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Open AccessJournal ArticleDOI

Photopolymerization in 3D Printing

Ali Bagheri, +1 more
- Vol. 1, Iss: 4, pp 593-611
TLDR
The field of 3D printing is continuing its rapid development in both academic and industrial research environments as mentioned in this paper, which offers flexibility over the final properties of the 3D printed materials (such as optical, chemical and mechanical properties) using versatile polymer chemistry.
Abstract
The field of 3D printing is continuing its rapid development in both academic and industrial research environments. The development of 3D printing technologies has opened new implementations in rapid prototyping, tooling, dentistry, microfluidics, biomedical devices, tissue engineering, drug delivery, etc. Among different 3D printing techniques, photopolymerization-based process (such as stereolithography and digital light processing) offers flexibility over the final properties of the 3D printed materials (such as optical, chemical, and mechanical properties) using versatile polymer chemistry. The strategy behind the 3D photopolymerization is based on using monomers/oligomers in liquid state (in the presence of photoinitiators) that can be photopolymerized (via radical or cationic mechanism) upon exposure to light source of different wavelengths (depending on the photoinitiator system). An overview of recent evolutions in the field of photopolymerization-based 3D printing and highlights of novel 3D print...

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Citations
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Journal ArticleDOI

Plasmonic and Semiconductor Nanoparticles Interfere with Stereolithographic 3D Printing.

TL;DR: It is observed that both, material-specific (absorption profiles) and unspecific (radical quenching at nanoparticle surfaces) pathways co-exist by which the photopolymerization procedure is altered, which can be exploited to increase the printing resolution leading to a reduction of the minimum feature size.
Journal ArticleDOI

RAFT agent symmetry and the effects on photo-growth behavior in living polymer networks

TL;DR: Here it is described how different symmetries of RAFT agent act after growth, where asymmetric networks showed a pore-filling behaviour, while symmetric networks underwent mesh-expansion.
Journal ArticleDOI

Additive manufacturing: Frameworks for chemical understanding and advancement in vat photopolymerization

Johanna J. Schwartz
- 01 Jun 2022 - 
TL;DR: In this article , the authors discuss some of the considerations for polymer-based additive manufacturing methods and focus on the chemistries of vat photopolymerization, in which light is used to cure a resin from liquid to solid, to provide an example of how chemical advancements have led to increased speed, resolution, and multimaterial printing capabilities not previously possible.
Journal ArticleDOI

Additive Manufacture of Small-Scale Metamaterial Structures for Acoustic and Ultrasonic Applications.

TL;DR: A review of metamaterials can be found in this article, where the authors highlight the advantages and disadvantages of different techniques that act as barriers towards the development of realizable acoustic metammaterials for practical audio and ultrasonic applications and speculate on potential future developments.
Journal ArticleDOI

Recent Advances on Photoinitiating Systems Designed for Solar Photocrosslinking Polymerization Reactions

TL;DR: An overview of the different photo-initiating systems developed for polymerization processes done under sunlight or even daylight is provided in this paper , where the authors compare the efficiency of these systems with those obtained with artificial light sources.
References
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Journal ArticleDOI

Thiol–Ene Click Chemistry

TL;DR: The radical-mediated thiol-ene reaction has all the desirable features of a click reaction, being highly efficient, simple to execute with no side products and proceeding rapidly to high yield.
Journal ArticleDOI

Hydrogels as Extracellular Matrix Mimics for 3D Cell Culture

TL;DR: The use of both synthetic and natural hydrogels as scaffolds for three-dimensional cell culture as well as synthetic hydrogel hybrids that incorporate sophisticated biochemical and mechanical cues as mimics of the native extracellular matrix are discussed.
Journal ArticleDOI

Polymers for 3D Printing and Customized Additive Manufacturing

TL;DR: Polymers are by far the most utilized class of materials for AM and their design, additives, and processing parameters as they relate to enhancing build speed and improving accuracy, functionality, surface finish, stability, mechanical properties, and porosity are addressed.
Journal ArticleDOI

3D printing of polymer matrix composites: A review and prospective

TL;DR: In this paper, the authors give an overview on 3D printing techniques of polymer composite materials and the properties and performance of 3D printed composite parts as well as their potential applications in the fields of biomedical, electronics and aerospace engineering.
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