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Showing papers on "Cluster (physics) published in 2019"


Journal ArticleDOI
TL;DR: In this paper, the authors derived the mean proper motions and space velocities of 154 Galactic globular clusters and the velocity dispersion profiles of 141 Globular clusters based on a combination of Gaia DR2 proper motions with ground-based line-of-sight velocity.
Abstract: We have derived the mean proper motions and space velocities of 154 Galactic globular clusters and the velocity dispersion profiles of 141 globular clusters based on a combination of Gaia DR2 proper motions with ground-based line-of-sight velocities. Combining the velocity dispersion profiles derived here with new measurements of the internal mass functions allows us to model the internal kinematics of 144 clusters, more than 90 per cent of the currently known Galactic globular cluster population. We also derive the initial cluster masses by calculating the cluster orbits backwards in time applying suitable recipes to account for mass-loss and dynamical friction. We find a correlation between the stellar mass function of a globular cluster and the amount of mass lost from the cluster, pointing to dynamical evolution as one of the mechanisms shaping the mass function of stars in clusters. The mass functions also show strong evidence that globular clusters started with a bottom-light initial mass function. Our simulations show that the currently surviving globular cluster population has lost about 80 per cent of its mass since the time of formation. If globular clusters started from a lognormal mass function, we estimate that the Milky Way contained about 500 globular clusters initially, with a combined mass of about 2.5 × 10 M. For a power-law initial mass function, the initial mass in globular clusters could have been a factor of three higher.

363 citations


Journal ArticleDOI
TL;DR: In a growing number of galaxy clusters diffuse extended radio sources have been found. as mentioned in this paper classified diffuse cluster radio sources into radio halos, cluster radio shocks (relics), and revived AGN fossil plasma sources.
Abstract: In a growing number of galaxy clusters diffuse extended radio sources have been found. These sources are not directly associated with individual cluster galaxies. The radio emission reveal the presence of cosmic rays and magnetic fields in the intracluster medium (ICM). We classify diffuse cluster radio sources into radio halos, cluster radio shocks (relics), and revived AGN fossil plasma sources. Radio halo sources can be further divided into giant halos, mini-halos, and possible “intermediate” sources. Halos are generally positioned at cluster center and their brightness approximately follows the distribution of the thermal ICM. Cluster radio shocks (relics) are polarized sources mostly found in the cluster’s periphery. They trace merger induced shock waves. Revived fossil plasma sources are characterized by their radio steep-spectra and often irregular morphologies. In this review we give an overview of the properties of diffuse cluster radio sources, with an emphasis on recent observational results. We discuss the resulting implications for the underlying physical acceleration processes that operate in the ICM, the role of relativistic fossil plasma, and the properties of ICM shocks and magnetic fields. We also compile an updated list of diffuse cluster radio sources which will be available on-line ( http://galaxyclusters.com ). We end this review with a discussion on the detection of diffuse radio emission from the cosmic web.

347 citations


Journal ArticleDOI
18 Oct 2019-Science
TL;DR: Generating a large-scale two-dimensional continuous-variable cluster state that is compatible with Bosonic error-correcting codes that enable fault-tolerant quantum computation and readily scalable and fault tolerant.
Abstract: Entanglement is the key resource for measurement-based quantum computing. It is stored in quantum states known as cluster states, which are prepared offline and enable quantum computing by means of purely local measurements. Universal quantum computing requires cluster states that are both large and possess (at least) a two-dimensional topology. Continuous-variable cluster states—based on bosonic modes rather than qubits—have previously been generated on a scale exceeding one million modes, but only in one dimension. Here, we report generation of a large-scale two-dimensional continuous-variable cluster state. Its structure consists of a 5- by 1240-site square lattice that was tailored to our highly scalable time-multiplexed experimental platform. It is compatible with Bosonic error-correcting codes that, with higher squeezing, enable fault-tolerant quantum computation.

307 citations


Journal ArticleDOI
TL;DR: Three-level, four- partite cluster states have now been created in the time and frequency domain of two photons on-chip, confirming genuine multi-partite entanglement with higher noise robustness compared to conventional two-level cluster states.
Abstract: Taking advantage of quantum mechanics for executing computational tasks faster than classical computers1 or performing measurements with precision exceeding the classical limit2,3 requires the generation of specific large and complex quantum states. In this context, cluster states4 are particularly interesting because they can enable the realization of universal quantum computers by means of a ‘one-way’ scheme5, where processing is performed through measurements6. The generation of cluster states based on sub-systems that have more than two dimensions, d-level cluster states, provides increased quantum resources while keeping the number of parties constant7, and also enables novel algorithms8. Here, we experimentally realize, characterize and test the noise sensitivity of three-level, four-partite cluster states formed by two photons in the time9 and frequency10 domain, confirming genuine multi-partite entanglement with higher noise robustness compared to conventional two-level cluster states6,11–13. We perform proof-of-concept high-dimensional one-way quantum operations, where the cluster states are transformed into orthogonal, maximally entangled d-level two-partite states by means of projection measurements. Our scalable approach is based on integrated photonic chips9,10 and optical fibre communication components, thus achieving new and deterministic functionalities. The creation and manipulation of large quantum states is necessary for quantum information processing tasks. Three-level, four-partite cluster states have now been created in the time and frequency domain of two photons on-chip.

