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Open AccessJournal ArticleDOI

Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Citations
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Journal ArticleDOI

Quality and haptic feedback of three-dimensionally printed models for simulating dental implant surgery.

TL;DR: In this article , the authors compare the haptic feedback of different 3D-printed models for simulating dental implant surgery and find that the material jetting-based model with acrylic-based resin provided the best haptic perception for performing implant surgery.
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Utilizing 4D Printing to Design Smart Gastroretentive, Esophageal, and Intravesical Drug Delivery Systems

TL;DR: In this article , a review on 4D printed devices for gastroretentive, esophageal, and intravesical delivery is presented, where the currently unmet needs and challenges for these application sites are tried to be defined and reported on published solution concepts involving 4D printing.
Journal ArticleDOI

Fast Living 3D Printing via Free Radical Promoted Cationic RAFT Polymerization.

TL;DR: In this paper , a photoinduced free radical-promoted cationic reversible addition-fragmentation chain transfer polymerization of vinyl ethers was used to build living objects by a commercial DLP 3D printer at a relatively fast building speed.
Journal ArticleDOI

Swelling behavior and tensile strength of additively manufactured and commercial O-rings in the presence of linear, branched, cyclic, and aromatic compounds and alcohols

TL;DR: In this article , the authors show that exposure of these O-rings and those from commercial sources to linear, branched, cyclic, and aromatic compounds and alcohols for 24 hours causes swelling and changes in the ultimate tensile strength.
Journal ArticleDOI

Main group element and metal-containing polymers as photoresponsive soft materials

TL;DR: In this article , the authors describe the most recent efforts to expand the array of photoresponsive polymers to include inorganic and heteroatom moieties and, in doing so, to prepare polymers with potentially more sensitive and selective photochemical responses.
References
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Journal ArticleDOI

Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI

Hydrogels as Extracellular Matrix Mimics for 3D Cell Culture

TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Journal ArticleDOI

Polymers for 3D Printing and Customized Additive Manufacturing

TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Journal ArticleDOI

3D printing of polymer matrix composites: A review and prospective

TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
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