications

TL;DR: Additive manufacturing (AM) has enabled the customized fabrication of objects with complex geometries and functionalities in mechanical and electrical properties as mentioned in this paper , but many challenges, such as the suboptimal quality of manufactured products and limited material available for 3D printing, need to be addressed for the broad adoption of additively manufactured polymer composites.
Journal ArticleDOI

Recent advances on push–pull organic dyes as visible light photoinitiators of polymerization

TL;DR: An overview of the different D-π-A push-pull dyes used as visible photoinitiators of polymerization is presented in this paper, where a clear evolution in the chemical structure of electron acceptors can be clearly observed, evidencing the strong activity existing around these structures.
References
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Journal ArticleDOI

Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI

Hydrogels as Extracellular Matrix Mimics for 3D Cell Culture

TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Journal ArticleDOI

Polymers for 3D Printing and Customized Additive Manufacturing

TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Journal ArticleDOI

3D printing of polymer matrix composites: A review and prospective

TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
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