259 citations


Journal ArticleDOI
TL;DR: A simple, efficient, and low-cost all-in-one photocatalytic H2 evolution system composed of a thiazolo[5,4-d]thiazole-linked COF as the photoabsorber and an earth-abundant, noble-metal-free nickel-thiolate hexameric cluster co-catalyst assembled in situ in water, together with triethanolamine as the sacrificial electron donor is reported.
Abstract: Solar hydrogen (H2) evolution from water utilizing covalent organic frameworks (COFs) as heterogeneous photosensitizers has gathered significant momentum by virtue of the COFs’ predictive structura...

207 citations


Journal ArticleDOI
TL;DR: The authors demonstrate that the solution for CO oxidation is to tackle the issue of lacking neighboring Pt atoms in the single-atom Pt1/CeO2 system, which is well-represented by a Pt8O14 model cluster that retains 100% metal dispersion.
Abstract: Despite the maximized metal dispersion offered by single-atom catalysts, further improvement of intrinsic activity can be hindered by the lack of neighboring metal atoms in these systems. Here we report the use of isolated Pt1 atoms on ceria as "seeds" to develop a Pt-O-Pt ensemble, which is well-represented by a Pt8O14 model cluster that retains 100% metal dispersion. The Pt atom in the ensemble is 100-1000 times more active than their single-atom Pt1/CeO2 parent in catalyzing the low-temperature CO oxidation under oxygen-rich conditions. Rather than the Pt-O-Ce interfacial catalysis, the stable catalytic unit is the Pt-O-Pt site itself without participation of oxygen from the 10-30 nm-size ceria support. Similar Pt-O-Pt sites can be built on various ceria and even alumina, distinguishable by facile activation of oxygen through the paired Pt-O-Pt atoms. Extending this design to other reaction systems is a likely outcome of the findings reported here.

202 citations


Journal ArticleDOI
TL;DR: Because of their interesting structures and bonding and potentials as motifs for new nanomaterials, size-selected boron clusters have received tremendous interest in recent years and have allowed systematic joint photoelectron spectroscopy and theoretical studies, revealing predominantly two-dimensional structures.
Abstract: Because of their interesting structures and bonding and potentials as motifs for new nanomaterials, size-selected boron clusters have received tremendous interest in recent years. In particular, boron cluster anions (Bn−) have allowed systematic joint photoelectron spectroscopy and theoretical studies, revealing predominantly two-dimensional structures. The discovery of the planar B36 cluster with a central hexagonal vacancy provided the first experimental evidence of the viability of 2D borons, giving rise to the concept of borophene. The finding of the B40 cage cluster unveiled the existence of fullerene-like boron clusters (borospherenes). Metal-doping can significantly extend the structural and bonding repertoire of boron clusters. Main-group metals interact with boron through s/p orbitals, resulting in either half-sandwich-type structures or substitutional structures. Transition metals are more versatile in bonding with boron, forming a variety of structures including half-sandwich structures, metal-centered boron rings, and metal-centered boron drums. Transition metal atoms have also been found to be able to be doped into the plane of 2D boron clusters, suggesting the possibility of metalloborophenes. Early studies of di-metal-doped boron clusters focused on gold, revealing ladder-like boron structures with terminal gold atoms. Recent observations of highly symmetric Ta2B6− and Ln2Bn− (n = 7–9) clusters have established a family of inverse sandwich structures with monocyclic boron rings stabilized by two metal atoms. The study of size-selected boron and doped-boron clusters is a burgeoning field of research. Further investigations will continue to reveal more interesting structures and novel chemical bonding, paving the foundation for new boron-based chemical compounds and nanomaterials.

148 citations


Journal ArticleDOI
TL;DR: In this article, a multidimensional spectroscopy method was proposed to isolate individual nuclear-nuclear spin interactions with high spectral resolution and high accuracy of 2.2 mHz.
Abstract: Nuclear magnetic resonance (NMR) is a powerful method for determining the structure of molecules and proteins. While conventional NMR requires averaging over large ensembles, recent progress with single-spin quantum sensors has created the prospect of magnetic imaging of individual molecules. As an initial step towards this goal, isolated nuclear spins and spin pairs have been mapped. However, large clusters of interacting spins - such as found in molecules - result in highly complex spectra. Imaging these complex systems is an outstanding challenge due to the required high spectral resolution and efficient spatial reconstruction with sub-angstrom precision. Here we develop such atomic-scale imaging using a single nitrogen-vacancy (NV) centre as a quantum sensor, and demonstrate it on a model system of $27$ coupled $^{13}$C nuclear spins in a diamond. We present a new multidimensional spectroscopy method that isolates individual nuclear-nuclear spin interactions with high spectral resolution ($< 80\,$mHz) and high accuracy ($2$ mHz). We show that these interactions encode the composition and inter-connectivity of the cluster, and develop methods to extract the 3D structure of the cluster with sub-angstrom resolution. Our results demonstrate a key capability towards magnetic imaging of individual molecules and other complex spin systems.

147 citations


Journal ArticleDOI
TL;DR: In this paper, the authors focus on the main observational features of clusters in the Milky Way and its satellites, and find that most of the observational facts related to the chemical evolution in globular clusters are described as being primarily a function of the initial mass of the clusters, tuned by further dependence on the metallicity, which likely determines the possibility of independent chemical evolution of the fragments or satellites, where the clusters form.
Abstract: Globular clusters are large and dense agglomerate of stars. At variance with smaller clusters of stars, they exhibit signs of some chemical evolution. At least for this reason, they are intermediate between open clusters and massive objects such as nuclear clusters or compact galaxies. While some facts are well established, the increasing amount of observational data are revealing a complexity that has so far defied the attempts to interpret the whole data set in a simple scenario. We review this topic focusing on the main observational features of clusters in the Milky Way and its satellites. We find that most of the observational facts related to the chemical evolution in globular clusters are described as being primarily a function of the initial mass of the clusters, tuned by further dependence on the metallicity—that mainly affects specific aspects of the nucleosynthesis processes involved—and on the environment, that likely determines the possibility of independent chemical evolution of the fragments or satellites, where the clusters form. We review the impact of multiple populations on different regions of the colour–magnitude diagram and underline the constraints related to the observed abundances of lithium, to the cluster dynamics, and to the frequency of binaries in stars of different chemical composition. We then re-consider the issues related to the mass budget and the relation between globular cluster and field stars. Any successful model of globular cluster formation should explain these facts.

131 citations



Journal ArticleDOI
01 Nov 2019
TL;DR: In this paper, the Sum Of Squared Error (SSE) was used to improve the performance of the K-means algorithm in determining the optimum number of clusters in a cluster.
Abstract: K-Means is a simple clustering algorithm that has the ability to throw large amounts of data, partition datasets into several clusters k. The algorithm is quite easy to implement and run, relatively fast and efficient. Another division of K-Means still has several weaknesses, namely in determining the number of clusters, determining the cluster center. The results of the cluster formed from the K-means method is very dependent on the initiation of the initial cluster center value provided. This causes the results of the cluster to be a solution that is locally optimal. This research was conducted to overcome the weaknesses in the K-Means algorithm, namely: improvements to the K-Means algorithm produce better clusters, namely the application of Sum Of Squared Error (SSE) to help K-Means Clustering in determining the optimum number of clusters, From this modification process, it is expected that the cluster center obtained will produce clusters, where the cluster members have a high level of similarity. Improving the performance of the K-Means cluster will be applied to determining the number of clusters using the elbow method.

Journal ArticleDOI
TL;DR: Electrospray ionization mass spectrometry (ESI-MS) analysis suggests that the metal cluster skeleton of Dy76 shows good stability in various solvents, and provides insight into the novel fusion assembly process.
Abstract: Although great achievements have been made in the synthesis of giant lanthanide clusters, novel structural models are still scarce. Herein, we report a giant lanthanide cluster Dy76 , constructed from [Dy3 (μ3 -OH)4 ] and [Dy5 (μ4 -O)(μ3 -OH)8 ] building blocks. As the largest known Dy cluster, the structure of Dy76 can be seen as arising from the fusion of two Dy48 clusters; these clusters can be isolated under various synthetic conditions and were characterized by single-crystal X-ray diffraction. This new, fused structural model of the pillar motif has not been found in Ln clusters. Furthermore, the successful conversion of Dy76 back into Dy48 in a retrosynthetic manner supports the proposed fusion formation mechanism of Dy76 . Electrospray ionization mass spectrometry (ESI-MS) analysis suggests that the metal cluster skeleton of Dy76 shows good stability in various solvents. This work not only reveals a new structural type of Ln clusters but also provides insight into the novel fusion assembly process.

Journal ArticleDOI
TL;DR: A semi‐quantum key distribution protocol based on four‐particle cluster states is put forward, which can achieve key distribution among one quantum party and two classical parties simultaneously, and can be expanded to the χ‐party ( χ>3 ) communication scheme.

Journal ArticleDOI
Lindsey Bleem1, Sebastian Bocquet1, Sebastian Bocquet2, B. Stalder3  +156 moreInstitutions (56)
TL;DR: In this article, the authors describe the observations and resultant galaxy cluster catalog from the 2770 deg$^2$ SPTpol Extended Cluster Survey (SPT-ECS).
Abstract: We describe the observations and resultant galaxy cluster catalog from the 2770 deg$^2$ SPTpol Extended Cluster Survey (SPT-ECS). Clusters are identified via the Sunyaev-Zel'dovich (SZ) effect, and confirmed with a combination of archival and targeted follow-up data, making particular use of data from the Dark Energy Survey (DES). With incomplete followup we have confirmed as clusters 244 of 266 candidates at a detection significance $\xi \ge 5$ and an additional 204 systems at $4 4$ threshold, and $ 10\% $ of their measured SZ flux. We associate SZ-selected clusters, from both SPT-ECS and the SPT-SZ survey, with clusters from the DES redMaPPer sample, and find an offset distribution between the SZ center and central galaxy in general agreement with previous work, though with a larger fraction of clusters with significant offsets. Adopting a fixed Planck-like cosmology, we measure the optical richness-to-SZ-mass ($\lambda-M$) relation and find it to be 28% shallower than that from a weak-lensing analysis of the DES data---a difference significant at the 4 $\sigma$ level---with the relations intersecting at $\lambda=60$ . The SPT-ECS cluster sample will be particularly useful for studying the evolution of massive clusters and, in combination with DES lensing observations and the SPT-SZ cluster sample, will be an important component of future cosmological analyses.

Journal ArticleDOI
TL;DR: In this paper, the spatial locations of young star clusters are correlated with those of molecular clouds in NGC 5194, in order to investigate the time-scale over which clusters separate from their birth clouds.
Abstract: We present a study correlating the spatial locations of young star clusters with those of molecular clouds in NGC 5194, in order to investigate the time-scale over which clusters separate from their birth clouds. The star cluster catalogues are from the Legacy ExtraGalactic UV Survey (LEGUS) and the molecular clouds from the Plateau de Bure Interefrometer Arcsecond Whirpool Survey (PAWS). We find that younger star clusters are spatially closer to molecular clouds than older star clusters. The median age for clusters associated with clouds is 4 Myr, whereas it is 50 Myr for clusters that are sufficiently separated from a molecular cloud to be considered unassociated. After ∼6 Myr, the majority of the star clusters lose association with their molecular gas. Younger star clusters are also preferentially located in stellar spiral arms where they are hierarchically distributed in kpc-size regions for 50–100 Myr before dispersing. The youngest star clusters are more strongly clustered, yielding a two-point correlation function with α = −0.28 ± 0.04, than the giant molecular cloud (GMCs) (α = −0.09 ± 0.03) within the same PAWS field. However, the clustering strength of the most massive GMCs, supposedly the progenitors of the young clusters for a star formation efficiency of a few per cent, is comparable (α = −0.35 ± 0.05) to that of the clusters. We find a galactocentric dependence for the coherence of star formation, in which clusters located in the inner region of the galaxy reside in smaller star-forming complexes and display more homogeneous distributions than clusters further from the centre. This result suggests a correlation between the survival of a cluster complex and its environment.

Journal ArticleDOI
TL;DR: This Account introduces the recent progress in the theoretical exploration of structures and evolution patterns of a class of atomically precise thiolate-protected gold nanoclusters using density functional theory computations and indicates some basic structural and electronic evolution patterns.
Abstract: ConspectusUnderstanding the structure and structure–property relationship of atomic and ligated clusters is one of the central research tasks in the field of cluster research. In chemistry, empirical rules such as the polyhedral skeleton electron pair theory (PSEPT) approach had been outlined to account for skeleton structures of many main-group atomic and ligand-protected transition metal clusters. Nonetheless, because of the diversity of cluster structures and compositions, no uniform structural and electronic rule is available for various cluster compounds. Exploring new cluster structures and their evolution is a hot topic in the field of cluster research for both experiment and theory.In this Account, we introduce our recent progress in the theoretical exploration of structures and evolution patterns of a class of atomically precise thiolate-protected gold nanoclusters using density functional theory computations. Unlike the conventional ligand-protected transition metal compounds, the thiolate-prote...

Journal ArticleDOI
TL;DR: It is shown that, using an energy-minimization analysis, one can predict equilibrium values of the cluster radius that correspond to rotation without radial pulsations, and evolve as metastable states in a Gross-Pitaevskii equations regime.
Abstract: We show that metastable ring-shaped clusters can be constructed from two-dimensional quantum droplets in systems described by the Gross-Pitaevskii equations augmented with Lee-Huang-Yang quantum corrections. The clusters exhibit dynamical behavior ranging from contraction to rotation with simultaneous periodic pulsations, or expansion, depending on the initial radius of the necklace pattern and phase shift between adjacent quantum droplets. We show that, using an energy-minimization analysis, one can predict equilibrium values of the cluster radius that correspond to rotation without radial pulsations. In such a regime, the clusters evolve as metastable states, withstanding abrupt variations in the underlying scattering lengths and keeping their azimuthal symmetry in the course of evolution, even in the presence of considerable perturbations.

Journal ArticleDOI
TL;DR: The optical spectrum of the mixture showed unique features which were in good agreement with the results from time-dependent density functional theory (TD-DFT) and the presence of two entities in a single crystal and their molecular formulae were confirmed by detailed electrospray ionization mass spectrometry.
Abstract: Two ligand-protected nanoscale silver moieties, [Ag46 (SPhMe2 )24 (PPh3 )8 ](NO3 )2 and [Ag40 (SPhMe2 )24 (PPh3 )8 ](NO3 )2 (abbreviated as Ag46 and Ag40 , respectively) with almost the same shell but different cores were synthesized simultaneously. As their external structures are identical, the clusters were not distinguishable and become co-crystallized. The occupancy of each cluster was 50 %. The outer shell of both is composed of Ag32 S24 P8 , which is reminiscent of fullerenes, and it encapsulates a well-studied core, Ag14 and a completely new core, Ag8 , which correspond to a face-centered cube and a simple cube, respectively, resulting in the Ag46 and Ag40 clusters. The presence of two entities (Ag40 and Ag46 clusters) in a single crystal and their molecular formulae were confirmed by detailed electrospray ionization mass spectrometry. The optical spectrum of the mixture showed unique features which were in good agreement with the results from time-dependent density functional theory (TD-DFT).

Journal ArticleDOI
TL;DR: The essential criteria for dynamical behavior in boron clusters are the absence of a localized two-center, two-electron (2c-2e) bond between two molecular regions that tend to rotate with respect to each other, and retention of the delocalized electronic structure throughout the rotation/reorganization process.
Abstract: Isolated boron clusters exhibit many intriguing properties, which have only recently been unfolding with the hand-in-hand advancement of state-of-the-art experimental and theoretical methods for the analyses of their electronic structure, chemical reactivity, and nuclear dynamics. A fascinating property that a number of these clusters display is fluxionality, a dynamical phenomenon associated with the delocalized nature of the chemical bonding and related to the continuous exchange between interatomic neighbors. The electron-deficient nature of boron is the driving force behind its extraordinary ability to form multicenter bonds, and this in turn leads to fluxional behavior only when an appropriate combination of topology and bonding is present. The first instance of fluxionality in boron clusters, the quasi-planar anion B19-, was reported in 2010. The rotational barrier of the inner B6 unit spinning within the peripheral B13 ring can be overcome even at low temperature, mimicking the characteristic motion of a rotary internal combustion engine, and hence, B19- was entitled a boron-based molecular Wankel engine. Shortly after that, it was found that other quasi-planar boron clusters, like B13+ and B182-, also exhibit an almost barrier-free rotation of internal planar moieties. The case of the B13+ cation is special because, on the one hand, it was chosen to examine the way to initiate, control, and direct the internal rotation using circularly polarized laser radiation, and on the other hand, the experimental manifestation of fluxionality was first established for this system through infrared experiments. Nevertheless, fluxional behavior is not limited to planar or pure boron clusters. Larger boron clusters, such as the fullerene-analogue borospherenes B40 and B39-, are also predicted to show pronounced dynamical behavior that is related to the interconversion between six- and seven-membered rings. Be6B11-, a triple-layer cluster, is another particularly interesting system since it exhibits multifold fluxionality consisting of the revolution of the outer boron ring around the Be6 core and the spinning of the two Be3 rings with respect to each other. The essential criteria for dynamical behavior in boron clusters are (1) the absence of a localized two-center, two-electron (2c-2e) bond between two molecular regions that tend to rotate with respect to each other, (2) the absence of steric hindrances for rotation and reorganization, and (3) retention of the delocalized electronic structure throughout the rotation/reorganization process. The fulfillment of the above three conditions ensures that low energy barriers will be associated with the rotation or reorganization of molecular moieties. The first two points can be illustrated from the facts that a single localized C-B σ bond in CB18 raises the rotational barrier by 27.0 kcal·mol-1 and the expansion of the outer ring by a single boron atom in moving from B12+ to B13+ lowers the rotational barrier by 7.5 kcal·mol-1. Alternatively, it is also possible to make a rigid boron cluster fluxional through doping, where the geometric and electronic changes caused by a suitable dopant, as in MB12- (M = Co, Rh, Ir) and B10Ca, reduce the corresponding rotational barriers enough to achieve fluxionality. At present, there are 13 pure boron clusters (B11-/0/+, B13+/0/-, B15+/0/-, B182-, B19-, and B20-/2-) and eight metal-doped boron clusters (B10Ca, NiB11-, [B2-Ta@B18]-, Be6B11-, Be6B102-, and MB18- (M = K, Rb, Cs)) that have sufficiently small rotational barriers (less than ∼1.5 kcal·mol-1) to exhibit fluxional behavior at low temperature. Some of the other reported boron clusters show more sizable barriers, and their dynamical behavior is manifested only at elevated temperatures. The research on such systems is driven by the notion that it ultimately will pave the way for the development of light-harvesting boron-based nanomotors/machines and robots, a reality that may not be that far away!

Journal ArticleDOI
TL;DR: It is shown that the electron-donating effect of donor groups can enhance ligand-centered transitions and thoroughly eliminate cluster-centered excited states by delocalizing the molecular transition orbitals from the cluster unit to the ligand, leading to 13-fold increased photoluminescence quantum yield.
Abstract: Organic light-emitting diodes using cluster emitters have recently emerged as a flexible optoelectronic platform to extend their biological and optical applications. However, their inefficient cluster-centered excited states and deficient electrical properties limit device performance. Here, we introduce donor groups in organic ligands to form ligand-activated clusters, enabling the fabrication of the first cluster-based sky blue–emitting device with a record 30- and 8-fold increased luminance and external quantum efficiency up to ~7000 nits and ~8%, respectively. We show that the electron-donating effect of donor groups can enhance ligand-centered transitions and thoroughly eliminate cluster-centered excited states by delocalizing the molecular transition orbitals from the cluster unit to the ligand, leading to 13-fold increased photoluminescence quantum yield. In turn, the excellent rigidity and photostability of the cluster unit improve the color purity and efficiency stability of the devices. These results will motivate the further development of high-performance optoelectronic clusters by ligand engineering.

Journal ArticleDOI
TL;DR: Gonzalez et al. as mentioned in this paper presented the Massive and Distant Clusters of WISE Survey (MaDCoWS), a search for galaxy clusters at 0.7 ≲ z ≲ 1.5 based upon data from the Wide-Field Infrared Survey Explorer (WISE) mission.
Abstract: Author(s): Gonzalez, AH; Gettings, DP; Brodwin, M; Eisenhardt, PRM; Stanford, SA; Wylezalek, D; Decker, B; Marrone, DP; Moravec, E; O'Donnell, C; Stalder, B; Stern, D; Abdulla, Z; Brown, G; Carlstrom, J; Chambers, KC; Hayden, B; Lin, YT; Magnier, E; Masci, FJ; Mantz, AB; McDonald, M; Mo, W; Perlmutter, S; Wright, EL; Zeimann, GR | Abstract: © 2019. The American Astronomical Society. All rights reserved. We present the Massive and Distant Clusters of WISE Survey (MaDCoWS), a search for galaxy clusters at 0.7 ≲ z ≲ 1.5 based upon data from the Wide-field Infrared Survey Explorer (WISE) mission. MaDCoWS is the first cluster survey capable of discovering massive clusters at these redshifts over the full extragalactic sky. The search is divided into two regions - the region of the extragalactic sky covered by Pan-STARRS (δ g -30°) and the remainder of the southern extragalactic sky at δ l -30° for which shallower optical data from the SuperCOSMOS Sky Survey is available. In this paper, we describe the search algorithm, characterize the sample, and present the first MaDCoWS data release - catalogs of the 2433 highest amplitude detections in the WISE-Pan-STARRS region and the 250 highest amplitude detections in the WISE-SuperCOSMOS region. A total of 1723 of the detections from the WISE-Pan-STARRS sample have also been observed with the Spitzer Space Telescope, providing photometric redshifts and richnesses, and an additional 64 detections within the WISE-SuperCOSMOS region also have photometric redshifts and richnesses. Spectroscopic redshifts for 38 MaDCoWS clusters with IRAC photometry demonstrate that the photometric redshifts have an uncertainty of σ z /(1 + z) ≃ 0.036. Combining the richness measurements with Sunyaev-Zel'dovich observations of MaDCoWS clusters, we also present a preliminary mass-richness relation that can be used to infer the approximate mass distribution of the full sample. The estimated median mass for the WISE-Pan-STARRS catalog is , with the Sunyaev-Zel'dovich data confirming that we detect clusters with masses up to M 500 ∼ 5 ×10 14 M (M 200 ∼ 10 15 M ).

Journal ArticleDOI
TL;DR: The impact of rotational diffusion on the process of irreversible nanoparticle aggregation is investigated in nanoparticle aggregations at low temperatures with high uniformity.
Abstract: We simulated irreversible aggregation of non-interacting particles and of particles interacting via repulsive and attractive potentials explicitly implementing the rotational diffusion of aggregating clusters. Our study confirms that the attraction between particles influences neither the aggregation mechanism nor the structure of the aggregates, which are identical to those of non-interacting particles. In contrast, repulsive particles form more compact aggregates and their fractal dimension and aggregation times increase with the decrease of the temperature. A comparison of the fractal dimensions obtained for non-rotating clusters of non-interacting particles and for rotating clusters of repulsive particles provides an explanation for the conformity of the respective values obtained earlier in the well established model of diffusion-limited cluster aggregation neglecting rotational diffusion and in experiments on colloidal particles.

Journal ArticleDOI
TL;DR: In this article, the authors reported the detection of intracluster light (ICL) with 300 galaxy clusters in the redshift range of 0.2-0.3.
Abstract: Using data collected by the Dark Energy Survey (DES), we report the detection of intracluster light (ICL) with ~300 galaxy clusters in the redshift range of 0.2–0.3. We design methods to mask detected galaxies and stars in the images and stack the cluster light profiles, while accounting for several systematic effects (sky subtraction, instrumental point-spread function, cluster selection effects, and residual light in the ICL raw detection from background and cluster galaxies). The methods allow us to acquire high signal-to-noise measurements of the ICL and central galaxies (CGs), which we separate with radial cuts. The ICL appears as faint and diffuse light extending to at least 1 Mpc from the cluster center, reaching a surface brightness level of 30 mag arcsec−2. The ICL and the cluster CG contribute 44% ± 17% of the total cluster stellar luminosity within 1 Mpc. The ICL color is overall consistent with that of the cluster red sequence galaxies, but displays the trend of becoming bluer with increasing radius. The ICL demonstrates an interesting self-similarity feature—for clusters in different richness ranges, their ICL radial profiles are similar after scaling with cluster R 200m , and the ICL brightness appears to be a good tracer of the cluster radial mass distribution. These analyses are based on the DES redMaPPer cluster sample identified in the first year of observations.


Journal ArticleDOI
TL;DR: In the proposed method, an overlap clustering is used to obtain the supports (unions of the core regions and the fringe regions) of the clusters and perturbation analysis is applied to separate thecore regions from the supports.
Abstract: The traditional k-means, which unambiguously assigns an object precisely to a single cluster with crisp boundary, does not adequately show the fact that a cluster may not have a well-defined cluster boundary. This paper presents a three-way k-means clustering algorithm based on three-way strategy. In the proposed method, an overlap clustering is used to obtain the supports (unions of the core regions and the fringe regions) of the clusters and perturbation analysis is applied to separate the core regions from the supports. The difference between the support and the core region is regarded as the fringe region of the specific cluster. Therefore, a three-way explanation of the cluster is naturally formed. Davies–Bouldin index (DB), Average Silhouette index (AS) and Accuracy (ACC) are computed by using core region to evaluate the structure of three-way k-means result. The experimental results on UCI data sets and USPS data sets show that such strategy is effective in improving the structure of clustering results.

Journal ArticleDOI
TL;DR: This work proposes a novel Local Cores-based Cluster Validity (LCCV) index, which is effective for obtaining the optimal cluster number for data sets containing clusters with arbitrary shapes and a hierarchical clustering algorithm based on the LCCV index.
Abstract: It is critical to evaluate the quality of clusters for most cluster analysis. A number of cluster validity indexes have been proposed, such as the Silhouette and Davies–Bouldin indexes. However, these validity indexes cannot be used to process clusters with arbitrary shapes. Some researchers employ graph-based distance to cluster nonspherical data sets, but the computation of graph-based distances between all pairs of points in a data set is time-consuming. A potential solution is to select some representative points. Inspired by this idea, we propose a novel Local Cores-based Cluster Validity (LCCV) index to improve the performance of Silhouette index. Local cores, with local maximum density, are selected as representative points. Since graph-based distance is used to evaluate the dissimilarity between local cores, the LCCV index is effective for obtaining the optimal cluster number for data sets containing clusters with arbitrary shapes. Moreover, a hierarchical clustering algorithm based on the LCCV index is proposed. The experimental results on synthetic and real data sets indicate that the new index outperforms existing ones.

Journal ArticleDOI
TL;DR: In this paper, Henon-type Monte Carlo codes are used to explore initial cluster parameters that map into the bimodal distribution in core radii separating the so-called corecollapsed and non-core-collapsed clusters.
Abstract: Globular clusters (GCs) in the Milky Way exhibit a well-observed bimodal distribution in core radii separating the so-called "core-collapsed" and "non-core-collapsed" clusters. Here, we use our Henon-type Monte Carlo code, CMC, to explore initial cluster parameters that map into this bimodality. Remarkably, we find that by varying the initial size of clusters (specified in our initial conditions in terms of the initial virial radius, $r_v$) within a relatively narrow range consistent with the measured radii of young star clusters in the local universe ($r_v \approx 0.5-5$ pc), our models reproduce the variety of present-day cluster properties. Furthermore, we show that stellar-mass black holes (BHs) play an intimate role in this mapping from initial conditions to the present-day structural features of GCs. We identify "best-fit" models for three GCs with known observed BH candidates, NGC 3201, M22, and M10, and show that these clusters harbor populations of $\sim 50-100$ stellar-mass BHs at present. As an alternative case, we also compare our models to the core-collapsed cluster NGC 6752 and show that this cluster likely contains few BHs at present. Additionally, we explore the formation of BH binaries in GCs and demonstrate that these systems form naturally in our models in both detached and mass-transferring configurations with a variety of companion stellar types, including low-mass main sequence stars, white dwarfs, and sub-subgiants.

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TL;DR: In this paper, a modified convergent point method was used to search for stars with space velocities close to the space velocity of the Praesepe cluster and its tails.
Abstract: Within a 400 pc sphere around the Sun, we search for Praesepe's tidal tails in the Gaia DR2 dataset. We used a modified convergent-point method to search for stars with space velocities close to the space velocity of the Praesepe cluster. We find a clear indication for the existence of Praesepe's tidal tails, both extending up to 165~pc from the centre of the cluster. A total of 1393 stars populate the cluster and its tails, giving a total mass of 794 M_Sun. We determined a tidal radius of 10.77 pc for the cluster and a tidal mass of 483 M_Sun. The corresponding half-mass radius is 4.8 pc. We also found clear indication for mass segregation in the cluster. The tidal tails outside 2 tidal radii are populated by 389 stars. The total contamination of our sample by field stars lies between 50 to 100 stars or 3.6 to 7.2 per cent. We used an astrometrically and photometrically clean sub-sample of Gaia DR2 which makes our Praesepe sample incomplete beyond M_G ~ 12.0 mag, which corresponds to about 0.25 M_Sun. A comparison with an N-body model of the cluster and its tails shows remarkably good coincidence. Three new white dwarfs are found in the tails.

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TL;DR: A Cloud-terminal integrated GIS platform architecture designed to meet the requirements of processing and analyzing spatiotemporal big data and developed according to the architecture is described.

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TL;DR: The results highlight the crucial importance of the reactive atmosphere on the stability of single-atom versus cluster catalysts and Pt cluster mobility is shown to be activated at low temperature and high H2 pressure.
Abstract: Atomically dispersed metals promise the ultimate catalytic efficiency, but their stabilization onto suitable supports remains challenging owing to their aggregation tendency. Focusing on the industrially-relevant Pt/γ-Al2O3 catalyst, in situ X-ray absorption spectroscopy and environmental scanning transmission electron microscopy allow us to monitor the stabilization of Pt single atoms under O2 atmosphere, as well as their aggregation into mobile reduced subnanometric clusters under H2. Density functional theory calculations reveal that oxygen from the gas phase directly contributes to metal-support adhesion, maximal for single Pt atoms, whereas hydrogen only adsorbs on Pt, and thereby leads to Pt clustering. Finally, Pt cluster mobility is shown to be activated at low temperature and high H2 pressure. Our results highlight the crucial importance of the reactive atmosphere on the stability of single-atom versus cluster catalysts.